• Title/Summary/Keyword: Matrix carrier

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Nonvolatile Memory and Photovoltaic Devices Using Nanoparticles

  • Kim, Eun Kyu;Lee, Dong Uk
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.02a
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    • pp.79-79
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    • 2013
  • Quantum-structures with nanoparticles have been attractive for various electronic and photonic devices [1,2]. In recent, nonvolatile memories such as nano-floating gate memory (NFGM) and resistance random access memory (ReRAM) have been studied using silicides, metals, and metal oxides nanoparticles [3,4]. In this study, we fabricated nonvolatile memories with silicides (WSi2, Ti2Si, V2Si) and metal-oxide (Cu2O, Fe2O3, ZnO, SnO2, In2O3 and etc.) nanoparticles embedded in polyimide matrix, and photovoltaic device also with SiC nanoparticles. The capacitance-voltageand current-voltage data showed a threshold voltage shift as a function of write/erase voltage, which implies the carrier charging and discharging into the metal-oxide nanoparticles. We have investigated also the electrical properties of ReRAM consisted with the nanoparticles embedded in ZnO, SiO2, polyimide layer on the monolayered graphene. We will discuss what the current bistability of the nanoparticle ReRAM with monolayered graphene, which occurred as a result of fully functional operation of the nonvolatile memory device. A photovoltaic device structure with nanoparticles was fabricated and its optical properties were also studied by photoluminescence and UV-Vis absorption measurements. We will discuss a feasibility of nanoparticles to application of nonvolatile memories and photovoltaic devices.

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A Study on the Analytical Characterizations of the Low Flow-Low Power ICP-AES (Low flow-low power 유도결합 플라즈마 원자방출 분광법에서의 분석적 특성에 관한 연구)

  • Yang, Hae Soon;Kim, Young Man;Kim, Sun Tae;Choi, Beom Suk
    • Analytical Science and Technology
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    • v.7 no.3
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    • pp.253-260
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    • 1994
  • Analytical characteristics of low power-low flow inductively coupled plasma-atomic emission spectometry(ICP-AES) has been studied. Although the net intensity of the low power ICP is lower than the moderate power ICP, the signal to background ratio becomes higher since the background intensity decreases with decreasing the RF power. The detection limit of the low power ICP is comparable with that of the moderate power ICP. The dynamic range of the calibration curve of the low power ICP is $10^4{\sim}10^5$. The ionization interferences by alkali metals increase with increasing the carrier gas flow rate, but the effects are not varied significantly with the RF power.

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Bioelectrochemical Denitrification Using Permeabilized Ochrobactrum anthropi SY509

  • Choi Kyung-Oh;Song Seung-Hoon;Kim Yang-Hee;Park Doo-Hyun;Yoo Young-Je
    • Journal of Microbiology and Biotechnology
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    • v.16 no.5
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    • pp.678-682
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    • 2006
  • To remove nitrate from wastewater, a novel bioelectrochemical denitrification system is introduced. In this proposed system, biological reactions are coupled with reactions on the electrode, whereby the electrons are transferred to the bacterial enzymes via a mediator as an electron carrier. The denitrification reaction was achieved with permeabilized Ochrobactrum anthropi SY509 containing denitrifying enzymes, such as nitrate reductase, nitrite reductase, and nitrous oxide reductase, and methyl viologen was used as the mediator. The electron transfer from the electrode to the enzymes in the bacterial cells was confirmed using cyclic voltammetry. A high removal efficiency of nitrate was achieved when the bioelectrochemical system was used with the permeabilized cells. Furthermore, when the permeabilized cells were immobilized to a graphite felt electrode using a calcium alginate matrix containing graphite powder, a high removal efficiency was achieved (4.38 nmol/min mg cell) that was comparable to the result when using the free permeabilized cells.

