• 제목/요약/키워드: Mass transfer rate

검색결과 856건 처리시간 0.031초

Ar+O2 혼합가스 취입에 의한 용철의 탈탄 반응속도 (Decarbonization Kinetics of Molten Iron by Ar+O2 Gas Bubbling)

  • 손호상;정광현
    • 대한금속재료학회지
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    • 제47권2호
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    • pp.107-113
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    • 2009
  • Molten iron with 2 mass % carbon content was decarbonized at 1823 K~1923 K by bubbling $Ar+O_2$ gas through a submerged nozzle. The reaction rate was significantly influenced by the oxygen partial pressure and the gas flow rate. Little evolution of CO gas was observed in the initial 5 seconds of the oxidation; however, this was followed by a period of high evolution rate of CO gas. The partial pressure of CO gas decreased with further progress of the decarbonization. The overall reaction is decomposed to two elementary reactions: the decarbonization and the dissolution rate of oxygen. The assumptions were made that these reactions are at equilibrium and that the reaction rates are controlled by mass transfer rates within and around the gas bubble. The time variations of carbon and oxygen contents in the melt and the CO partial pressure in the off-gas under various bubbling conditions were well explained by the mathematical model. Based on the present model, it was explained that the decarbonization rate of molten iron was controlled by gas-phase mass transfer at the first stage of reaction, but the rate controlling step was transferred to liquid-phase mass transfer from one third of reaction time.

다중 영역법을 이용한 증발식 응축관 주위의 열 및 물질전달 해석 (Numerical study of heat and mass transfer around an evaporative condenser tube by multi-zone method)

  • 윤일철;이재헌
    • 대한기계학회논문집
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    • 제19권12호
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    • pp.3317-3328
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    • 1995
  • The objective of the present study is to predict the characteristics of heat and mass transfer around an evaporative condenser. Numerical calculations have been performed using multi-zone method to investigate heat transfer rate and evaporation rate with the variation of inlet condition(velocity, relative humidity and temperature) of the moist air, the flow rate of the cooling water and the shape of the condenser tube. From the results it is found that the profile of heat flux is the same as that of evaporation rate since heat transfer along the gas-liquid interface is dominated by the transport of latent heat in association with the vaporization(evaporation) of the liquid film. The evaporation rate and heat transfer rate is increased as mass flow rate increases or relative humidity and temperature decrease respectively. But the flow rate of the cooling water hardly affect the evaporation rate and heat flux along the gas-liquid interface. The elliptic tube which the ratio of semi-minor axis to semi-major axis is 0.8 is more effective than the circular tube because the pressure drop is decreased. But the evaporation rate and heat flux shown independency on the tube shape.

복합 건축자재의 물질전달계수를 이용한 실내 오염물질 농도 예측방법 (A prediction of indoor pollutant concentration using method mass transfer coefficient in multi-layered building materials)

  • 김창남;이윤규;이승복;김태연
    • KIEAE Journal
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    • 제7권5호
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    • pp.53-58
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    • 2007
  • In order to predict the indoor air pollutant, the VOCs emission rate is used through small chamber in the design process. However, the small chamber method has limitations as the convective mass transfer coefficient, the most important factor when predicting VOCs contamination of indoor air, is different between the small chamber result and the measured data in the actual building. Furthermore, the existing studies which analyzed mass transfer coefficient in the small chamber were directed on the small chambers developed at the time and FLEC(Field and Laboratory Emission Cell), thus, are different from the current small chamber which has been changed with improvements. The purpose of this study is to determine the emission rate of pollutant in multi-layered building materials, and predict the indoor pollutant concentration through the CFD(Computational of Fluid Dynamics) and CRIAQ2 based on the mass transfer coefficient on singled-layered building material by using the current small chamber widely used in Korea. Futhermore, this study used the new convective mass transfer coefficient(hm') which indicates the existing convective mass transfer coefficient(hm) including VOC partition coefficient(k). Also, formaldehyde was selected as target pollutant.

