• Title/Summary/Keyword: Material separation

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Theoretical Study for Hydrogen Production from an Integrated Gasification Combined Cycle System

  • Lee, Sang-Sup
    • Environmental Engineering Research
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    • v.16 no.1
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    • pp.35-39
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    • 2011
  • An integrated gasification combined cycle (IGCC) system has been attracting attention due to its increased energy conversion efficiency and ability to treat various carbonaceous materials. IGCC is also expected to play an important role in the future supply of hydrogen energy. The use of a palladium-based membrane to separate the hydrogen from the synthesis gas stream has been intensively studied due to its exceptional hydrogen-separating capability. However, theoretical research on hydrogen separation is still an unfamiliar area in Korea. First-principle density functional theory was applied in this study to investigate the dissociative adsorption of hydrogen onto a palladium surface. The stability of hydrogen on the surface was theoretically evaluated with various adsorption configurations, partial pressures and temperatures. Further theoretical and experimental studies were also suggested to find a more hydrogen-selective material.

Hydrogen Separation from Binary and Quaternary Gas Mixtures Using Organic Templating Silica Membrane (유기템플레이팅 실리카막을 이용한 이성분 및 사성분 수소 분리)

  • Moon, Jong-Ho;Bae, Ji-Han;Chung, Jong-Tae;Lee, Jae-Wook;Lee, Chang-Ha
    • 한국신재생에너지학회:학술대회논문집
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    • 2007.06a
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    • pp.9-12
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    • 2007
  • The transport mechanisms of the MTES (methyltriethoxysilane) templating silica/a-alumina composite membrane were evaluated by using four binary and one quaternary hydrogen mixtures through permeation experiments at unsteady- and steady-states. Since the permeation flux in the MTES membrane, through the experimental and theoretical studies, was affected by molecular sieving effects as well as surface diffusion properties, the kinetic and equilibrium separation should be considered simultaneously according to molecular properties. In order to depict the transient multi-component permeation on the templating silica membrane, the GMS (generalized Maxwell-Stefan) and DGM (dust gas model) were adapted to unsteady-state material balance.

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Comparative dynamic analysis of axially loaded beams on modified Vlasov foundation

  • Hizal, Caglayan;Catal, Hikmet Huseyin
    • Structural Engineering and Mechanics
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    • v.57 no.6
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    • pp.969-988
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    • 2016
  • Vibration analysis of the beams on elastic foundation has gained the great interest of many researchers. In the literature, there are many studies that focus on the free vibration analysis of the beams on one or two parameter elastic foundations. On the other hand, there are no sufficient studies especially focus on the comparison of dynamic response including the bending moment and shear force of the beams resting on Winkler and two parameter foundations. In this study, dynamic response of the axially loaded Timoshenko beams resting on modified Vlasov type elastic soil was investigated by using the separation of variables method. Governing equations were obtained by assuming that the material had linear elastic behaviour and mass of the beam was distributed along its length. Numerical analysis were provided and presented in figures to find out the differences between the modified Vlasov model and conventional Winkler type foundation. Furthermore, the effect of shear deformation of elastic soil on the dynamic response of the beam was investigated.

High throughput sorting(HTS) system using a cantilever-type electrode array (캔틸레버(Cantilever) 형태의 전극 어레이(array)를 이용한고속 분리 시스템)

  • Lee, Jung-Hun;Kim, Young-Ho;Kim, Young-Geun;Kim, Byung-Kyu
    • Journal of Sensor Science and Technology
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    • v.19 no.2
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    • pp.112-117
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    • 2010
  • A high-throughput sorting (HTS) system has been designed to separate target particles using a negative dielectrophoretic (n-DEP) force. The system consists of a meso-sized channel and a cantilever-type electrode(CE) array designed to separate a large number of target particles by discerning subtle difference of weight and dielectric material property of the particles. Using the polystyrene beads with various sizes of 10, 25 and $50{\mu}m$, the developed system exhibits high-throughput sorting of about 200 beads/sec and more than 80 % of separation efficiency.

Slaking and Particle-Separation Characteristics of the Organic Fine Soil in Paddy Fields (전답용 유기질 세립토의 슬레이킹 내구성 및 분쇄 특성)

  • Cho, Sung-Min
    • Journal of the Korean Society of Environmental Restoration Technology
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    • v.5 no.3
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    • pp.1-8
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    • 2002
  • Clayey paddy soils should be mixed with other good coarse soils to be used as a material for the lining, or, embankment. However, it has been difficult to separate soil particles from each other because of the internal cohesion in the soil gradation(separation) characteristics of the fine soil were investigated by various laboratory tests including the slaking durability test. Degradation rate of the soil were dependent upon the clay content and the initial water content before the submergence. The amount of degradations decreased as initial water content increased with exponential functions. The dried specimens separated into the particles after 24 hours of the submergence and specimens which water contents were less than 10% also separated into the particles after 2, or 3 days of the submergence. Compaction curves and the unconfined strength were not varied before and after the submergence. However, unconfined strength decreased as water content increased.

