• Journal of Environmental Health Sciences
• /
• v.27 no.4
• /
• pp.85-91
• /
• 2001

The regulation of Material safety data sheets(MSDS) was required for the chemicals in use in the workplace from July 1976. Under the provisions of the workplace hazardous materials information system, employers in Korea must be provided with accurate and comprehensive MSDS. To examine the reliability of MSDS for organic solvents, 63 organic solvents and MSDS were collected from the workplace of 39 companies located in Kyonggi province. Manufacture\`s MSDS were compared with the actual composition of the collected samples, and further examined the reliability by checking whether the chemicals analyzed were included in the MSDS correctly. 38 solvents were able to analyze their composition by gas chromatography-mass selective detector(GC-MSD). Among them, 28 solvents were incorrect in their composition and contents. In some case, health hazardous or carcinogenic chemicals which were not included in the MSDS were detected from samples. As a result of evaluating whether the MSDS correspond to the regulation required by Industrial Safety and Health Act (ISHA), the information in the MSDS including hazard classification, occupational exposure level, toxicity, regulatory information were incorrectly provided, and some MSDS did not disclose carcinogenic in their MSDS, and some MSDS were not written in the standard format. From this survey, continuous monitoring and promoting correct MSDS, and analyzing the components of the solvents were required to endure the reliability of MSDS for organic solvents.

• Journal of Korean Society of Occupational and Environmental Hygiene
• /
• v.22 no.4
• /
• pp.276-283
• /
• 2012

Objectives: This study was conducted to survey the viewpoints on the material safety data sheets(MSDS) training for safety and health managers(SHMs) and workers. Subjects and Methods: A surveillance was made using a self-reported questionnaire for 78 SHMs and 122 workers to survey their viewpoints on the MSDS training. Survey results were analyzed using the SPSS program(Version 12.0 SPSS Inc., USA). Results: The result of the study shows that there are contrasts with the cognition of SHMs' and workers' on the education of MSDS and the program preference for education efficiency of MSDS. Workers were significantly more interested in the MSDS education than the SHMs did. Workers preferred the education program which is easily to be understood, to voluntarily participate on MSDS education, but SHMs did the quiz program. Also we found that the SHMs wanted to learn the education program via the expert(37.3%) rather than education resources(33.3%) which were served by government or relevant agency. In contrast, workers wanted the audio-visual education program, which is mainly consisted of accident cases (33.3%), rather than periodical education program(22.1%). Conclusions: This study showed that effectiveness of MSDS education was associated with the program served by company, and the education program for the voluntary participation of the workers should be made practical and attractive.

• Journal of Korean Society of Occupational and Environmental Hygiene
• /
• v.15 no.1
• /
• pp.52-60
• /
• 2005

This study was carried to assess the accuracy of material safety data sheets (MSDS) for some water-soluble metalworking fluid (MWF) with respect to mono- ethanolamine(MEA), di-ethanolamine(DEA) and tri-ethanolamine (TEA). 39 fresh and 52 used MWFs for this study were taken from the workplace. The quantification and qualification of MEA, DEA and TEA were done using ion-chromatography. Three main findings of this study were 1) EA that was not addressed in material safety & data sheets (MSDS) was found to be enough higher than 1%, 2) 33.3% of 39 fresh MWF showed ingredient and concentration of MEA, DEA and TEA in MSDS and 3) the concentrations of MEA(20.5%), DEA(41.3%) and TEA(15.4%) were much higher than those indicated in MSDS. Consequently, we concluded that the accuracy on ingredients and concentrations of MEA, DEA and TEA provided in MWF was very low. Our study recommends that the limit concentration of chemical except for carcinogen that employer has to indicate in MSDS should be lowered from 1% to 0.1% .