Chitosan-Coated Fe3O4 Magnetic Nanoparticles as Carrier of Cisplatin for Drug Delivery

  • Arum, Yosefine;Oh, Yun-Ok;Kang, Hyun Wook;Ahn, Seok-Hwan;Oh, Junghwan
    • Fisheries and Aquatic Sciences
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    • v.18 no.1
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    • pp.89-98
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    • 2015
  • A synthesis method for a chitosan-coated magnetic drug-delivery system of cisplatin is proposed. Here, cisplatin was conjugated to the surface of Magnetite ($Fe_3O_4$) nanoparticles via a (3-Aminopropyl)-trimethoxysilane (APTS) coupling agent. To reduce the cytotoxic effect of cisplatin, the magnetic drug was then encapsulated in chitosan (CS-cisplatin-$Fe_3O_4$) through the water/oil (W/O) emulsion method. The CS-cisplatin-$Fe_3O_4$ nanoparticles were synthesized in a spherical shape with a diameter of 190 nm. The cytotoxicity assay was performed using HeLa cells. The cisplatin uptake of the cells was determined using High Performance Liquid Chromatography (HPLC) to calculate the drug content. The controlled release of cisplatin was demonstrated by regulating the dissolution and diffusion of the drug through the chitosan matrix.

Tooth-derived bone graft material

  • Kim, Young-Kyun;Lee, Junho;Um, In-Woong;Kim, Kyung-Wook;Murata, Masaru;Akazawa, Toshiyuki;Mitsugi, Masaharu
    • Journal of the Korean Association of Oral and Maxillofacial Surgeons
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    • v.39 no.3
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    • pp.103-111
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    • 2013
  • With successful extraction of growth factors and bone morphogenic proteins (BMPs) from mammalian teeth, many researchers have supported development of a bone substitute using tooth-derived substances. Some studies have also expanded the potential use of teeth as a carrier for growth factors and stem cells. A broad overview of the published findings with regard to tooth-derived regenerative tissue engineering technique is outlined. Considering more than 100 published papers, our team has developed the protocols and techniques for processing of bone graft material using extracted teeth. Based on current studies and studies that will be needed in the future, we can anticipate development of scaffolds, homogenous and xenogenous tooth bone grafts, and dental restorative materials using extracted teeth.

Electronic Structure of Organic/organic Interface Depending on Heteroepitaxial Growth Using Templating Layer

  • Lim, Hee Seon;Kim, Sehun;Kim, Jeong Won
    • Applied Science and Convergence Technology
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    • v.23 no.6
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    • pp.351-356
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    • 2014
  • The electronic structure at organic-organic interface gives essential information on device performance such as charge transport and mobility. Especially, the molecular orientation of organic material can affect the electronic structure at interface and ultimately the device performance in organic photovoltaics. The molecular orientation is examined by the change in ionization potential (IP) for metal phthalocyanines (MPc, M=Zn, Cu)/fullerene ($C_{60}$) interfaces on ITO by adding the CuI templating layer through ultraviolet photoelectron spectroscopy measurement. On CuPc/$C_{60}$ bilayer, the addition of CuI templating layer represents the noticeable change in IP, while it hardly affects the electronic structure of ZnPc/$C_{60}$ bilayer. The CuPc molecules on CuI represent relatively lying down orientation with intermolecular ${\pi}-{\pi}$ overlap being aligned in vertical direction. Consequently, in organic photovoltaics consisting of CuPc and $C_{60}$ as donor and acceptor, respectively, the carrier transport along the direction is enhanced by the insertion of CuI templaing layer. In addition, optical absorption in CuPc molecules is increased due to aligned transition matrix elements. Overall the lying down orientation of CuPc on CuI will improve photovoltaic efficiency.

