• Korean Chemical Engineering Research
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• v.60 no.4
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• pp.582-587
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• 2022

Biphasic solvents are attracting attention as energy-reducing solvents for capturing CO₂ from flue gas in combustion process. In this study, considering diethylenetriamine (DETA) and diethylethanolamine (DEEA) mixed solvents, one of the biphasic solvents by blending of two types of amines, the CO₂ absorption rates of DETA and DEEA was measured by wetted wall column. The effects of DETA and DEEA concentrations and operating temperature on the overall mass transfer coefficient were investigated. As a result, the overall mass transfer coefficient was proportional to the DETA concentration. However, in the case of the DEEA concentration, the effect was small and when the concentration was exceeded, the overall mass transfer coefficient decreased. The DETA aqueous solution showed little change in the overall mass transfer coefficient with the operating temperature, whereas the DEEA aqueous solution increased the overall mass transfer coefficient with the operating temperature. As a result of obtaining the observed reaction rate constant under the pseudo-first-order reaction assumption, it was found that the observed reaction rate constant in DETA aqueous solution was proportional to the DETA concentration, but DEEA did not fit the pseudo-first-order reaction assumption.

• Journal of Microbiology and Biotechnology
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• v.23 no.10
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• pp.1445-1453
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• 2013

The scale-up criterion of constant oxygen mass transfer coefficient ($k_La$) was applied for the production of itaconic acid (IA) in a 50 L pilot-scale fermentor by the fungal cells of Aspergillus terreus. Various operating conditions were examined to collect as many $k_La$ data as possible by adjusting the stirring speed and aeration rate in both 5 L and 50 L fermentor systems. In the fermentations performed with the 5 L fermentor, the highest IA production was obtained under the operating conditions of 200 rpm and 1.5 vvm. Accordingly, we intended to find out parallel agitation and aeration rates in the 50 L fermentor system, under which the $k_La$ value measured was almost identical to that ($0.02sec^{-1}$) of the 5 L system. The conditions of 180 rpm and 0.5 vvm in the 50 L system turned out to be optimal for providing almost the same volumetric amount of dissolved oxygen (DO) into the fermentor, without causing shear damage to the producing cells due to excessive agitation. Practically identical fermentation physiologies were observed in both fermentations performed under those respective operating conditions, as demonstrated by nearly the same values of volumetric ($Q_p$) and specific ($q_p$) IA production rates, IA production yield ($Y_{p/s}$), and specific growth rate (${\mu}$). Specifically, the negligible difference of the specific growth rate (${\mu}$) between the two cultures (i.e., $0.029h^{-1}$ vs. $0.031h^{-1}$) was notable, considering the fact that ${\mu}$ normally has a significant influence on $q_p$ in the biosynthesis of secondary metabolites such as itaconic acid.

• Journal of the Korean Chemical Society
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• v.22 no.5
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• pp.340-355
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• 1978

Model reactions were often applied in the measuring of the mass transfer coefficient and interfacial area between gas and liquid, which are the most important factors in the design of equipment for gas absorption accompanied with chemical reaction this study, wetted wall column was applied to the sulfite-system among the known model reactions. It was found that one could not ignore the effect of contact time on the determination of mass transfer coefficient and interfacial area. When the reaction rate is very high or very low, the differences of absorption rate would be very large in according to the length of column, that is to the contact time. But the effect of contact time was free about the rate constant $k_2=5.5{\times}10^6m^3/kmol{\cdot}s$, that means the rate of gas absorption become independent upon the hydrodynamics of the equipment. It has shown that instead of steel column could be applied the fine grain-graphite column.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.17 no.12
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• pp.1177-1184
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• 2005

A numerical analysis was carried out on the heat and mass transfer, and pressure drop characteristics of the modular tube bundle heat exchanger. The finite volume method with a $k-\varepsilon$ turbulence model was used for the analysis. Due to condensation, the total heat transfer rate is observed about $4\~8\%$ higher than that on dry surfaces. Total heat transfer rate increases with increase in the velocity, temperature and relative humidity of incoming air. It also increases with decreasing the aspect ratio of heat exchanger tube. The inlet velocity of cooling water has little effect on the total heat transfer when the other conditions are fixed.

