• Title/Summary/Keyword: Matrix separation

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Gas Permeability through Mixed Matrix Membrane of Poly(dimethylsiloxane) with Aluminosilicate Hollow Nanoparticles (알루미노규산염 나노입자를 이용한 Poly(dimethylsiloxane) 복합매질 분리막의 기체투과 특성)

  • Fang, Xiaoyi;Jung, Bumsuk
    • Membrane Journal
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    • v.29 no.1
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    • pp.51-60
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    • 2019
  • In order to improve gas separation properties of polymeric membranes which have been widely applied in the industry field, aluminosilicate hollow nanoparticles named as allophanes were synthesized by sol-gel method and formulated in Poly(dimethylsiloxane) (PDMS) matrix to investigate the gas separation properties of PDMS membrane. Transmission electron microscope (TEM), Energy dispersive X-ray analysis (EDX), X-ray diffractometer (XRD), Surface area and pore size analyzer (BET) and Fourier transform infrared spectrophotometer (FTIR) were carried out to characterize the synthetic allophanes. Then the PDMS mixed matrix membranes were prepared by adding different volume fraction of allophanes. To examine the effect of allophanes addition in PDMS matrix using unmodified allophane and modified ones, the gas permeation experiments were performed using oxygen, nitrogen, methane and carbon dioxide. As the volume fraction of modified allophane increased up to 4.05 Vol% the permeability of four test gases through PDMS mixed matrix membranes increased. Also, the selectivity of $O_2/N_2$ and $CO_2/CH_4$ increased with the contents of the modified allophane. Further improvement of gas separation properties of PDMS mixed matrix membranes containing higher volume percent of allophanes can be expected as long as well dispersion of allophanes in PDMS matrix can be achieved for better PDMS membranes.

Demodulation and Performance of Multicomponent Undersampled AM, FM and AM-FM Signals (다중 성분의 저표본화된 AM, FM 및 AM-FM 신호들의 복조와 성능)

  • Son, Tae-Ho;Hwang, Ui-Cheon
    • The Transactions of the Korean Institute of Electrical Engineers D
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    • v.49 no.7
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    • pp.399-406
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    • 2000
  • We propose an nonlinear demodulation algorithm for undersampled multicomponent AM(Amplitude Modulation), FM(Frequency Modulation) and AM-FM signals. First, we derive respectively undersampling frequency of the AM, FM and AM-FM using undersampling scheme, and separate respectively monocomponent signals from multicomponent signals using periodic algebraic separation algorithm. In this case augmented separation matrix is very regular and sparse, it has a special structure. The proposed demodulation algorithm detects respectively message signals of the IA(Instantaneous Amplitude) and IF(Instantaneous Frequency) from descrete monocomponent AM, FM and AM-FM signals with an undersampling frequency to be controllable. Verifying the RMS(Root Mean Squares) errors of the detected signals, we show that the performance is excellent.

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Rheological behavior during the phase separation of thermoset epoxy/thermoplastic polymer blends

  • Kim, Hongkyeong;Kookheon Char
    • Korea-Australia Rheology Journal
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    • v.12 no.1
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    • pp.77-81
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    • 2000
  • Rheological behavior of thermoset/thermoplastic blends of epoxy/polyethersulphone (PES) was monitored during curing of the epoxy resin. During the isothermal curing of the mixture, a fluctuation in viscosity just before the abrupt viscosity increase was observed. This fluctuation is found to be due to the phase separation of PES from the matrix epoxy resin during the curing. The experimentally observed viscosity fluctuation is simulated with a simple two phase suspension model in terms of the increase in domain size. The viscosity profiles obtained experimentally at different isothermal curing temperatures are in good agreement with the predictions from the simple model taking into account the viscosity change due to the growth of PES domain and the network formation of the epoxy matrix.