Recent Applications of Polymeric Biomaterials and Stem Cells in Tissue Engineering and Regenerative Medicine (고분자 생체재료와 줄기세포를 이용한 조직공학과 재생의학의 최신 동향)

  • Lee, Sang Jin;Yoo, James J.;Atala, Anthony
    • Polymer(Korea)
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    • v.38 no.2
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    • pp.113-128
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    • 2014
  • Tissue engineering and regenerative medicine strategies could offer new hope for patients with serious tissue injuries or end-stage organ failure. Scientists are now applying the principles of cell transplantation, material science, and engineering to create biological substitutes that can restore and maintain normal function in diseased or injured tissues/organs. Specifically, creation of engineered tissue construct requires a polymeric biomaterial scaffold that serves as a cell carrier, which would provide structural support until native tissue forms in vivo. Even though the requirements for scaffolds may be different depending on the target applications, a general function of scaffolds that need to be fulfilled is biodegradability, biological and mechanical properties, and temporal structural integrity. The scaffold's internal architecture should also enhance the permeability of nutrients and neovascularization. In addition, the stem cell field is advancing, and new discoveries in tissue engineering and regenerative medicine will lead to new therapeutic strategies. Although use of stem cells is still in the research phase, some therapies arising from tissue engineering endeavors that make use of autologous adult cells have already entered the clinic. This review discusses these tissue engineering and regenerative medicine strategies for various tissues and organs.

Sensitivity Analysis of Coupled Horizontal and Torsional Vibration of Hull Girder (선체 저차 수평.비틂 연성 고유진동 감도해석)

  • Dae-Seung Cho;Sa-Soo Kim;Doo-Yong Na
    • Journal of the Society of Naval Architects of Korea
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    • v.36 no.2
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    • pp.105-113
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    • 1999
  • This paper resents a prediction method of natural frequencies of coupled horizontal and torsional vibration of hull girder based on design sensitivity analysis in case of the changes of system parameters. The sensitivity analysis is formulated applying the direct differentiation method and transfer matrix method. In the analysis, warping, shear deformation due to torsion and the continuity condition at the connected part of open and closed hull section are considered. Using the presented method. The affection for natural frequencies by the change of system parameters, especially cargo and added mass and their centers, is numerically investigated for a real large container carrier.

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Review on Facilitated Olefin Transport Membranes Utilizing Polymer Electrolytes and Polymer Nanocomposites (고분자 전해질과 고분자 나노복합체를 활용한 올레핀 촉진수송 분리막에 대한 총설)

  • Kang, Sang Wook
    • Membrane Journal
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    • v.26 no.3
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    • pp.173-178
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    • 2016
  • In this short review, the polymer electrolyte membranes consisting of polymer and Ag salts were introduced and various approaches to solve the long-term stability were summarized. In particular, utilizing $AgNO_3$ as carriers with ionic liquid, the replacement of polymer matrix as poly(ethylene phthalate) (PEP) for strong coordinative interactions with Ag ions and the introduction of $Al(NO_3)_3$ to $polymer/AgBF_4$ complexes were introduced for long-term stable facilitated olefin transport membranes. For the polymer nanocomposite membranes, the role of electron acceptors as polarizer on the surface of AgNPs and the approach to solve the low permeance were introduced.

Radiochemical separation of 89Zr: a promising radiolabel for immuno-PET

  • Vyas, Chirag K.;Park, Jeong Hoon;Yang, Seung Dae
    • Journal of Radiopharmaceuticals and Molecular Probes
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    • v.2 no.1
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    • pp.43-50
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    • 2016
  • $^{89}Zr$ with the favorable nuclear decay kinetics and chemical properties is an appealing radiometal for its application in immuno-PET using radiolabeled monoclonal antibodies. Rising demand of ultrahigh purity and high-specific activity $^{89}Zr$ has propelled the radiochemist worldwide to develop an overall efficacious method for its promising separation from the target matrix $^{89}Y$. The requirement of elevated radiochemical purity (${\geq}$ 99.99%) has accelerated the efforts since last two decades to achieve higher decontamination and separation factors of carrier free $^{89}Zr$ over $^{89}Y$ using several suitable separation techniques. However, each of the technique has its own pros and cons which prior to its actual medical application needs to be optimized and thoroughly scrutinized to avoid further complications during radiolabelling of the pharmaceuticals. In this short review article we will specifically consider as well focus on the historical development and the recent advances on the radiochemical separation of $^{89}Zr$ from $^{89}Y$ which will be helpful for the separation scientist involved in this area to understand the existing available means and plan the strategy to investigate and develop the novel techniques to overcome the problems involved in the present methods.