이액상계를 이용한 토양슬러리 반응기에서의 PAH 거동 특성

  • 이재영;백기태;조현정;양지원
    • 한국지하수토양환경학회:학술대회논문집
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    • 한국지하수토양환경학회 2003년도 추계학술발표회
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    • pp.144-147
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    • 2003
  • In this study, the mass transfer behaviors of phenanthrene, anthracene, and pyrene in soil slurry reactor (SSR) using two-liquid phase (TLP) system were investigated. The mass transfer ratio and rate of PAH in the TLP system using light paraffine oil, which has the highest solubility of PAH, were influenced by the amount of light paraffine oil and mixing speed. When the amount of light paraffine oil decreased from 15 % to 2.5 % (v/v), the mass transfer ratio of anthracene decreased significantly compared with that of phenanthrene and pyrene. As mixing speed increased, the initial mass transfer rate of PAH within 1 day was enhanced. However, each final mass transfer ratio of three PAHs after 5 day was similar irrespective of mixing speed.

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평판 후류가 원통 표면의 물질전달에 미치는 영향에 대한 실험적 연구 (Experimental study on the effect of flat-plate wake on mass transfer about a cylinder in crossflow)

  • 맹두진;김형수;이준식
    • 대한기계학회논문집
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    • 제18권10호
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    • pp.2779-2786
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    • 1994
  • This study presents an experimental investigation of the effect of the wake on mass transfer about a circular cylinder in crossflow. The flat-plate wake was generated by merging two mirror images of turbulent boundary layers that were well developed along the both sides of flat plate with a sharp trailing edge. The velocity field was measured by a hot-wire system and the mass transfer rate by a naphthalene sublimation method. The mixing and developing stages of the wake were addressed to identify flow conditions. The mass transfer effects of different developing stages of the wake was discussed in detail. It is noted that a local maximum appears not at the front stagnation point but at a point a little downstream when the cylinder is located in the nearwake region and much more elevated mass transfer rate is obtained compared to effect of free-stream turbulence.

유출홀이 설치된 회전하는 정사각 유로에서의 열/물질전달 특성 (Heat/Mass Transfer Characteristics on Rotating Square Channel with Bleed Holes)

  • 김상인;김경민;이동현;이동호;조형희
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2004년도 추계학술대회
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    • pp.1104-1109
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    • 2004
  • The present study has been conducted to investigate convective heat/mass transfer inside the cooling passage with bleed holes. The rotating square channel has 40.0 mm hydraulic diameter and the bleed holes on the leading surface of the channel. The hole diameter of bleed hole is 4.5 mm and its spacing (P/d=4.9) is about five times of hole diameter. Mass flow rate through bleed holes is 10% of the main flow rate and rotation number is changed form 0.0 to 0.4. A naphthalene sublimation technique is employed to determine the detailed local heat transfer coefficients using the heat and mass transfer analogy. The cooling performance is influenced by mass flow rate through bleed holes and Coriolis force of rotating channel for fixed reynolds number. The heat transfer is enhanced around holes on the leading surface because of trapping flow by bleeding. However heat transfer on the leading surface is decreased due to Coriolis force.

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초기 횡방향 유동이 존재하는 충돌제트/유출냉각에서 요철이 설치된 유출면에서의 열/물질전달 특성 (Heat/Mass Transfer Characteristics on Rib-roughened Surface for Impingement/Effusion Cooling System with Initial Crossflow)

