• 한국산업보건학회지
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• 제21권3호
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• pp.128-138
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• 2011

Objectives: It has been pointed out that there are problems in handling and managing chemicals due to trade secrets of Material Safety Data Sheet(MSDS). To date, some company intentionally leave out of several parts and use an inaccurate expression in MSDS. In particular, with the result of the inspection of the government and labour community, it is required that the 2nd section in MSDS included the composition and information on ingredients has to be provided with comprehensive expression to secure more reliability. Methods: Therefore, this study is aimed: 1) to recognize the current status of trade secrets of MSDS in workplaces with both domestic manufacturers of chemical products and multinational corporations; 2) to make contributions to prevention of the industrial accidents by providing the accurate information of MSDS; 3) to improve the risk communication system related with chemicals; 4) to impress workers on the importance of right of known for MSDS. With the result we analyzed the status of trade secrets in MSDS in 73 companies, such as petrochemistry production, paint production, metal processing oil production, detergent production, and international company related with chemicals, we have found that 38,150 (45.5%) have the trade secrets parts in the total number of 83,832 in MSDS. Also, based on the 288 MSDS gathered by the Occupational Safety and Health Research Institute (OSHRI) from 2005 to 2009, 41.7% of the MSDS are classified into the trade secrets. Conclusions: Therefore, to procure an assurance system of MSDS, we suggest that a MSDS picking up and checking system be legislated in the Occupational Safety and Health Act to protect workers from the unidentified chemical hazards due to the secret trade of MSDS.

• 한국재난관리표준학회지
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• 제3권2호
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• pp.27-32
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• 2010

자체방제계획서는 위험물질의 등급, 주위환경의 피해, 사고대응계획 등으로 구성된 체계적인 관리제도이다. 자체 방제계획서 작성지원 프로그램의 개발 목적은 사고를 예방하고, 사고를 제어할 수 있도록 안전관리 시스템을 각 시설에 제공하는 것이다. 이 프로그램은 MSDS(Material Safety Data Sheet), SOP(Standard Operation Procedure), ERP(Emergency Response Plan) 등 일반적인 안전관련 자료를 포함하고 있다. 자체방제계획서는 위험 확인, 평가, 예방 계획, 안전 분석 등으로 구성되어있다. 또한, 자체방제계획서 작성지원 프로그램은 정부 또는 관련 기관이 중소기업에서 발생 가능한 사고를 관리하는데 유용하다.

• 한국재료학회지
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• 제31권2호
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• pp.68-74
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• 2021

Zinc-ion Batteris (ZIBs) are recently being considered as energy storage devices due to their high specific capacity and high safety, and the abundance of zinc sources. Especially, ZIBs can overcome the drawbacks of conventional lithium ion batteris (LIBs), such as cost and safety issues. However, in spite of their advantages, the cathode materials under development are required to improve performance of ZIBs, because the capacity and cycling stability of ZIBs are mainly influenced by the cathode materials. To design optimized cathode materials for high performance ZIBs, a novel manganese oxide (MnO2) coated graphite sheet is suggested herein with improved zinc-ion diffusion capability thanks to the uniformly decorated MnO2 on the graphite sheet surface. Especially, to optimize MnO2 on the graphite sheet surface, amounts of percursors are regulated. The optimized MnO2 coated graphite sheet shows a superior zinc-ion diffusion ability and good electrochemical performance, including high specific capacity of 330.8 mAh g-1 at current density of 0.1 A g-1, high-rate performance with 109.4 mAh g-1 at a current density of 2.0 A g-1, and remarkable cycling stability (82.2 % after 200 cycles at a current density of 1.0 A g-1). The excellent electrochemical performance is due to the uniformly decorated MnO2 on the graphite sheet surface, which leads to excellent zinc-ion diffusion ability. Thus, our study can provide a promising strategy for high performance next-generation ZIBs in the near future.

• 한국산업보건학회지
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• 제26권4호
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• pp.404-410
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• 2016

Objectives: This study aimed to examine and analyze the material safety data sheet(MSDS) information for photoresist chemicals used in certain processes in semiconductor plants. Methods: After collecting MSDS for 178 chemical products currently used in certain processes in semiconductor plants, we analyzed Sections 2, 3, 11, and 15 of each MSDS with reference to the guidelines for evaluating the reliability of MSDS provided by the Korea Occupational Safety and Health Agency. In addition, we reviewed the recorded uses and the ratios of trade secrets. Results and Conclusions: We studied a total of 178 chemical products. An MSDS was available for 176(98.9%) of them and all adhered to the Globally Harmonized System(GHS) regulations. There were 37 cases of errors in Hazard Identification, pertaining to 20.8% of all products surveyed. There were 64 cases of errors in the current legal circumstances, pertaining to 36.0% of all products. There were a total of 407 trade secrets across 52.2% of products. We believe that a government-led education and certification system needs to be introduced to improve the transfer of MSDS information. The government, chemical manufacturers and suppliers all need to make an effort to produce reliable MSDS.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 1998년도 가을 학술발표대회 논문집(III)
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• pp.809-814
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• 1998

Recently many cases that using strengthening method with a steel plate or carbon-fiber sheet in a construction field are increasing. In this reason, it is demanded that developing a plan of preventing delamination of strengthening material. So in this research, for the case of strengthening method of steel plate, it is made use of notch and anchor bolt and for the case of carbon fiber sheet, it is made use of notch, anchor bolt, line anchor and shear strengthening. After all the cases were applied, we made 15 specimen beams. The beams was measured and analyzed about the behavior property of strengthened beams, the ability strengthening method, the relation between load and the shape of failure, the crack load, the yield load, the shape of crack pattern, the increasing rate from yield load and maximum load and the strain of rebar. All the strengthening methods results in almost same value until the yield load, and it wasn't quite different from the theoretical value. But for the case of increasing rate from the yield load and maximum load, comparing with the existing method, the new strengthening methods are proved to be profitable about the safety.