Feasibility Study with Several Sorption Materials to Treat Road Runoff Pollutions (흡착 소재별 도로 노면 유출 오염원의 저감성 비교 연구)

  • Park, Sangwoo;Oh, Jeill;Choi, Younghwa
    • Journal of Korean Society of Water and Wastewater
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    • v.20 no.5
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    • pp.709-717
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    • 2006
  • This research was conducted to figure out the feasibility of several sorption materials to treat various pollutants in road runoff. In advance of the major feasibility test with various sorption materials, the separation process with $1.2{\mu}m$ filter was conducted and showed that slight portion of pollutants was removed(Orgamic pollutant - 20%, Nutrient salt - 50%, Heavy metals - 0~30%). To remove dissolved pollutants in runoff, various materials were tested through an isotherm sorption experiment. As a result, GAC showed most effective material among them to lessen most contaminants such as organic compounds and nutrients. On the other hand, ion-exchange resin and Zeolite showed limited usefulness on the some heavy metals. Freundlich model was most suitable for the current experiment data, and the amount of adsorbent (GAC) could calculated based on this model.

Development of Separation Process for Active Ingradient from Waste Biomass (폐 바이오매스로부터 생리활성물질의 분리공정 개발)

  • Sung, Ju-Li;Kim, Seong-Mun;Kim, Jin-Hyun
    • Proceedings of the Korean Institute of Resources Recycling Conference
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    • 2003.10a
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    • pp.196-200
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    • 2003
  • A novel prepurification method was developed aiming at increasing yield and purity, also reducing solvent usage for purification of paclitaxel. The use of a micelle and precipitation in the prepurification process allows for rapid separation of paclitaxel from interfering compounds and dramatically reduces solvent usage compared to alternative methodologies. The prepurification process serves to minimize the size and complexity of the HPLC operations for paclitaxel purification. The process is readily scalable to a pilot plant and eventually to a production environment where multikilogram quantities of material are expected to be produced. As much as possible, the process has been optimized to minimize solvent usage, complexity, and operating costs.

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Methods to Improve Light Harvesting Efficiency in Dye-Sensitized Solar Cells

  • Park, Nam-Gyu
    • Journal of Electrochemical Science and Technology
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    • v.1 no.2
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    • pp.69-74
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    • 2010
  • Methodologies to improve photovoltaic performance of dye-sensitized solar cell (DSSC) are reviewed. DSSC is usually composed of a dye-adsorbed $TiO_2$ photoanode, a tri-iodide/iodide redox electrolyte and a Pt counter electrode. Among the photovoltaic parameters of short-circuit photocurrent density, open-circuit voltage and fill factor, short-circuit photocurrent density is the collective measure of light harvesting, charge separation and charge collection efficiencies. Internal quantum efficiency is known to reach almost 100%, which indicates that charge separation occurs without loss by recombination. Thus, light harvesting efficiency plays an important role in improvement of photocurrent. In this paper, technologies to improve light harvesting efficiency, including surface area improvement by nano-dispersion, size-dependent light scattering efficiency, bi-functional nano material, panchromatic absorption by selective positioning of three different dyes and transparent conductive oxide (TCO)-less DSSC, are introduced.

Rational Design of Extractive Distillation Toward Enhanced Separation of HFPO from HFP/HFPO Mixture

  • Lee, Yongtaek
    • Clean Technology
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    • v.24 no.1
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    • pp.15-20
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    • 2018
  • Hexafluoropropyleneoxide ($C_3F_6O$, HFPO) is highly expensive and it may be used as a raw material for the synthesis of various fluorine based compounds. Currently, extractive distillation method has gained considerable attention to collect the HFPO from a mixture of HFPO / hexafluoropropylene ($C_3F_6$, HFP). Optimized operating conditions are studied using a theoretical method for the extraction process. Among available solvents for the purification process, the use of 1,1-dichloro-1-fluoroethane exhibits a high purity of HFPO as a top product and minimize the required heat duty. Since the boiling point of the solvent increases as the pressure in the column increases, the enhanced extractive capability of the solvent led to the high purity of HFPO at the high pressure.

The review of IFMFC (International Forum on Magnetic Force Control) -The accumulated knowledge and experience of the magnetic force control with IFMFC

  • Watanabe, Tsuneo
    • Progress in Superconductivity and Cryogenics
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    • v.20 no.2
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    • pp.20-23
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    • 2018
  • The practical use of superconducting magnets is limited to medical equipment, energy equipment and the like. Therefore, it does not fully utilize the superior features of superconducting magnet or magnetic force. In order to overcome this blockage condition, The international Forum on Magnetic Force Control (IFMFC) was launched in Tokyo in 2010 by the magnetic separation researchers in Japan, Korea and China. The policy is to hold around the country every year, to apply the application to the engineering field of magnetic force utilization and information exchange about the development of applied science to mutual visit of researchers and to develop the application field of superconducting magnets in particular. The main object is to review the field of application of magnetic force with respect to published papers at 8 IFMFCs, and to introduce the trend of research forum utilizing strong magnetic force which is rare in the world. The United Nations is asking each country to achieve Corporate Social Responsibility (CSR) targets for 2030. This IFMFC review will be utilized in this field.