• 한국세라믹학회지
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• 제34권8호
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• pp.886-896
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• 1997

To investigate an effect of phase separation on precipitation characteristics of CuCl nanocrystals in CuCl doped nonlinear optical glasses, borosilicate glass systems with 9 different compositions with ~2wt% of CuCl were selected and CuCl doped glasses were prepared by melting and precipitation method. Microstructural properties of the CuCl doped glasses were analyzed by optical absorption spectroscopy, acid elution test, TEM, and EDXS. While phase separation did not occur in Glass A~D, interconnected and droplet microstructures due to phase separation were found in Glass E, F and Glass G~I, respectively. In the particular composition of the matrix glasses in this study, the precipitation of the CuCl particles was observed in the phase separable glasses, not in phase non-separable glasses. The CuCl particles were precipitated in both silica-rich phase region and boronrich phase region of the glass matrix. In the case of 7.7Na2O-36.6B2O3-52.7SiO2(mole%) glass, the larger CuCl particles than those in the silica-rich phase region were observed in the boron-rich phase region.

• 한국세라믹학회지
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• 제35권12호
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• pp.1337-1342
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• 1998

To investigate an effect of phase separation on precipitation characteristics of ZnS microcrystals in ma-trix glass ZnS doped borosilicate glasses for nonlinear optical applications were prepared by melting and pre-cipitation process. ZnS dopant contributed to phase separation promotion which increased the phase separa-tion of the matrix glass within immiscibility region. It was also found that ZnS as phase separation promoter showed a similar contribution for some selected glass compositions in miscibility region. The precipitation of ZnS microcrystals occurred in thephase separable glass compoitions. The radius of ZnS microcrystals in-creased with increasing the heat treatment temperature and Na2O contents of matrix glass composition. The ZnS particle sizes estimated by effective mass approximation ranged from about 30 to 80${\AA}$ It was suf-ficiently small to show quantum confinement effect.

• 한국전자통신학회논문지
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• 제14권4호
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• pp.729-736
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• 2019

본 논문에서는 비음수 행렬 분해 필터 뒷단에 위너필터를 추가하여 배경음 분리 성능을 향상하는 방법을 제안한다. 배경음이 혼재된 음성 신호의 경우 비음수 행렬 분해 기법으로 1차 분리된 신호에는 아직 완전히 분리되지 못한 부분이 잔류할 수 있다. 이러한 경우 위너필터에 의해 잔류하는 신호의 크기에 비례하여 줄여줄 수 있어 배경음 분리 또는 저감 효과를 기대할 수 있다. 실험을 통해 위너필터를 추가한 경우가 비음수행렬 분해 기법만 적용한 경우에 비해 저감 효과가 높은 것을 확인할 수 있었다.

• Journal of Electrical Engineering and Technology
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• 제10권5호
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• pp.2179-2188
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• 2015

Recently, many researches have been done to solve the challenging problem of Blind Source Separation (BSS) problems in the underdetermined cases, and the “Two-step” method is widely used, which estimates the mixing matrix first and then extracts the sources. To estimate the mixing matrix, conventional algorithms such as Single-Source-Points (SSPs) detection only exploits the sparsity of original signals. This paper proposes a new underdetermined mixing matrix estimation method for time-delayed mixtures based on the receiver prior exploitation. The prior information is extracted from the specific structure of the complex-valued mixing matrix, which is used to derive a special criterion to determine the SSPs. Moreover, after selecting the SSPs, Agglomerative Hierarchical Clustering (AHC) is used to automaticly cluster, suppress, and estimate all the elements of mixing matrix. Finally, a convex-model based subspace method is applied for signal separation. Simulation results show that the proposed algorithm can estimate the mixing matrix and extract the original source signals with higher accuracy especially in low SNR environments, and does not need the number of sources before hand, which is more reliable in the real non-cooperative environment.

• Bulletin of the Korean Chemical Society
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• 제23권11호
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• pp.1541-1544
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• 2002

The concentration of B in steels is important due to its influence on mechanical properties of steel such as hardenability, hot workability, and creep resistance. An analytical method has been developed to determine B in steel samples by high-resolution inductively coupled plasma mass spectrometry (HR-ICP-MS). National Institute of Standard and Technology Standard Reference Material (NIST SRM) 348a was analyzed to validate the analytical method. The steel sample was digested in a centrifuge bottle with addition of aqua regia and $^{10}B$ spike isotope. Sample pH was then adjusted to higher than 10 to precipitate most matrix elements such as Fe, Cr, and Ni. After centrifugation, the supernatant solution was passed through a cation exchange column to enhance the matrix separation efficiency. B recovery efficiency was about 37%, while matrix removal efficiency was higher than 99.9% for major matrix elements. The isotope dilution method was used for quantification and the determined B concentration was in good agreement with the certified value.

• 대한기계학회논문집A
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• 제20권4호
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• pp.1146-1153
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• 1996

The properties of FRP(fiber-reinforced plastics) depend not only on the characteristics of the matrix but also on the structure of fiber mat and the fiber type of reinforcement. Therefore it is very important to study the characteristics of reinforcement and matrix. In this paper, a method is proposed which can be used to measure the mean coeffcient of separation for the press molding of FRP, and the mean equivalent coefficient of separation is obtained from the separation coefficient. And the relationship between the mean equivalent coefficient of separation and the structure of fiber mat is discussed. The effects of corrlelation coefficient between separation and orientation on the mean equivalent coefficient are also presented.