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Novel Phenol Resin Carbonizing Method for Carbon Interlayer Coating between Reinforcing Fiber and Matrix in Fiber Reinforced Ceramic Composite (페놀수지 탄화 코팅법을 이용한 섬유강화 복합재료 계면 형성에 관한 연구)

  • Kim, Se-Young;Woo, Sang-Kuk;Han, In-Sub
    • Journal of the Korean Ceramic Society
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    • v.46 no.3
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    • pp.301-305
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    • 2009
  • The novel carbon coating process for interlayer of fiber reinforced ceramic composites between fiber and matrix was performed by carbonizing phenolic resin solution that coated on fiber surface in $N_2$ atmosphere at $600^{\circ}C$ to improve the strength and fracture toughness of CMC(ceramic matrix composite). 160 nm carbon layer was coated on fiber surface with 5 vol% of phenolic resin solution. Since the process temperature ($600^{\circ}C$) is lower than chemical vapor deposition($900{\sim}1000^{\circ}C$), the strength and toughness could be preserved. Furthermore the coating thickness uniformity was improved to 8% of deviation along the stacking sequence. Therefore, prevention from fiber degradation during coating process and controlling coating thickness uniformity along the preform depth were achieved by coating with phenolic resin carbonizing method.

Preparation of Polyvinylpyrrolidone/AgBF4/Al(NO3)3 Electrolyte Membranes for Facilitated Gas Transport (기체 촉진수송을 위한 polyvinylpyrrolidone/AgBF4/Al(NO3)3 전해질 분리막 제조)

  • Yoon, Ki Wan;Kang, Sang Wook
    • Membrane Journal
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    • v.26 no.1
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    • pp.38-42
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    • 2016
  • Polyvinylpyrrolidone (PVP), which is glassy polymer to have amide functional group, was induced to fabricate the facilitated olefin transport membranes for olefin/paraffin separation. Separation performance for the mixed gas consisting of propylene and propane (50 : 50 vol%) was measured by gas chromatography and bubble flow meter. The properties of membranes were confirmed by scanning electron microscope and FT-IR. The results of long-term separation tests showed the selectivity of 15 and permeance of 1.3 GPU. The membranes was compared with poly(2-ethyl-2-oxazoline) $(POZ)/AgBF_4/Al(NO_3)_3$ membranes and the characteristics were confirmed as polymer matrix for facilitated transport membranes.

12-Oxoeicosatetraenoic acid, a candidate signal for placenta separation, activates matrix metalloproteinase and induces apoptosis in bovine trophoblast cells

  • Hachiro Kamada
    • Animal Bioscience
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    • v.36 no.3
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    • pp.429-440
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    • 2023
  • Objective: 12-oxo-5Z,8Z,10E,14Z-eicosatetraenoic acid (12-KETE), a metabolite of arachidonic acid, is a strong candidate signal for placenta separation following calf discharge at delivery. In the present study, the effects of 12-KETE on bovine trophoblast cells were investigated to determine its function in the placentome at delivery. Methods: Bovine trophoblast cells derived from blastocysts were used. They were cocultured with or without fibroblasts derived from bovine placentome and/or bovine uterine epithelial cells. 12-KETE was added to the culture medium. Results: Bovine trophoblast cells contained binucleate cells and strongly expressed caudal type homeobox 2 (CDX-2) genes. Addition of 12-KETE to the trophoblast cell colony without feeder cells or that on a fibroblast monolayer induced rapid exfoliation of the colony. After 12-KETE addition, trophoblast cells emitted strong fluorescence caused by the degradation of dye-quenched collagen, indicating that 12-KETE activated matrix metalloproteinase of the trophoblast cells. Exfoliated cell colonies were stained with YOPRO-1, but not propidium iodide (PI). Moreover, DNA fragmentation and Bcl-2 associated X protein (Bax) gene (apoptosis stimulator) upregulation were observed in exfoliated cells, indicating that 12- KETE induced trophoblast cell apoptosis. These results were consistent with previous in vivo observations; however, even a lower concentration of 12-KETE activated trophoblast protease. Meanwhile, fibroblasts derived from the bovine placentome converted arachidonic acid to 12-KETE. Conclusion: These observations indicate that 12-KETE may serve as a signal for placenta separation at delivery.