• 한국안전학회지
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• 제14권4호
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• pp.53-59
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• 1999

Recently, Tailor Welded Blank (TWB) is widely used in automotive industry since the transformation characteristic of its material can be changed. However, clearance between welding surfaces becomes the important factor which affect the quality of the laser weld, causing difficulties in preparing the sheet. The objective of this paper is to systematically evaluate the effects of previously presented fracture criterion and shearing condition on precise mechanical shearing simulation result. For this purpose, a parametric study was peformed to investigate the effect of finite element size and fracture criterion on simulation result. Also, in order to predict the optimum shearing condition, effect of shearing conditions such as clearance and punch radius on the shear plane shape was evaluated.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2006년도 추계 학술발표회 논문집
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• pp.649-652
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• 2006

The exist waterproofing membrane cause not to assure proper thickness in constructing. It become a serious problem which as decreasing of durability, waterproofing membrane to be tom and break down. Therefore, it is necessary that the expert have to construct waterproof works,, if not, it can be frost and thawing or chemical corrosion called one of the reason in maintaining the safety of concrete structure. In summarize, for this paper, it would be understand that exposed and compound experimental study of waterproofing sheet using coat material filling into the protuberance to improve the durability for concrete structure can widely apply to field to solve the these significant problem.

• 한국기계가공학회지
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• 제19권11호
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• pp.102-108
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• 2020

The demand for lightweight materials and high-strength steel has rapidly increased to help reduce the weight of a vehicle body; it improves the fuel efficiency of automobiles and provides passenger safety. Additionally, as the material becomes thinner, the demand for its resistance against corrosion becomes higher. Hence, the application of the surface-treated steel sheet has surged rapidly. In this study, a weld bonding experiment using a delta spot welding machine is performed on a thin sheet of a different material (Al6061-T6/GA440). The thickness of the material was kept at 1 mm to reduce the weight of the automobile body parts. Additionally, the purpose of this study is to control the heat input by applying the welding conditions of a multi-stage pressure pattern to improve corrosion resistance shear strength. The analysis of nugget diameter measurement, shear tensile test, and salt spray test was performed to achieve the aim.

• 대한치과기공학회지
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• 제38권3호
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• pp.209-216
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• 2016

Purpose: The purpose of this study is to discover the recognition of dental technicians on MSDS and to research the furnishing rate of Material Safety Data Sheet (MSDS) in dental laboratories. Method: 104 dental technicians who were self-written questionnaire. The results were analyzed by SPSS 12.0. The answers to the questionnaire underwent frequency analysis, chi-square test were performed. Results: The result of cross analysis on the occurrence of occupational diseases according to whether MSDS is furnished showed that the group with MSDS furnished had 37.8% of damages due to their occupation, but the group with MSDS unfurnished had 65.7% of damages due to their occupation, which displayed a significant difference(p<0.05). The result of cross analysis on whether the education about chemicals according to whether MSDS is furnished showed there were relatively more responses of no education on the types and characteristics of chemicals, the effect on human body and its risk, emergency measure when exposed to risk, the treating and storing methods and the disposal methods. In addition, there were significant differences on whether all the above education was done between the group with MSDS furnished and the group without MSDS(p<0.000). Conclusion: In order to secure safe working environment of dental technicians and to reduce occurrence of damage caused by chemicals, the related education is necessary. The recognition of dental technicians on MSDS and furnishing rate is increasing but still insufficient, so the related organizations need to establish education and PR measures for prevention of damage.

• 한국환경보건학회지
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• 제27권4호
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• pp.85-91
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• 2001

The regulation of Material safety data sheets(MSDS) was required for the chemicals in use in the workplace from July 1976. Under the provisions of the workplace hazardous materials information system, employers in Korea must be provided with accurate and comprehensive MSDS. To examine the reliability of MSDS for organic solvents, 63 organic solvents and MSDS were collected from the workplace of 39 companies located in Kyonggi province. Manufacture\`s MSDS were compared with the actual composition of the collected samples, and further examined the reliability by checking whether the chemicals analyzed were included in the MSDS correctly. 38 solvents were able to analyze their composition by gas chromatography-mass selective detector(GC-MSD). Among them, 28 solvents were incorrect in their composition and contents. In some case, health hazardous or carcinogenic chemicals which were not included in the MSDS were detected from samples. As a result of evaluating whether the MSDS correspond to the regulation required by Industrial Safety and Health Act (ISHA), the information in the MSDS including hazard classification, occupational exposure level, toxicity, regulatory information were incorrectly provided, and some MSDS did not disclose carcinogenic in their MSDS, and some MSDS were not written in the standard format. From this survey, continuous monitoring and promoting correct MSDS, and analyzing the components of the solvents were required to endure the reliability of MSDS for organic solvents.