• Title/Summary/Keyword: Material Decomposition

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Study on $H_2$ Sensing Characteristics of Gas Extractor for Dissolved Gas in Oil (유중 가스 검출장치의 수소 가스 감지 특성에 관한 연구)

  • Hwang, Kyu-Hyun;Seo, Ho-Joon;Rhie, Dong-Hee
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.07b
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    • pp.1162-1165
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    • 2004
  • In oil-filled enuipment such as transformers, partial discharge or local overheating will precede a final shutdown. Accompanied with such problems is a decomposition of insulating material into gases, which are dissolved into the transformer oil. The gases dissolved in oil can be separated with some membranes based on the differences in permeability of membranes to different gases. This paper discuss the permeability characteristics of several membranes for separation hydrogen gas in oil. With result of this paper, it may become possible to detect fault-related gases from transformer oil and predict incipient failures in the future.

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Analysis of Thermo Chemically Decomposing Composites for Rocket Thermal Insulators (로켓 방화벽용 열경화성 복합재의 거동해석)

  • Lee, Sunpyo;Lee, Jung-Youn
    • Journal of the Korean Society of Propulsion Engineers
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    • v.5 no.4
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    • pp.1-11
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    • 2001
  • A theory for time-dependent, high temperature ablation of poroelastic carbon composite insulators is applied using finite element methods to determine material properties from experimental data. The theory contains important revisions to that in Lee, Salamon and Sullivan[1] by making a sharp distinction between Biots constants and permeability and setting both to analytical functions of porosity. The finite element program and material modeling has been modified to (1) more closely adhere to porous-material theory, (2) include a newly discovered analytical simplification and (3) refine the material property descriptions. Application to experimental problems and comparisons with data permit determination of Biots constants and permeability and their evolution with respect to matrix decomposition and clearly show how material parameters affect the material response, e.g., amplitude and the location of peaks with respect to temperature. In particular, the response is very sensitive to permeability and dominated by it.

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Slurry Phase Decomposition of Food Waste by Using Various Microorganisms (미생물을 이용한 액상소멸방식의 음식물쓰레기 처리)

  • Kwon, Bum Gun;Na, Suk-Hyun;Lim, Hye-Jung;Lim, Chae-Sung;Chung, Seon-Yong
    • Journal of Korean Society of Environmental Engineers
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    • v.36 no.5
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    • pp.303-310
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    • 2014
  • This study investigated the reduction of food waste through the slurry phase decomposition in a source of food waste by microorganisms. The reactor used in the experiment was composed of both woodchip with wood material and sponges with polyurethane material as media of attached microorganisms, and food waste was mixed with a constant cycle consisted of a stirring device. During the experimental period of 100 days, the change in weight over the cumulative total amount of food waste added was reduced by 99%. Approximately, 1% of the residual food waste could be inherently recalcitrant materials (cellulose, hemicellulose, lignin, etc.) and thus was thought to be the result of the accumulation. The initial pH in wastewater generated from food waste was low with 3.3 and after 24 hours treatment this pH was increased to 5.8. The concentrations of COD, BOD, SS, salinity, TN and TP were gradually decreased. Food waste decay was proceeded by the seven species microorganisms identified and confirmed in this study, making a slurry phase and thus reducing residual food wastes. In the initial phase, the microbial population was approximately $3.3{\times}10^4$ cell/mL, and after 15 days this population was a constant with $5.1{\times}10^6$ cell/mL which means a certain stabilization for the reduction of food wastes. From these results, it can be considered that organic matter decomposition as well as the weight loss of food wastes by microorganisms is done at the same time.

