• Title/Summary/Keyword: Material Recycle

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Manufacture of Nano-Sized Ni-ferrite Powder from Waste Solution by Spray Pyrolysis Process (분무열분해 공정에 의한 폐액으로부터 니켈 페라이트 나노 분말 제조)

  • Yu Jae-Keun;Suh Sang-Kee;Kang Seong-Gu;Kim Jwa-Yeon;Park Si-Hyun;Park Yaung-Soo;Choi Jae-Ha;Sohn Jin-Gun
    • Resources Recycling
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    • v.12 no.4
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    • pp.20-29
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    • 2003
  • In order to efficiently recycle the waste solution resulting from shadow mask processing, nano-sized Ni-ferrite powder was fab-ricated through spray pyrolysis process. The average particle size of the powder was below 100nm. In this study, the effects of the reaction temperature. the concentration of raw material solution and the injection speed of solution on the properties of powder were respectively investigated. As the reaction temperature increased from $800^{\circ}C$ to $1100^{\circ}C$, average particle size of the powder significantly Increased and power structure became more solid, whereat its specific surface area was greatly reduced. Formation rate and crystallization of($NiFe_2$$O_4$) phale increased along with the temperature rise. As the concentrations of iron and nickel components in wastere solution increased, particle size of the powder became larger, particle size distribution became more irregular, and specific surface area was reduced. Formation rate and crystallization of $NiFe_2$$O_4$ phase increased significantly along with the increase of the concentration of solution. As the inlet speed of solution increased, particle size of the powder became larger, particle size distribution became wider, specific surface area was reduced and powder structure became less solid. As the inlet speed of solution decreased, formation rate and crystallization of $NiFe_2$$O_4$ phase significantly increased.

An analysis of the properties of mortar according to the change of the replacement rate of waste foundry sands (폐주물사의 치환율 변화에 따른 모르타르의 특성 분석)

  • Ryu, Hyun-Gi;Kwon, Yong-Ju
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.4 no.4
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    • pp.99-104
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    • 2009
  • For recycling of waste foundry sands, researchers recently try to recycle them rather than depend on reclamation, and are studying on how to combine waste foundry sands with cement and use them for various kinds of construction material as the effective recycling method of waste foundry sand. In this research, The ways to find the proper replacement rate of waste foundry sands and to make use of them were suggested through the experiments on the range to apply waste foundry sands with two levels of 1:3 mixture rate of W/C 43% and 50%. The research result showed that in terms of liquidity as the characteristic of unhardened mortar, as the replacement rate of waste foundry sands increased, its flow tended to decrease. The amount of air also displayed a similar tendency to that of liquidity in that the higher the replacement rate of waste foundry sands became, the lower it became. With regard to the solidity trait of hardened mortar, it increased when the waste foundry sands were replaced more, and the replacement of waste foundry sands caused increased initial solidity. As for the amount of water permeated and that of water absorbed as the water tight proofing properties, the amount of permeated water was proved to decrease because of the gap recharge effect by the fine powder of waste foundry sands, and the replacement of waste foundry sands in the structures requiring watertightness is concluded to be very effective.

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Evaluation for Applicability as the Inorganic Binder with Rapid Setting Property for Construction Material of LFS Produced from Various Manufacturing Process (다양한 철강제조공정에서 부산되는 전기로 환원슬래그의 급경성 무기결합재로의 적용성 검토)

  • Kim, Jin-Man;Choi, Sun-Mi;Kim, Ji-Ho
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.7 no.2
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    • pp.70-77
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    • 2012
  • The Ladle Furnace Slag, about 20% of the electric arc furnace slag, has high content of free CaO and free MgO, which generates the expansion collapse by hydration reaction. Although many researchers have been endeavoring to recycle the EAF reducing slag in construction fields, there is not found the effective recycling method up to now. However, the LFS(Ladle Furnace Slag) contains mineral composition of the system of calcium aluminate with high-reactivity. Therefore, it is possible to developed the quick setting property and the high strength at the early age by the rapid cooling. This study aimed to check the reactive minerals and predict the reactivity with water on the LFS discharged from different steel product plants. The test results show that many types of LFS has hydration reactivity and can use in construction field as a inorganic binder with the rapid setting property.

