• Composites Research
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• v.29 no.6
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• pp.395-400
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• 2016

Recently, many research groups have studied on the epoxy-based multifunctional electrolyte to develop the structural composite bearing high mechanical properties without sacrificing the ionic conductivity at the same time. The studies on the optimal content and material selection for structural electrolyte have been published, while its curing behavior has not much analyzed yet. In this study, epoxy-based structural electrolyte containing solid electrolyte was prepared by varying the curing temperature and time. In addition, the ionic conductivities and mechanical properties of specimens were measured. We also find out the optimal hardening condition where the epoxy domain enables to be hardened within the range of temperature at which the thermal decomposition of electrolyte does not occur. Finally, we propose the multifunctional structural electrolyte showing achievable electrical and mechanical properties (282 MPa and $9{\times}10^{-6}S/cm@25^{\circ}C$).

• Journal of the Korean Society of Propulsion Engineers
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• v.1 no.2
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• pp.91-102
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• 1997

In order to evaluate the effects of aging on the ignition performance, pyrotechnic igniters were separated from twelve-year-old, fifteen-year-old, and sixteen-year-old live rocket motors. The characteristic values of the ignition material were measured, and the firing tests of the igniters were performed. The moisture content, the outer dimension, the crush strength, the thermal decomposition characteristics, and the heat of formation the B/$KNO_3$ ignition pellet were measured. The crush strength was increased and the heat of formation was reduced as aged, but no change was detected for other characteristic values. The burning test results of the igniter pellet in the closed bomb and the inert motor showed that the burning rate of the ignition pellet was increased by 10%, and the integration of pressure $P_t$ of the p-t curve was reduced by 15% for aged samples. It was inferred that the burning rate was increased as the crack was appeared in the pellet and $P_t$ could be proportionally decreased with the heat of explosion.

• Steel and Composite Structures
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• v.16 no.1
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• pp.21-44
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• 2014

The aim of this study is to determine the dynamic characteristics of long reinforced concrete highway bridges with post-tension tendons using analytical and experimental methods. It is known that the deck length and height of bridges are affected the dynamic characteristics considerably. For this purpose, Berta Bridge constructed in deep valley, in Artvin, Turkey, is selected as an application. The Bridge has two piers with height of 109.245 m and 85.193 m, and the total length of deck is 340.0 m. Analytical and experimental studies are carried out on Berta Bridge which was built in accordance with the balanced cantilever method. Finite Element Method (FEM) and Operational Modal Analysis (OMA) which considers ambient vibration data were used in analytical and experimental studies, respectively. Finite element model of the bridge is created by using SAP2000 program to obtain analytical dynamic characteristics such as the natural frequencies and mode shapes. The ambient vibration tests are performed using Operational Modal Analysis under wind and human loads. Enhanced Frequency Domain Decomposition (EFDD) and Stochastic Subspace Identification (SSI) methods are used to obtain experimental dynamic characteristics like natural frequencies, mode shapes and damping ratios. At the end of the study, analytical and experimental dynamic characteristic are compared with each other and the finite element model of the bridge was updated considering the material properties and boundary conditions. It is emphasized that Operational Modal Analysis method based on the ambient vibrations can be used safely to determine the dynamic characteristics, to update the finite element models, and to monitor the structural health of long reinforced concrete highway bridges constructed with the balanced cantilever method.

• Journal of the Microelectronics and Packaging Society
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• v.24 no.1
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• pp.67-73
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• 2017

An analysis of thermal degradation of epoxy based adhesive performed by thermogravimetry tests are presented in this study. Six different heating rates were employed for the weight change measurements. Based on the data, an Arrhenius type modeling equation was developed by calculating activation energies and proportional constants, and $n^{th}$ polynomial function was adopted to predict the weight change rates. The prediction results by the modeling was compared with the data using the average activation energy. It was found that the activation energy at the each heating rate was not same due to the different degradation kinetics, especially at the high heating rate. To overcome this pitfall, a new approach using exponential function series was introduced and employed. The calculation results showed very good agreements with the test data regardless of the heating rates.

• Applied Chemistry for Engineering
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• v.29 no.4
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• pp.468-473
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• 2018

In this study, the reforming reaction of vacuum residues (VR), high viscosity oil residues produced from vacuum distillation process of petroleum oil, was carried out using catalytic aquathermolysis reaction. VR showed a prone to decrease the amount of resins and asphaltenes in the constituents, and to increase saturates and aromatics when reacting with steam at 30 bar and above $300^{\circ}C$ for 24 h. When the amount of steam is not enough at this reaction, the asphaltene content in the products was rather increased after the reaction. As a result of the catalytic aquathermolysis using the metal oxide-zeolite catalyst with the decaline as a hydrogen donor, a 10% decrease in resin and asphaltene as well as a 10% increase in the aromatic hydrocarbon were observed. Consequently, the viscosity of VR decreased by 70% after the reaction. GC-Mass spectroscopy showed that the aquathermolysis of VR resulted in the decomposition of the resins and asphaltens into a low molecular weight material.