Incremental Fuzzy Clustering Based on a Fuzzy Scatter Matrix

  • Liu, Yongli;Wang, Hengda;Duan, Tianyi;Chen, Jingli;Chao, Hao
    • Journal of Information Processing Systems
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    • v.15 no.2
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    • pp.359-373
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    • 2019
  • For clustering large-scale data, which cannot be loaded into memory entirely, incremental clustering algorithms are very popular. Usually, these algorithms only concern the within-cluster compactness and ignore the between-cluster separation. In this paper, we propose two incremental fuzzy compactness and separation (FCS) clustering algorithms, Single-Pass FCS (SPFCS) and Online FCS (OFCS), based on a fuzzy scatter matrix. Firstly, we introduce two incremental clustering methods called single-pass and online fuzzy C-means algorithms. Then, we combine these two methods separately with the weighted fuzzy C-means algorithm, so that they can be applied to the FCS algorithm. Afterwards, we optimize the within-cluster matrix and betweencluster matrix simultaneously to obtain the minimum within-cluster distance and maximum between-cluster distance. Finally, large-scale datasets can be well clustered within limited memory. We implemented experiments on some artificial datasets and real datasets separately. And experimental results show that, compared with SPFCM and OFCM, our SPFCS and OFCS are more robust to the value of fuzzy index m and noise.

A Study on the Processing of Long Fiber-Reinforced Composite Materials for Thermoforming On the Correlation Coefficient between Separation and Orientation (Thermoforming용 長纖維强化 複合材料의 成形工程에 관한 硏究 分離$\cdot$配向의 相關계수)

  • 이동기;김정락;김상필;이우일;김이곤
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.17 no.5
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    • pp.1106-1114
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    • 1993
  • A composite material is composed of a reinforcement and a matrix, which determine mechanical characteristics of the molded part. There is no doubt that the properties of a composite material depend not only on the characteristics of the matrix but also on the structure of glass fiber mat and a fiber type of reinforcement. Therefore it is very important to study the composites of reinforcement and the matrix, and to control the fiber type in the process of molding of composite materials. In this study, the specimen was made of a glass fiber mat of 6-7mm thickness by scattering it in the air after cutting the glass fiber mat with needle punching makes change according to the type of needle and the number of times of stretching. First the sheet was made by means of a hot-press after accumulating a matrix and a glass fiber according to each mat structure of glass fiber. It was heated the manufactured sheet with the dry oven and molded it a secondary high temperature compression by a 30 ton oilhydraulic press. A definition of a correlation coefficient is showed up during this period and find it out with the relation of the fiber-matrix separation and the fiber orientation. We studied effects of the glass fiber mat structures on the correlation coefficient.

Evaluation of a Pretreatment Method for Two-Dimensional Gel Electrophoresis of Synovial Fluid Using Cartilage Oligomeric Matrix Protein as a Marker

  • Kong, Min-Kyung;Min, Byoung-Hyun;Lee, Pyung-Cheon
    • Journal of Microbiology and Biotechnology
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    • v.22 no.5
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    • pp.654-658
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    • 2012
  • Osteoarthritis (OA) is the most common rheumatic pathology. One of the major objectives of OA research is the development of early diagnostic strategies such as those using proteomic technology. Synovial fluid (SF) in OA patients is a potential source of biomarkers for OA. The efficient and reliable preparation of SF proteomes is a critical step towards biomarker discovery. In this study, we have optimized a pretreatment method for twodimensional gel electrophoresis (2DE) separation of the SF proteome, by enriching low-abundance proteins and simultaneously removing hyaluronic acid, albumin, and IgG. SF samples pretreated using this optimized method were then evaluated by 1DE and 2DE separation followed by immunodetection of cartilage oligomeric matrix protein (COMP), a known OA biomarker, and by the identification of 3 proteins (apolipoprotein, haptoglobin precursor, and fibrinogen D fragment) that are related to joint diseases.

Audio Source Separation Method based on Beamspace-domain Multichannel Non-negative Matrix Factorization, Part II: A Study on the Beamspace Transform Algorithms (빔공간-영역 다채널 비음수 행렬 분해 알고리즘을 이용한 음원 분리 기법 Part II: 빔공간-변환 기법에 대한 고찰)

  • Lee, Seok-Jin;Park, Sang-Ha;Sung, Koeng-Mo
    • The Journal of the Acoustical Society of Korea
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    • v.31 no.5
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    • pp.332-339
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    • 2012
  • Beamspace transform algorithm transforms spatial-domain data - such as x, y, z dimension - into incidence-angle-domain data, which is called beamspace-domain data. The beamspace transform method is generally used in source localization and tracking, and adaptive beamforming problem. When the beamspace transform method is used in multichannel audio source separation, the inverse beamspace transform is also important because the source image have to be reconstructed. This paper studies the beamspace transform and inverse transform algorithms for multichannel audio source separation system, especially for the beamspace-domain multichannel NMF algorithm.