A study on the pyrolysis of lithium carbonate for conversion of lithium hydroxide from lithium carbonate (탄산리튬으로부터 수산화리튬 전환을 위하여 탄산리튬의 열분해에 대한 연구)

  • Park, Jae Eun;Park, Min Hwa;Seo, Hyeong Jun;Kim, Tae Seong;Kim, Dae Weon;Kim, Bo Ram;Choi, Hee Lack
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.31 no.2
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    • pp.89-95
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    • 2021
  • Research on the production of lithium hydroxide (LiOH) has been actively conducted in response to the increasing demand for high nickel-based positive electrode materials for lithium-ion batteries. Herein we studied the conversion of lithium oxide (Li2O) through thermal decomposition of lithium carbonate for the production of lithium hydroxide from lithium carbonate (Li2CO3). The reaction mechanism of lithium carbonate with alumina, quartz and graphite crucible during heat treatment was confirmed. When graphite crucible was used, complete lithium oxide powder was obtained. Based on the TG analysis results, reagent-grade lithium carbonate was heat-treated at 700℃, 900℃ and 1100℃ for various time and atmosphere conditions. XRD analysis showed the produced lithium oxide showed high crystallinity at 1100℃ for 1 hour in a nitrogen atmosphere. In addition, several reagent-grade lithium oxides were reacted at 100℃ to convert to lithium hydroxide. XRD analysis confirmed that lithium hydroxide (LiOH) and lithium hydroxide monohydrate (LiOH·H2O) were produced.

Decomposition Characteristics of CF4 by SiC/Al2O3 Modified with Cerium Sulfate Using Microwave System (마이크로파를 이용한 황산세륨으로 개질화 된 SiC/Al2O3 촉매의 CF4 분해 특성)

  • Choi, Sung-Woo
    • Journal of Korean Society of Environmental Engineers
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    • v.37 no.12
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    • pp.668-673
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    • 2015
  • Alumina-based catalysts with different Ce loadings were studied in the decomposition of $CF_4$ using microwave heating system. Heating material of microwave system used Silicon Carbide. The crystallographic phases of catalysts were investigated by XRD and decomposition rates of $CF_4$ were examined by GC-TCD. The catalysts of 10 wt% Ce modified $Al_2O_3$ showed higher $CF_4$ decomposition rate than un-modified $Al_2O_3$ for $500^{\circ}C$ reaction temperature. The k value of catalysts shows the order of $Ce(20)/Al_2O_3=Ce(0)/Al_2O_3<Ce(5)/Al_2O_3<Ce(10)/Al_2O_3$. XRD patterns of $Ce(0)/Al_2O_3$ were no difference before and after the reaction and showed $Al_2O_3$ phases. With the increase in Ce loadings, $CeO_2$, $AlF_3$ of XRD peaks was observed. The results was indicated that Ce modifed $Al_2O_3$ than un-modifed $Al_2O_3$ was decreased reaction temperature to $200^{\circ}C$ with same decomposition rate. Also the appropriated cerium sulfate loadings on $Al_2O_3$ were 5~10 wt%.

Comparison of Bone Volume Measurements Using Conventional Single and Dual Energy Computed Tomography (전산화단층영상검사에서 단일에너지와 이중에너지를 이용한 뼈 부피측정의 비교)

  • Kim, Yung-kyoon;Park, Sang-Hoon;Kim, Yon-Min
    • Journal of radiological science and technology
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    • v.40 no.2
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    • pp.253-259
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    • 2017
  • The study examines changes in calcium volume on born by comparing two figures; one is measured by dual energy computed tomography(DECT) followed by applying variation in monochromatic energy selection(keV), material decomposition(MD), and material suppressed iodine(MSI) analysis, and the other is measured by conventional single source computed tomography(CSCT). For this study, based on CSCT images taken by using human mimicked phantom, 70, 100, 140 keV and MSI, MD material calcium weighting(MCW) and MD material iodine weighting(MIW) of DECT were applied respectively. Then calculated calcium volume was converted to Agatston score for comparison. Volume of human mimicked phantom was in inverse proportion to keV. The volume decreased while keV increased(p<0.05). The most similar DECT volumes were reconstructed at 70 keV, the difference was showed $35.8{\pm}12.2$ for rib, femur ($16.1{\pm}24.1$), pelvis($13.7{\pm}18.8$), and spine($179.0{\pm}61.8$). However, the volume of MSI was down for each organ; the volume of rib was 5.55%, femur(76.34%), pelvis(55.16%) and spine(87.58%). The volume of MSI decreased 55.9% for rib, femur(80.7%), pelvis(69.6%) and spine(54.2%) while MD MIW reduced for rib(83.51%), femur(87.68%), pelvis(86.64%), and spine(82.62%). With the results, the study found that outcomes were affected by the method which examiners employed. When using DECT, calcium volume of born dropped with keV increased. It also found that the most similar DECT images were reconstructed at 70 keV. The results of experiments implied that the users of MSI and MD should be cautious of errors as there are big differences in scores between those two methods.