• Journal of applied mathematics & informatics
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• v.9 no.2
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• pp.731-744
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• 2002

The temperature distribution in human skin and subdermal tissue layer is presented using bioheat transfer equation. The body temperature is determined by the balance between heat produced and heat lost by our body. The time-dependent solutions have been found to be affected by the metabolic heat generation rate, blood mass flow, the rate of evaporation of perspiration and also by the atmospheric temperature. The analytic solutions for different layers have been calculated numerically and are also shown graphically.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.24 no.11
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• pp.1486-1496
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• 2000

The initial flame kernel development and flame propagation in a constant volume combustion chamber is analyzed by the heat release rate and the mass fraction burnt. The combustion pressure is measured with a piezoelectric type pressure sensor. In order to evaluate the effects of ignition system and ignition energy on the flame propagation, four different ignition systems are designed and tested, and the ignition energy is varied by the dwell time. Several different spark plugs are also tested and examined to analysis the effects of electrodes on flame kernel development. The results show that the when the dwell time is increased, and when the spark plug gap is extended, heat release rate and the mass burnt fraction are increased. The materials and shapes of electrodes affect the flame development, because they change the energy transfer efficiency from electrical energy to chemical energy. The diameter of electrodes influences not only the heat release rate but also the mass burnt fraction as well.

• Journal of Microbiology and Biotechnology
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• v.21 no.6
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• pp.652-658
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• 2011

The growth kinetics of Streptomyces noursei NRRL 5126 was investigated under different aeration and agitation combinations in a 5.0 l stirred tank fermenter. Poly-${\varepsilon}$-lysine biosynthesis, cell mass formation, and glycerol utilization rates were affected markedly by both aeration and agitation. An agitation speed of 300 rpm and aeration rate at 2.0 vvm supported better yields of 1,622.81 mg/l with highest specific productivity of 15 mg/l.h. Fermentation kinetics performed under different aeration and agitation conditions showed poly- ${\varepsilon}$-lysine fermentation to be a growth-associated production. A constant DO at 40% in the growth phase and 20% in the production phase increased the poly-${\varepsilon}$-lysine yield as well as cell mass to their maximum values of 1,992.35 mg/l and 20.73 g/l, respectively. The oxygen transfer rate (OTR), oxygen utilization rate (OUR), and specific oxygen uptake rates ($qO_2$) in the fermentation broth increased in the growth phase and remained unchanged in the stationary phase.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.20 no.4
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• pp.1481-1490
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• 1996

This study is intend to improve flow pattern within evaporator, which is low quality and low mass flux, by installing narrow horizontal annular crevice so that enhance heat transfer coefficient. The motive, which made to study heat transfer enhancement by using narrow annular crevice, came from capillary phenomena and pumping force of generating vapor on refrigerant boiling. Tests were run about 5 models of turbulence promoter with CFC-12, in the range of evaporating temperature (15.deg. C), mass flux (50 to 100 kg/m$\^$2/s), heat flux (3.4 to 6.7 kW/m$\^$2/), quality (0.1 to O.5). It is observed that flow pattern within evaporator is changed closely to semi-annular flow or annular flow, of which refrigerant liquid is reached to the upper side of tube by using narrow annular crevice. When the narrow annular crevice is installed in the evaporator tube, local heat transfer coefficient is generally more improved than that of smooth tube. That fact is according to observed result of flow pattern. It is learned that narrow annular crevice has more efficiency at a low mass flux. At the TP-5, enhancement of heat transfer rate is about 170% compare to that of smooth tube on a low mass flux (50 kg/m$\^$2/s), and it is about 134% on a high mass flux (100 kg/M$\^$2/S), so that we know that it is on a very high condition.

• International Journal of Air-Conditioning and Refrigeration
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• v.11 no.4
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• pp.188-198
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• 2003

R410A and R407C are considered to be alternative refrigerants of R22 for the air-conditioners. An experimental study is carried out to investigate the effect of the change of mass flow rate on the characteristics of heat transfer and pressure drop in three row slit finned-tube heat exchanger for R407C, R410A and R22. R407C, a non-azeotropic refrigerant mixture, exhibited a quite different condensation phenomenon from those of R22 and R410A and its condensation heat transfer coefficient was much lower than that of R22 and R410A. On the other hand, the condensation heat transfer coefficient of R410A, near-azeotropic refrigerant mixture, was a little higher than that of R22. R410A also showed the lowest condensation pressure drop across the test section. For all refrigerants, the condensation heat transfer coefficient and pressure drop increase as the mass flux increases. The condensation heat transfer coefficient correlation proposed by Kedzierski shows the best agreement with the experimental data within $\pm$20%.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.12 no.5
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• pp.448-456
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• 2000

For piping line systems associated with a double-acting reciprocating compressor, an analytical study has been made on the gas pulsation in piping lines and its effects on the compressor performance. The transfer matrix which relates mass flow rate to the gas pulsation downstream of the compressor valve can be obtained by an acoustic model for piping line systems which include snubber and after-cooler with the aid of four pole theory Since mass flow rate is affected by the pressure pulsation in the pressure plenum, while the latter being determined by the former, iteration in the calculation should be made for convergence. The gas pulsation in pipings is found to have an adverse effect on the compressor's performance, and the magnitude of the gas pulsation can be lowered by increasing snubber volume.