• 공업화학
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• 제35권3호
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• pp.155-181
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• 2024

최근, 기존 분리막의 성능을 향상시켜 CO₂ 분리를 효율적으로 수행하기 위한 중요한 연구가 진행되고 있다. 이는 탄소포집 공정에서의 활용을 확대하는 것을 목표로 하고 있다. 분리막 기술은 비용 및 에너지 효율성, 연속 운전, 작은 공정 크기 등의 장점으로 인해 탄소제로 이슈에 대처하는 유망한 탄소 포집 기술로 부상하고 있다. 연구된 여러 종류의 분리막 중 혼합기질막(mixed-matrix membrane, MMM)이 전반적인 가스 분리 공정의 효율을 향상시킬 수 있는 전통적인 분리막의 대안으로 제안되었다. 2D 나노소재는 쉬운 개질과 기능화, 다른 재료와의 결합 등 특징적인 성질로 인해 다양한 일반적인 2D 나노소재들이 가스 분리를 위한 효율적인 MMMs 제작에 사용되고 있다. 본 논문은 2D 나노소재를 사용한 MMMs 분야의 최근 발전을 검토하였다. 또한, CO₂ 분리 및 포집을 위한 2D 나노소재 기반 분리막의 현재 도전과 전망을 논의하였다.

• 한국원자력학회:학술대회논문집
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• 한국원자력학회 1996년도 추계학술발표회논문집(2)
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• pp.571-576
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• 1996

The 3-stage cascade composed of the multisection-type bithermal $H_2$/$H_2O$-exchange columns was suggested for heavy water separation. In order to study the separation characteristics for the cascade, a matrix equation with 18 simultaneous equations was composed and the concentrations and flow rates were calculated for the all parts of the cascade. Product D-concentration decreases and extraction yield increases with increasing cut in each stage, which is one of the principal parameters of the separation characteristics. The optimization of the 3-stage cascade can be made by case study using the matrix equation.

• 한국음향학회지
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• 제28권8호
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• pp.697-705
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• 2009

본 논문에서는 단일 채널 다성 음악에서 리듬 악기 신호를 블라인드 (blind) 방식으로 추출하는 방법을 제안한다. 상업적으로 판매되는 음악 신호는 대부분 2개 이하만의 혼합된 채널 형태로 사용자에게 제공되는 반면, 그 혼합 채널 신호에는 각각 가창 음원 (vocal)을 비롯한 많은 종류의 악기가 포함되어 있는 형태이다. 따라서, 혼합 신호의 개수가 음원 개수와 같거나 더 많은 상황을 가정하는 기존의 음원 분리 방법처럼, 혼합 환경이나 신호의 통계적 특성을 모델링하는 것 보다는, 특정 음원의 고유 특성을 활용하는 것이 이처럼 적은 개수의 혼합 신호만을 가지고 있는 환경 (underdetermined)에 더욱 적합하다. 본 논문에서는 다른 화성 악기와 혼합되어 있는 상창에서 리듬 악기 음원만을 추출하는 것을 목표로 한다. 비음수 행렬 인수분해 (NMF: Nonnegative Matrix Factorization)의 변형된 알고리즘인 비음수 행렬의 부분적 공동 분해 (NMPCF: Nonnegative Matrix Partial Co-Factorization)가 입력 행렬의 시간적인 속성과 주파수적인 속성에서 다양한 관계성을 분석하기 위해 활용된다. 또한 특정 시간 단위로 입력 신호를 파편화 (segmentation)하고, 파편들에서 반복적으로 발생하는 성분을 리듬 악기가 공통적으로 포함하고 있는 특성이라고 가정한다. 본 논문에서 제안하는 방법은 일반적으로 받아들여질 수 있을 정도의 성능을 보여주지만, 기본적으로는 사전 정보를 활용하는 타악기 음원 분리 방식보다 우수하지는 않다. 그러나 블라인드 방식의 특성상, 사전 정보를 획득한기에 용이하지 않은 경우, 또는 사전 정보와 현격히 다른 리듬 악기가 연주되는 경우 등에 보다 유연하게 대응할 수 있다.

• Bulletin of the Korean Chemical Society
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• 제25권2호
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• pp.233-236
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• 2004

Total impurity analysis of a primary standard solution is one of the essential procedures to determine an accurate concentration of the standard solution by the gravimetry. Bi impurity is determined in Pb standard solutions by inductively coupled plasma mass spectrometry (ICP-MS). The direct nebulization of the Pb standard solution produces a significant amount of the Pb matrix-induced molecular ions which give rise to a serious spectral interference to the Bi determination. In order to avoid the spectral interference from the interferent $^{208}PbH^+$, the hydride generation method is employed for the matrix separation. The Bi hydride vapor is generated by reaction of the sample solution with 1% sodium borohydride solution. The vapor is then directed by argon carrier gas into the ICP after separation from the mixture solution in a liquid-gas separator made of a polytetrafluoroethylene membrane tube. The presence of 1000 ${\mu}$g/mL Pb matrix caused reduction of the bismuthine generation efficiency by about 40%. The standard addition method is used to overcome the chemical interference from the Pb matrix. Optimum conditions are investigated for the hydride-generation ICPMS. The detection limit of this method is 0.5 pg/mL for the sample solutions containing 1000 ${\mu}$g/mL Pb matrix.