  • 이동호;남용우;조형희
    • 대한기계학회논문집B
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    • 제28권3호
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    • pp.338-348
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    • 2004
  • The present study is conducted to investigate the effect of rib arrangements on an impingement/effusion cooling system with initial crossflow. To simulate the impingement/effusion cooling system, two perforated plates are placed in parallel and staggered arrangements with a gap distance of 2 times of tile hole diameter. Initial crossflow passes between the injection and effusion plates, and the square ribs (3mm) are installed on the effusion plate. Both the injection and effusion hole diameters are 10mmand Reynolds number based on the hole diameter and hole-to-hole pitch are fixed to 10,000 and 6 times of the hole diameter, respectively. To investigate the effects of rib arrangements, various rib arrangements, such as 90$^{\circ}$transverse and 45$^{\circ}$angled rib arrangements, are used. Also, the effects of flow rate ratio of crossflow to impinging jets are investigated. With the initial crossflow, locally low transfer regions are formed because the wall jets are swept away, and level of heat transfer rate get decreased with increasing flow rate of crossflow. When the ribs are installed on the effusion plate, the local distributions of heat/mass transfer coefficients around the effusion holes are changed. The local heat/mass transfer around the stagnation regions and the effusion holes are affected by the rib positions, angle of attack and rib spacing. For low blowing ratio, the ribs have adverse effects on heat/mass transfer, but for higher blowing ratios, higher and more uniform heat transfer coefficient distributions are obtained than the case without ribs because the ribs prevent the wall jets from being swept away by the crossflow and increase local turbulence of the flow near the surface. Average heat transfer coefficients with rib turbulators are approximately 10% higher than that without ribs, and the higher values are obtained with small pitch of ribs. However, the attack angle of the rib has little influence on the average heat/mass transfer.

계면활성제의 농도가 유하액막의 열전달 특성에 미치는 영향에 관한 실험적 연구 (An Experimental Study on Heat Transfer in a Falling Liquid Film with Surfactant)

  • 김경희;강병하;이대영
    • 대한설비공학회:학술대회논문집
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    • 대한설비공학회 2006년도 하계학술발표대회 논문집
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    • pp.150-155
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    • 2006
  • Falling liquid plays a role in a wide variety of naturally occurring phenomena as well as in the operation of industrial process equipment where heat and mass transfer take place. In such cases, it is required that the falling film should spread widely on the surface forming thin liquid film to enlarge contact surface. An addition of surface active agent to a falling liquid film affects the flow characteristics of the falling film. In this study the heat transfer characteristics for a falling liquid film has been investigated by an addition of the surface active agents. The falling liquid film was formed on a vertical flat plate. As the mass flow rate of liquid falling film is increased, the wetted area is a little increased while the heat transfer rate as well as heat transfer coefficient is significantly increased. It is also found that both wetted area and heat transfer rate is substantially increased while heat transfer coefficient is a little increased with an increase in the surfactant concentration at a given mass flow rate.

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마이크로 스케일 연소기의 백금 촉매 반응 모델링과 물질 전달 특성에 대한 연구 (A Study on the Modeling of Pt-Catalyzed Reaction and the Characteristics of Mass Transfer in a Micro-Scale Combustor)

  • 이광구;영목웅이
    • 대한기계학회논문집B
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    • 제32권11호
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    • pp.870-877
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    • 2008
  • Numerical analysis is applied to model Pt-catalyzed reaction in a micro-scale combustor fueled by butane. The reaction constants of catalytic oxidation are determined from plug flow model with the experimental data. Orders of magnitude between the chemical reaction rate and the mass transfer rate are carefully compared to reveal which mechanism plays a dominant role in the total fuel conversion rate. For various conditions of fuel flow rate and surface temperature, the profiles of Sherwood number are investigated to study the characteristics of the mass transport phenomena in the micro-tube combustor.

아이스슬러리형 빙축열 시스템을 이용한 냉각 시스템의 특성 분석 (Characteristic Analysis of the Cooling System Using Ice Slurry Type Heat Storage System)

  • 이동원;이순명
    • 대한설비공학회:학술대회논문집
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    • 대한설비공학회 2006년도 하계학술발표대회 논문집
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    • pp.111-115
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    • 2006
  • To clarify the hydraulic and thermal characteristics of ice slurry which made from 6.5% ethylene glycol-water solution flow in the double tube and plate type heat exchanger, experimental studies were performed. The mass flux and Ice fraction of ice slurry were varied from 800 to $3,500 kg/m^2s$(or 7 to 17 kg/min) and from 0 to 25%, respectively. During the experiment, it was found that the measured pressure drop and heat transfer rate increase with the mass flux and ice fraction; however the effect of ice fraction appears not to be significant at high mass flux region. At the region of low mass flux, a sharp increase in the pressure drop and heat transfer rate were observed depends on mass flux.

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