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Flexural Behavior of RC Beam Using High Volume Fly-Ash Cement (다량치환된 플라이애시 시멘트를 사용한 철근콘크리트 보의 휨거동)

  • Ahn, Young-Sun;Cha, Yeong-Dal
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.2 no.2
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    • pp.128-136
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    • 2014
  • It is known that the best way to recycle fly ash is to use in concrete. It is impossible to bury in the ground this fly ash recently, so it is trying to use high volume fly ash concrete. Nevertheless, recent main research topics are focused in the part of material only. However, it is necessary to perform the researches about elasticity modulus, stress-strain relationship and structural behavior. Therefore, in this paper, 18 test members were manufactured with 3 test variables, namely fly ash replacement ratio 0, 35, 50%, concrete compressive strength 20, 40, 60MPa and 2 tensile steel ratio. 18 test members were tested for flexural behavior. From the test results, there were no differences between 35, 50% high volume fly ash cement concrete and ordinary concrete without fly ash (FA=0%). In order to evaluate the HVFAC flexural behavior, Analytical model was proposed and the computer program was developed. There were no differences between test results and analysis results. So, the proposed analytical model was reasonable.

Evaluation of Domestic CCPs(Coal Combustion Products) Quality by API Test Method (API시험법에 의한 국내 석탄회의 품질 평가)

  • Yoo, Sung-Won;Yu, Kyung-Geun;Cho, Young-Keun
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.1 no.1
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    • pp.49-57
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    • 2013
  • Recently, recycling of industrial by-products and CO2 reduction have been important issues in the world. In this reason, applications and reuse of Fly ash as a binder for concrete, which is generated in thermoelectric power plant, have been one of the effective recycle methods. In order for Fly ash to be applied to concrete, Korean Standard(KS) has selected and managed quality such as $SiO_2$, fineness, specific gravity, ignition loss and activity index. However, there is a limits for activity index, whose test period required is at least 28 days or 91 days. Activity index is the critical indication standard to determine mechanical strength of concrete that contained Fly ash. To complement the disadvantage of test method, this research provided "API test method", which quickly measure Pozzolanic reaction of Fly ash can be considered as a alternative of activity index. Then, the adaptable API test method need to be investigated through comparative analysis with the test result of API, activity index and K-value. The test method can make evaluation of Fly ash quality faster and more accurate. As a result, most Fly ash produced in Korea has not been satisfied in the KS quality standard except water content and specific gravity, and especially fluidized bed boiler ash has its characteristics. Also, API, activity index and K-value have superior interrelationship. The interrelationship between API and activity index and K-value gets increased as the material age gets higher, so API test can be considered as very useful test method for Pozzolanic reaction evaluation of Fly ash.

Effects of pig manure composts with different composting periods on feeding rate, biomass and cocoon production of earthworm(Eisenia fetida) (돈분 퇴비의 부숙기간이 줄지렁이의 섭식률, 생체량 및 산란율에 미치는 영향)

  • Bae, Yoon-Hwan;Park, Kwang-Il
    • Journal of the Korea Organic Resources Recycling Association
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    • v.21 no.2
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    • pp.79-87
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    • 2013
  • Effects of pig manure with various composting periods(0, 15, 30, 50, 80 days) on feeding rate, biomass, cocoon production of earthworm(Eisenia fetida) population and physicochemical property of vermicast produced from pig manure were investigated. The feeding rate of earthworm was increased with longer composting period of pig manure. But the biomass production of earthworm population was highest upon the pig manure composted for 30 days. Upon the pig manure composted for 80 days, the biomass was severely reduced. Cocoon production was decreased with longer composting period and especially lower on the pig manure composted for 80 days. Values of pH, EC, C/N ratio of vermicasts produced from pig manure composts were lower than those of pig manures. And the organic material contents of vermicasts were uniformly reduced irrespective of composting duration of pig manure, whose values were 35.9-39.8%. From these results, the optimum composting period of pig manure for vermicomposting could be 15-30 days. And the application of vermicomposting upon the composted pig manure could be an efficient way for the treatment of pig feces, which can stabilize and recycle the organic wastes more rapidly than the conventional composting method.

Principle and Application of Composting for Soils Contaminated with Hazardous Organic Pollutants (오염토양 정화를 위한 콤포스팅 기술의 원리와 적용에 관한 고찰)

  • Park, Joon-Seok;Lee, Noh-Sup;In, Byung-Hoon;Namkoong, Wan;Hwang, Eui-Young
    • Journal of the Korea Organic Resources Recycling Association
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    • v.9 no.3
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    • pp.77-87
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    • 2001
  • Composting is a cost-effective and environmentally-sound technology to treat soils contaminated with hazardous organic pollutants. Pollutants to be treated are as follows: explosives, phenolic compounds, PAHs, petroleum hydrocarbons, pesticides, and etc. Composting systems are windrow, static pile, and in-vessel. Design and operational parameters of composting are aeration modes, temperature, moisture content, nutrient supplement, amendment added, and etc. Appropriate oxygen concentration of composting for contaminated soils are 5~15%, while some compounds are degraded well at the low $O_2$ concentration of 2~5%. The most diverse microorganisms live in the temperature of $25{\sim}40^{\circ}$. 50~90% of the soil field capacity is the moisture content not to make a problem in composting. Assuming a bacterial chemical equation is $C_{60}H_{87}O_{23}N_{12}P$, theoretical C : N : P from bacterial chemical portion is approximately 20 : 5 : 1. It should be noted that the ratio does not apply to the total organic carbon measured in a waste because not all carbon metabolized by bacteria is synthesized to new cellular material. Initial C/N ratio of 25~40 is optimum. It is more economical to recycle soils or composts than to add commercial microbes.

