• Steel and Composite Structures
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• v.48 no.3
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• pp.305-320
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• 2023

The mechanical properties of polymeric composites are degraded under elevated temperatures due to the effect of temperature on the mechanical behavior of the resin and resin fiber interfaces. In this study, the effect of temperature on the impact response of the carbon fiber reinforced plastics (CFRP) was investigated at low-velocity impact (LVI) using a drop-weight impact tester machine. All the composite plates were fabricated using a vacuum infusion process with a stacking sequence of [45/0_2/-45/90_2]s, and a thickness of 2.9 mm. A group of the specimens was exposed to an environment with a temperature cycling at the range of -30 ℃ to 65 ℃. In addition, three other groups of the specimens were aged at ambient (28 ℃), -30 ℃, and 65 ℃ for ten days. Then all the conditioned specimens were subjected to LVI at three energy levels of 10, 15, and 20 J. To assess the behavior of the damaged composite plates, the force-time, force-displacement, and energy-time diagrams were analyzed at all temperatures. Finally, radiography, optical microscopy, and scanning electron microscopy (SEM) were used to evaluate the effect of the temperature and damages at various impact levels. Based on the results, different energy levels have a similar effect on the LVI behavior of the samples at various temperatures. Delamination, matrix cracking, and fiber failure were the main damage modes. Compared to the samples tested at room temperature, the reduction of temperature to -30 ℃ enhanced the maximum impact force and flexural stiffness while decreasing the absorbed energy and the failure surface area. The temperature increasing to 65 ℃ increased the maximum impact force and flexural stiffness while decreasing the absorbed energy and the failure surface area. Applying 200 thermal cycles at the range of -30 ℃ to 65 ℃ led to the formation of fine cracks in the matrix while decreasing the absorbed energy. The maximum contact force is recorded under cyclic temperature as 5.95, 6.51 and 7.14 kN, under impact energy of 10, 15 and 20 J, respectively. As well as, the minimum contact force belongs to the room temperature condition and is reported as 3.93, 4.94 and 5.71 kN, under impact energy of 10, 15 and 20 J, respectively.

• Journal of the Korea Institute of Military Science and Technology
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• v.8 no.3 s.22
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• pp.124-130
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• 2005

In this paper, the effects of matrix hygrothermal aging and residual stress changes on $Avimid^{(R)}$ K3B/IM7 laminates in $80^{\circ}C$ water were studied. The factors causing the $80^{\circ}C$ water to degradation of the laminates could be the degradation of the matrix toughness, the change in residual stresses. After 500 hours fully saturated aging of the neat resin, the weight gain was 1.55% increase with the diffusion coefficient $7{\times}10^{-6}m^2/s$ and the fracture toughness was decreased about 41%. After 100 hours fully saturated aging of the $[+45/0/-45/90]_s$ K3B/IM7 laminates in $80^{\circ}C$ water, the weight gain was 0.41% increase with the diffusion coefficient $1{\times}10^{-6}m^2/s$ and the loss of the microcracking fracture toughness was 43.8% of the original toughness. To see whether the residual stress influenced the fracture toughness, two ply $[90^{\circ}/0^{\circ}]$ laminates were put in $80^{\circ}C$ water from 2 hours to 8 hours. The changes in residual stress in 8 hours are less than 3MPa. Because the 3MPa change is not sufficient to degrade the laminates, the main factor to degrade the microcracking fracture toughness was the degradation of the matrix fracture toughness.

• The Transactions of the Korean Institute of Electrical Engineers
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• v.38 no.7
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• pp.511-523
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• 1989

This paper investigates physical properties, the electrical and mechanical characteristics of the epoxy resin with different curing methods and postcuring conditions at room temperature or cryogenic temperature (LN2). According to the results in this paper, first, it is found that the physical properties, electrical and mechanical characteristics of the epoxy resin are largely affected by the interior reaction temperature on the curing. Thus, in the fabrication of the sample, several excellent characteristics of the sample are obtained by controlling the interior reaction temperature of the epoxy resin. Second, the sample having optimal electrical and mechanical characteristics is obtained for the repetitive post-curing method at 100c in view point of the post-curing conditions of the epoxy resin. Third, it appears that tan and characteristics at LN2 temperature are about half of those at room temperature. Fourth, it appears that the dielectric strength of the epoxy resin at LN2 temperature is higher by about 0.6-1.0 MV/cm than that at room temperature. The heat-aging of the epoxy resin due to the micro-defect and excess fever-movement have been noticed to affect dielectric strength at LN2 temperature more significantly than at room temperature.

• Restorative Dentistry and Endodontics
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• v.29 no.6
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• pp.520-531
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• 2004

The aim of this study was to investigate the effect of monomer and filler compositions on the rheological properties related to the handling characteristics of resin composites. Methods. Resin matrices that Bis-GMA as base monomer was blended with TEGDMA as diluent at various ratio were mixed with the Barium glass (0.7 um and 1.0 um), 0.04 um fumed silica and 0.5 um round silica. All used fillers were silane treated. In order to vary the viscosity of experimental composites, the type and content of incorporated fillers were changed, Using a rheometer, a steady shear test and a dynamic oscillatory shear test were used to evaluate the viscosity ($\eta$) of resin matrix, and the storage shear modulus (G'), the loss shear modulus (G"), the loss tangent ($tan{\delta}$) and the complex viscosity (${\eta}^*$) ofthe composites as a function of frequency ${\omega}{\;}={\;}0.1-100{\;}rad/s$. To investigate the effect of temperature on the viscosity of composites, a temperature sweep test was also undertaken. Results. Resin matrices were Newtonian fluid regardless of diluent concentration and all experimental composites exhibited pseudoplastic behavior with increasing shear rate. The viscosity of composites was exponentially increased with increasing filler volume%. In the same filler volume, the smaller the fillers were used, the higher the viscosities were. The effect of filler size on the viscosity was increased with increasing filler content. Increasing filler content reduced $tan{\delta}$ by increasing the G' further than the G". The viscosity of composites was decreased exponentially with increasing temperature.

