Browse > Article

Analysis of Hybrid Emulsion Surfaces by the Phase Lag Mapping Atomic Force Microscopy  

Han, Sang-Hoon (Department of Chemical Engineering, Dong-A University)
Kim, Jong-Min (Department of Chemical Engineering, Dong-A University)
Park, Dong-Won (Department of Chemical Engineering, Dong-A University)
Publication Information
Applied Chemistry for Engineering / v.17, no.4, 2006 , pp. 381-385 More about this Journal
Abstract
We applied a new analyzing technique for the polyurethane acrylate hybrid emulsion sample composed of polyurethane resin and acrylate resin using the phase-lag mapping techniques of atomic force microscopy. For the analysis, we synthesized similarly sized pure polyurethane dispersion and acrylate emulsion particles, which were used for measuring the standard phase-lag intensities for each material. Based on these signal intensity, we could discriminate acryl particle in the polyurethane dispersion matrix with the resolution of a few tens of nanometers. Thus, the techniques show a new possibility in the analysis of the organic two-phase particles, and we believe the techniques are helpful to design organic particles.
Keywords
hybrid emulsion; AFM; phase-lag; polyurethane; acrylate; analysis;
Citations & Related Records
연도 인용수 순위
  • Reference
1 S. M. Chang, H. J. Lee, J. M. Kim, and H. Muramatsu, Prospectives Ind. Chem., 2, 52 (1999)
2 H. S. Choi, S. T. Noh, and K. B. Choi J. Ind. Eng. Chem., 5, 52 (1999)
3 A. Noy, C. Frisbie, L. F. Rozsnyai, Mark S. Wrighton, and C. M. Lieber, J. Am. Chem. Soc., 117, 7943 (1995)   DOI   ScienceOn
4 G. Krausch, M. Hipp, M. Blau, O. Marti, and J. Mlynek, Macromolecules, 28, 260 (1995)   DOI   ScienceOn
5 L. M. Sergeeva, S. I. Skiba, and L. V. Karabanova, Polym. Int., 39, 317 (1996)   DOI
6 C. H. Cho, H. D. Seo, B. H. Min, H. K. Cho, S. T. Noh, H. G. Choi, Y. H. Cho, and J. H. Kim, J. Korean Ind. Eng. Chem., 13, 825 (2002)
7 Y. Tezuka, S. Nobe, and T. Shiomi, Macromolecules, 28, 8251 (1995)   DOI
8 S. H. Han and D. W. Park, J. Korean Ind. Eng. Chem., 17, 132 (2006)
9 J. M. Kim, H. S. Jung, J. W. Park, H. Y. Lee, and T. Kawai, Anal. Chem. Acta, 525, 151 (2004)   DOI   ScienceOn
10 S. J. Hanley, J. Giasson, J. F. Revoi, and D. G. Gray, Polymer, 33, 4639 (1992)   DOI   ScienceOn
11 C. Hare, J. Protective Coat., 10, 69 (1993)
12 J. M. Kim, H. S. Jung, J. W. Park, Y. Tetsuo, and O. Hiroaki, J. Am. Chem. Soc., 127, 2358 (2005)   DOI   ScienceOn
13 D. Park, B. Keszler, V. Galiatsatos, and J. P. Kenedy, Macromolecules, 28, 2595 (1995)   DOI   ScienceOn
14 U. S. Patent 5,173,526 (1992)
15 Y. Zhang, R. J. Heath, and D. J. Hourston, J. Appl. Polym. Sci., 75, 406 (2000)   DOI   ScienceOn
16 S. Dadbin and R. P. Chaplin, J. Appl. Polym. Sci., 81, 3361 (2001)   DOI   ScienceOn
17 J. Y. Kim, D. H. Shin, K. J. Ihn, and K. D. Suh, J. Ind. Eng. Chem., 9, 37 (2003)
18 R. van den Berg, H. de Groot, and M. A. van Dijk, Polymer, 35, 5778 (1994)   DOI   ScienceOn
19 M. Argaman, R. Golan, N. H. Thomson, and H. G. Hansma, Nucl. Acids. Res., 25, 4379 (1997)   DOI   ScienceOn
20 W. Saito, O. Mori, Y. Ikeo, M. Kawaguchi, T. Imae, and T. Kato, Macromolecules, 28, 7945 (1995)   DOI   ScienceOn
21 J. G. Park, J. Y. Kim, and K. D. Suh, J. Appl Polym. Sci., 69, 2291 (1998)   DOI   ScienceOn