Development and Evaluation of Predictive Model for Microstructures and Mechanical Material Properties in Heat Affected Zone of Pressure Vessel Steel Weld (압력용기강 용접 열영향부에서의 미세조직 및 기계적 물성 예측절차 개발 및 적용성 평가)

  • Kim, Jong-Sung;Lee, Seung-Gun;Jin, Tae-Eun
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.26 no.11
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    • pp.2399-2408
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    • 2002
  • A prediction procedure has been developed to evaluate the microtructures and material properties of heat affected zone (HAZ) in pressure vessel steel weld, based on temperature analysis, thermodynamics calculation and reaction kinetics model. Temperature distributions in HAE are calculated by finite element method. The microstructures in HAZ are predicted by combining the temperature analysis results with the reaction kinetics model for austenite grain growth and austenite decomposition. Substituting the microstructure prediction results into the previous experimental relations, the mechanical material properties such as hardness, yielding strength and tensile strength are calculated. The prediction procedure is modified and verified by the comparison between the present results and the previous study results for the simulated HAZ in reactor pressure vessel (RPV) circurnferential weld. Finally, the microstructures and mechanical material properties are determined by applying the final procedure to real RPV circumferential weld and the local weak zone in HAZ is evaluated based on the application results.

Influence of Global Climatic Changes on Wetland Biogeochemical Processes (습지의 생지화학적 반응과 전지구적 기후 변화의 영향)

  • Kang Hojeong
    • 한국생물공학회:학술대회논문집
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    • 2004.07a
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    • pp.35-45
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    • 2004
  • This paper reviewed effects of global climatic changes on wetland biogeochemistry, Wetlands play key roles in global as well as local material cycle, which includes carbon sequestration, $CH_4$ emission and DOC leaching, Increased air temperature, elevated $CO_2$ levels and changed precipitation patterns are believed to affect those processes substantially by modifying oxygen supply, carbon sources, and decomposition rates. For example, elevated $CO_2$ may increase $CH_4$ emission as well as DOC leaching from wetlands. In addition, interactions of multiple effects warrant further investigation.

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Studies on the Substances Contained in Gyrophora Esculanta Lowering Plasma and Liver Cholesterol Levels. (석이버섯 (Gyrophora Esculanta ) 중에 함유되어잇는 폐장 및 혈장 콜레스테롤의 저하생리활성물질에 관한 연구 (제 4 보))

  • 김천호
    • Journal of Nutrition and Health
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    • v.20 no.1
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    • pp.10-14
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    • 1987
  • The effect of the addition of the white powder separated from Sogi (Gyrophora esculenta) by the extraction methods with ethanol and acetone was checked by the feeding experiment in rats fed with a high cholesterol diet. From this experiment, it was confirmed that this material, which was assumed to be the mixture of gyrophoric acid and the decomposition products, could lower both liver and plasma cholesterol levels.

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Spherical Particles Formation in Lubricated Sliding Contact -Micro-explosion due to the Thermally-activated Wear Process-

  • Kwon, O.K.
    • Tribology and Lubricants
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    • v.11 no.5
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    • pp.1-9
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    • 1995
  • The mechanism of various spherical particles formation from wide range of tribo-systerns is suggested and deduced by the action of micro-explosion on the basis of the thermally-activated wear theory, in which the flash temperature at contact could be reached clearly upto the material molten temperature due to the secondary activation energy from the exothermic reactions involving lubricant thermo-decomposition, metals oxidation, hydrogen reactions and other possible complex thermo-reactions at the contacts. Various shapes of spherical particles generated from the tribosystem can be explained by the toroidal action of micro-explosion accompanied with the complex thermo-chemical reactions at the contact surfaces or sub-surfaces.