• Journal of Korean Society of Occupational and Environmental Hygiene
• /
• v.10 no.2
• /
• pp.18-26
• /
• 2000

Since the regulation of MSDS (Material Safety Data Sheets) had started from July 1996, employers were required to furnish MSDS for the chemicals in use in their workplace. However, many MSDS did not contain upright information for the chemicals, and they were not updated regularly, and were not written in the standard format required by the Industrial Safety and Health Act (ISHA). The purposes of this study were 1) to examine the reliability of MSDS for mixed solvents, 2) to provide reliable MSDS to employers or employees, 3) to find out any difficulties in implementing MSDS after the initiation, and 4) to promote regular MSDS updating and to ensure the reliability of MSDS for chemical manufacturers. To check the reliability of MSDS of mixed chemicals, 21 samples of mostly degreasing solvents were collected along with their MSDS from the work place. The samples were analyzed by gas chromatography-mass selective detector(GC-MSD). Their components were classified as saturated hydrocarbon, cyclic hydrocarbon, aromatics, and halogen containing hydrocarbon, and the amount of each class were measured. Manufacture's MSDS were compared with the actual composition of the collected samples, and further examined the reliability by checking whether the chemicals analyzed were included in the MSDS correctly. Finally, each item of MSDS was evaluated whether the MSDS correspond to the regulation required by ISHA. The results were following: 1) most of the degreasing solvents in MSDS were incorrect in their composition and contents, 2) the information in the MSDS including hazard classification, exposure level, toxicity, regulatory information were incorrectly provided, and 3) some MSDS did not disclose carcinogens in their MSDS. Continuous monitoring of MSDS was required to ensure reliability of MSDS. The Chemicals containing hydrocarbons from C10-C15 need to be tested to provide toxicity data. In addition, governmental support for providing correct MSDS was recommended to ensure reliability of MSDS. The MSDS regulation relating to the confidential business information may need to be revised to ensure reliability of MSDS.

• Journal of Korean Society of Occupational and Environmental Hygiene
• /
• v.17 no.1
• /
• pp.63-70
• /
• 2007

This study investigated the current management staus of chemical substance information on Material Safety Data Sheets(MSDS) and Chemical Information Cards(CIC) provided by Korea Occupational Safety & Health Agency(KOSHA) and also researched the kind and the characteristics of chemical substance information provided in other organizations. MSDS DB in Korean provided on KOSHANET(which is Kosha website) is 50,802 in total, among whom are single chemical substances with 31,870 kinds(18,932%) and are mixed chemical substances with 31,870 kinds(62.7%). The number of visiting MSDS DB on KOSHANET for the search of chemicals was 2,049,806. The number has increased each year. The CIC provided for workplaces is all 542 kinds : 14 harmful substances subject to permission, 168 harmful substances subject to management, 360 KOEL(Korean Occupational Exposure Limits) establishment substances. MSDS internationally provided by organizations producing MSDS DB was written with 16 sections, which is suitable for the writing basis of American Standards Institute(ANSI) and International Organization for Standardization(ISO) and provided chemical substance information on more than 100,000 kinds in most organizations.

• Journal of Technologic Dentistry
• /
• v.32 no.3
• /
• pp.221-232
• /
• 2010

Purpose: It is necessary for dental technicians exposed to hazardous chemicals in the dental laboratories to be informed of the various harmful effects of chemicals for their health and safety. The purposes of this study was to investigate the actual condition of the use of MSDS in dental laboratories and the recognition rate of MSDS for dental technicians. Methods: 231 dental technicians who were self-written questionnaire. The results were analyzed by SPSS 12.0. The answers to the questionnaire underwent frequency analysis, chi-square test and correlation analysis were performed to investigate association between health effects and recognition rate of chemical information. Results: The results from the effects of damage caused by chemicals 60.7%, and when it was less than 2 years working experience 47.6%. Currently any dental laboratories(rooms) was not furnished MSDS(0%) and even similar data furnishing rate was only 17.3%. Answer rate of 'Do not know about MSDS' was 73.6%. In addition to, education in the types and characteristics of chemicals(74.5%) does not receive all the higher education. For the question of 'To prevent human risks and accidents, is to provide chemical information needed', the answer rate of 'needed' was 87.2%. Moreover, the answer rate of 'To provide chemical information that could prevent accidents' was 76.6%. Therefore it was found that dental technicians need to be provided for chemical information. In addition, they wanted to get education related to chemicals used in the workplace(80.5%), and 90.9% was answered that they was willing to keep MSDS in they workplace. Conclusion: This study investigated the current dental laboratories(rooms) and the MSDS for the awareness and recognition of workers was very low, education was not being conducted properly. The dental laboratories(rooms) of the compact characteristics of the MSDS was not reasonably accessible and the furnishing location, dental laboratories(rooms) for the real item was needed for improvement. MSDS for dental technicians through education and promotion of information about chemicals and chemicals was to prevent health problems caused by the MSDS that will raise awareness of the necessity.