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Life Cycle Assessment of Part Reuse/Recycling in the End-of-Life Stage of Personal Computers (부품 재사용 여부에 따른 폐컴퓨터에 대한 전과정평가(LCA))

  • Lim, Hyeong-Soon;Yang, Yun-Hee;Song, Jun-Il;Lee, Kun-Mo
    • Journal of Korean Society of Environmental Engineers
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    • v.28 no.5
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    • pp.494-500
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    • 2006
  • Life Cycle Assessment(LCA) is an environmental assessment tool for evaluating environmental burdens associated with products, processes and activities from the raw material acquisition stage to the end-of-life stage. End-of-life stage as well as other processes requires a reliant database in order to increase the confidence in the LCA results. In this study, the flow of Personal Computer(as PC) in the end-of-life stage was examined and the database of two scenarios has been established, i.e. one is part reuse and the other is no part reuse, in the end-of-life phase of PC. Also, key environmental issues were identified by carrying out LCA on a PC in the end-of-life phase for eight environmental impact categories. The 'ozone layer depletion' contributes the highest environmental impact due to generation of $Cl_2$ gas during the incineration of waste plastics. In addition, the scenario 1(part reuse) is more environmentally sound than the scenario 2(no part reuse) when comparing two scenarios.

A Study on the Fundamental Properties of Ultra Rapid Hardening Mortar using Coal-Ash (잔골재 대체재로서 석탄회를 이용한 초속경 보수모르타르의 기초적 특성에 관한 연구)

  • Lee, Gun-Cheol;Oh, Dong-Uk;Kim, Young-Geun;Cho, Chung-Ki
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.6 no.1
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    • pp.128-135
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    • 2011
  • In this study, in order to develop ultra rapid hardening mortar(URHM) for tunnel repairs using bottom ash of low recycle ratio and Admixture as Eco concept, fundamental properties of URHM on temperature condition of construction field were performed. Test result, URHM of three types for fluidity and setting time were as in the following : B > C > A. Those for low temperatures were later than the standard condition. Compressive, bending and bond strength were similar with three types as follow. In compressive strength, initial strength of the low were smaller than the standard but the low in the long-term were similar with the standard. On the contrary to this, bending strength were similar in initial strength but the low in the long-term were smaller than the standard. The low in bond strength was average 35% less than the standard. Length changes was as in the following : A > C > B. the low is two times much as the standard but the case using blast furnace slag particles noticeably reduced length changes. Water absorption coefficient and water vapor resistance were as in the following : C > A > B. In case of URHM added bottom ash, water absorption coefficient and water vapor resistance were increased because bottom ash is porous material.

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Investigation of Characteristics of Incinerator Bottom Ash and Assessment for Recycle due to the Change of MSW Composition (생활폐기물 성상변화에 따른 소각시설 바닥재의 특성 변화와 시멘트 클링커 원료로 재활용 가능성 평가)

  • Lee, Woo Chan;Shin, Deuk Chol;Dong, Jong In
    • Applied Chemistry for Engineering
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    • v.25 no.1
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    • pp.103-106
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    • 2014
  • Recycling of bottom ash from municipal solid waste (MSW) incinerator has been strictly limited due to its composition of high level chlorine and other unfavorable substances. The composition of MSW has been, however, changed after the introduction of garbage-bag sales system, extended producer responsibility (EPR) policy and the prohibition of direct landfill of food waste. Recent waste shows reduced moisture and chlorine content, increased calorific value due to the separation of food waste, incombustible materials and PVC. The main purpose of this study is to investigate the trend of composition changes of MSW incinerator bottom ash and to compare the analytical results with those before the separation system was introduced. CaO content of bottom ash, one of the major component of cement clinker, increased from 26.7% in 2001 to 34.0% in 2006. The chlorine content showed a dramatic decrease from 1.84% in 2001 to 0.00655% in 2006, which is closely compatible with that of the fly ash of coal-utilizing thermal power plants, which is mainly due to the changes of MSW composition. It is eventually considered that there is a possibility of utilizing the incinerator bottom ash as a raw material of cement clinker feed substances.