• Journal of Adhesion and Interface
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• v.22 no.2
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• pp.63-68
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• 2021

Unsaturated Polyester Resin (UPR) is in general used as a resin to prepare for composite materials with reinforcing materials such as glass fibers. UPR, a thermosetting resin, is used in industry to prepare for sheet molding compound (SMC) molding prepreg that has excellent productivity and is advantageous for mass production among various molding methods of composite materials. The fiber-reinforced composite material using UPR as a matrix material is light and has the advantage of excellent physical properties, but it is weak against impact and is fragile. Four types of polyurethane were synthesized and added to UPR resin to overcome the shortcomings.

• Fibers and Polymers
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• v.4 no.2
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• pp.77-83
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• 2003

The cell modeling homogenization method to derive the constitutive equation considering the microstructures of the fiber reinforced composites has been previously developed for composites with simple microstructures such as 2D plane composites and 3D rectangular shaped composites. Here, the method has been further extended for 3D circular braided com-posites, utilizing B-spline curves to properly describe the more complex geometry of 3D braided composites. For verification purposes, the method has been applied for orthotropic elastic properties of the 3D circular braided glass fiber reinforced com-posite, in particular for the tensile property. Prepregs of the specimen have been fabricated using the 3D braiding machine through RTM (resin transfer molding) with epoxy as a matrix. Experimentally measured uniaxial tensile properties agreed well with predicted values obtained for two volume fractions.

• Journal of the Korean Ceramic Society
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• v.52 no.4
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• pp.284-289
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• 2015

This study examined carbon layer coating on silicon carbide (SiC) fibers by utilizing solid-state and wet chemistry routes to confer toughness to the fiber-reinforced ceramic matrix composites, as an alternative to the conventional pyrolytic carbon (PyC) interphase layer. Electrophoretic deposition (EPD) of carbon black nanoparticles using both AC and DC current sources, and the vacuum infiltration of phenolic resin followed by pyrolysis were tested. Because of the use of a liquid phase, the vacuum infiltration resulted in more uniform and denser carbon coating than the EPD routes with solid carbon black particles. Thereafter, vacuum infiltration with controlled variation in phenolic resin concentration, as well as the iterations of infiltration steps, was improvised to produce a homogeneous carbon coating having a thickness of several hundred nanometers on the SiC fiber. Conclusively, it was demonstrated that the carbon coating on the SiC fiber could be achieved using a simpler method than the conventional chemical vapor deposition technique.

• Composites Research
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• v.14 no.1
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• pp.30-38
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• 2001

As fiber reinforced composite materials are widely used in aircraft, space structures and robot arms, the on-line cure monitoring during the cure process of the composite materials has become an important research area for the better quality and productivity. In this paper, the dielectric circuit of the Wheatstone bridge type for measuring the dissipation factor during cure of thermsetting resin matrix composite materials was designed and manufactured. Also, the dielectric sensor for the cure monitoring of high temperature cure composites was developed and tested. The residual thermal stresses of the dielectric sensor during high temperature cure were analyzed by the finite element method and its dielectric characteristics at high temperature cure were analyzed by the finite element method and its dielectric characteristics at high temperature were evaluated. The on-line cure monitoring of the BMI(Bismaleimide) resin was performed using the developed Wheatstone bridge type circuit and the high-temperature dielectric sensor.

• International Journal of Concrete Structures and Materials
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• v.10 no.4
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• pp.539-553
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• 2016

Polymer concrete (PC) has been favoured over Portland cement concrete when low permeability, high adhesion, and/or high durability against aggressive environments are required. In this research, a new class of PC incorporating Multi-Walled Carbon Nanotubes (MWCNTs) is introduced. Four PC mixes with different MWCNTs contents were examined. MWCNTs were carefully dispersed in epoxy resin and then mixed with the hardener and aggregate to produce PC. The impact strength of the new PC was investigated by performing low-velocity impact tests. Other mechanical properties of the new PC including compressive, flexural, and shear strengths were also characterized. Moreover, microstructural characterization using scanning electron microscope and Fourier transform infrared spectroscopy of PC incorporating MWCNTs was performed. Impact test results showed that energy absorption of PC with 1.0 wt% MWCNTs by weight of epoxy resin was significantly improved by 36 % compared with conventional PC. Microstructural analysis demonstrated evidence that MWCNTs significantly altered the chemical structure of epoxy matrix. The changes in the microstructure lead to improvements in the impact resistance of PC, which would benefit the design of various PC structural elements.

• Applied Chemistry for Engineering
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• v.17 no.4
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• pp.381-385
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• 2006

We applied a new analyzing technique for the polyurethane acrylate hybrid emulsion sample composed of polyurethane resin and acrylate resin using the phase-lag mapping techniques of atomic force microscopy. For the analysis, we synthesized similarly sized pure polyurethane dispersion and acrylate emulsion particles, which were used for measuring the standard phase-lag intensities for each material. Based on these signal intensity, we could discriminate acryl particle in the polyurethane dispersion matrix with the resolution of a few tens of nanometers. Thus, the techniques show a new possibility in the analysis of the organic two-phase particles, and we believe the techniques are helpful to design organic particles.