• Applied Chemistry for Engineering
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• v.31 no.3
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• pp.317-322
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• 2020

Hydroxylammonium nitrate (HAN; NH₃OHNO₃) is an ionic energy material having a low melting temperature and vapor pressure with a high oxygen balance. To utilize it as an oxidizer for a high content liquid mono-propellant, a dual solvent was used to obtain HAN in a solid particulate form. The dehydrated crystal from an aqueous HAN was washed with dual organic solvents including acetone and ethanol, finally resulting in the moisture content of 13.8 wt%. When acetone was applied as a single solvent, the maximum synthesis yield of 88%, the HAN content evaluated by TGA of 86.2%, and the decomposition temperature ranged 160℃ to 205℃ were achieved.

• Proceedings of the Korea Society for Energy Engineering kosee Conference
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• 2007.11a
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• pp.187-192
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• 2007

A project is being implemented to develop the long distance energy transport technology using the chemical reactions. This project can be classified into three main research categories covering heat recovery reaction, long distance energy transport, and heat generation reaction. In this study, the methanol is selected as a system material since it shows several unique superior characteristics as follows: gaseous state of reactant and product, large heat of reaction, high yields of reaction at relatively low temperature, and also steady and economical supply. Furthermore, it is anticipated that the outcomes of this study can be widely applied to the related industries. A feasibility study was carried out to evaluate the economics of this technology which study was based on the following case: 10,000 households, 15km distance energy transportation, utilization of waste heat from power plant.

• Journal of the korean society of oceanography
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• v.35 no.1
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• pp.16-33
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• 2000

In order to measure the vertical fluxes of particles and reactive radionuclides such as thorium and polonium isotopes, Dunbar-type sediment traps were freely deployed at the Ulleung Basin and in warm and cold water masses around the polar front of the East Sea. We estimated the ratios of the catched (F) to the predicted $^234$Th fluxes (P) using natural tracers pair $^234$Th-$^238$U. The F/P ratios are decreased with increasing water depth. Whereas the concentrations of suspended particles are homogeneous in water column, the mass fluxes are also decreased with increasing water depth like the F/P ratios. These facts indicate that organic matters of settling particles are destructed within the euphotic layer due to decomposition. Whereas regenerations of sinking particles are negligible in the cold water mass, about 80% of them are regenerated in the warm water mass during falling of large particles. These downward mass fluxes are closely correlated with their primary productions in euphotic zone. The activities of $^234$Th, $^228$Th and $^210$Po in the sinking material were increased with water depth. Because $^234$Th steadily produced in the water column are cumulatively adsorbed on the surface of sinking particles, vertical $^234$Th fluxes were observed to increase with water depth. Therefore, these sinking particles play important roles in transporting the particle reactive elements like thorium from surface to the deep sea. The scavenging processes including adsorption and settling reactions generate radio-disequilibrium between daughter and parent nuclides in water column. The activity ratios of $^234$Th/$^238$U and $^228$Th/$^228$Ra were observed to be < 1.0 in the surface water and approached to be equilibrium below the thermocline. The extent of the deficiency of daughter nuclides compared to the parents nuclide was highly correlated with the vertical particle flux. Because most of the $^210$Po in the surface water are scavenged on a labile phase and are recycled at sub-surface depths (< 200 m), the $^210$Po are always observed to be excess activities compared to $^226$Ra in surface water.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.10 no.3
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• pp.226-232
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• 2000

Corrosion mechanisms by molten steel and slag were investigated in the zirconia/graphite composite as a material of submerged entry nozzle (SEN) using for producing high quality steel. Most of corrosions were started by the dissolution of zirconia particles into molten steel and oxidation of graphite, but subsequently three modes of corrosion were observed. Firstly, the penetration of slag into zirconia matrix was induced to the diffusion of stabilizing agent outward cubic zirconia grains, and the destabilization of cubic to fine monoclinic zirconia particles, which is enhanced to the decomposition and dissolution of them into slag. Secondly, molten slag penetrates into large cubic zirconia particles along grain boundary and decomposed them to fine cubic grains, which is also enhanced to the dissolution of zirconia grains into slag. Lastly, reaction between carbon and cubic zirconia was formed porous ZrC and enhanced the dissolution of it into slag.

• Journal of the Korean Society of Safety
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• v.24 no.3
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• pp.54-58
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• 2009

A substitute energy development has been required due to the exhaust of the fossil fuel and an environmental problem. Consequently, possible technologies producing hydrogen from water that does not release carbon is a very promising technology. Also, Iodine-Sulfur(IS) thermochemical water decomposition is one of the promising processes that are used to produce hydrogen efficiently using the high temperature gas-cooled reactor(HTGR) as an energy source that is possible to supply heat over 900$^{\circ}C$. In this study, to make a initiating events identification for the IS process, Master Logic Diagram(MLD) is used and 9 initiating events that cause a leakage of the chemical material are identified. Also, 6 events are identified among 9 initiating events above and are quantified using event tree.