• The Journal of the Korea Contents Association
• /
• v.18 no.11
• /
• pp.540-549
• /
• 2018

This study was conducted on 238 dental hygienists working in Daegu and Gyeongbuk area. In order to understand the status of harmful transmission of dental materials by type of work, we compared the differences in exposure time and work environment characteristics of hospital types and investigated the difference in the degree of recognition of material safety data. The results of the study were as follows: In case of hospitals, the exposure time of dust generated from chemicals was the longest. Resin filling, contact with disinfectant. 37 workers (29.4%) and 14 workers (12.5%) answered that they perceive the question about whether they are aware of the material safety data sheet (MSDS) for dental materials. There were 18 hospital workers and 6 clinic workers who had experience reading MSDS before using dental materials. The respondents who answered that they provided the material safety data of the dental materials used had a 2.39 times MSDS in hospital workers. Therefore, by recognizing the health hazards of chemical substances in accordance with the characteristics of each type of hospital and continuing to conduct health and safety education, the work environment should be improved by establishing proper recognition of MSDS information. It suggests the necessity of a system that can strengthen the management of chemical information provision and guarantee the strategic approach and workers' right to know.

• Journal of Korean Society of Occupational and Environmental Hygiene
• /
• v.28 no.1
• /
• pp.91-99
• /
• 2018

Objectives: From a policy perspective, the introduction of confidential information reviews is a vital task for expanding workers' right to know and improving hazardous materials information communication. In this study, rational methods for introducing and administering confidential information reviews were examined as a part of advancing chemical information communication. Methods: The domestic status, social demands, and control cases from other countries about confidential information in material safety data sheets(MSDSs) were all examined. Additionally, principles for introducing MSDS confidential information review, what needs to be revised prior to its introduction, and procedures and manners of reviewing confidential information were suggested. Results and Conclusions: When composition information on MSDS needs to be protected in the EU and Canada, confidential information should be claimed and then approved by competent authorities with a principle of reviewing confidential information prior to rescinding information from MSDS. Applying the same principle, certain information on an MSDS that needs to be protected should be reviewed and approved in Korea. As a result, the MSDS is communicated with approval numbers replacing composition information. MSDS confidential information review has five steps, including deciding whether chemicals claimed to be confidential are excluded from applying for a confidentiality exemption, the names and concentration ranges of ingredients are adequate, and the claimed information is valid in terms of confidentiality.

• Korean Journal of Hazardous Materials
• /
• v.6 no.2
• /
• pp.87-94
• /
• 2018

The study is aimed to analyze the MSDS awareness as per the properties, including general characteristics, of laboratory workers in university. It conducted the self-administered survey on the subject of 780 laboratory workers engaging in research activities in three university from February to May, 2017. Among them, it analyzed 686 cases except 94 of them, lacking content. As a result, education experience of MSDS, necessity of education, usage experience of MSDS, installation, comprehension, and accessibility showed a strategically significant difference in the recognition of MSDS. According to the categorical importance of MSDS, "the first aid measures" directly related to life was most significantly considered. It is estimated that it will contribute to prevention of safety accident by strengthening education on MSDS and increasing the level of awareness for laboratory workers.

• Proceedings of the Korea Contents Association Conference
• /
• 2017.05a
• /
• pp.295-296
• /
• 2017

본 연구는 대구 경북지역에 근무하는 치과위생사 238명을 대상으로 병원유형에 따른 물질안전보건자료(MSDS)의 인식정도를 조사하였다. 연구결과 병원급과 의원급에 대한 의식이 통계적으로 유의한 차이가 있는 것으로 나타났으며, 전체적으로도 MSDS인식정도가 높지 않았다. 치과근로자들의 근로환경 질의 향상을 위하여 소규모 치과의원에 대한 더욱 적극적인 홍보 및 교육이 필요하며, 구체적인 정책 및 제도가 마련되어야 할 것이라 사료되어 진다.