• Title/Summary/Keyword: Mass diffusion

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Preparation of AI-21Ti-23Cr High Temperature Protective Coating for TiAo Intermatallic Compounds by RF Magnetron Sputtering (RF Magnetron Sputtering에 의한 금속간화합물 TiAI 모재위의 AI-21Ti-23Cr 고온내산화코팅)

  • Park, Sang-Uk;Park, Jeong-Yong;Lee, Ho-Nyeon;O, Myeong-Hun;Wi, Dang-Mun
    • Korean Journal of Materials Research
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    • v.6 no.7
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    • pp.742-751
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    • 1996
  • Ti-48Al(at.%) specimens were coated with Al-21Ti-23Cr(at.%) film by RF magnetron sputtering. Ti-48Al specimen coated at 200, 0.8Pa and 573K showed the best oxidation resistance property in the isothermal oxidation test. Al-21Ti-23Cr film was amophous after depostion, but crystallized and fromed a protective ${Al}_{2}{O}_{3}$ layer on the surface during oxidation. Ti-48Al specimens coated at 573K have been sassessed by isothermal oxidation test for 100 hours at 1073K, 1173K and 1273K. The mass gain curves showed that parabolic stage continued at al tested temperature range in isothermal oxidation test, and the excellent oxidation resistance is attriutable to the formation of a protective ${Al}_{2}{O}_{3}$ layer on the surface of Al-21Ti-23Cr film. After oxidation test at 1273K, the matrix of Al-21Ti-23Cr film had transformed into TiAlCr phase due to the depletion of Al during oxidation and the diffusion of Ti from the substrate, and the extent of mass gain of the specimen increased compared with that of specimens tested at lower temperature.

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Chemical Composition and Antifungal Activity of Plant Essential Oils against Malassezia furfur (비듬균(Malassezia furfur)에 대한 식물 오일들의 항균활성 및 활성오일의 성분 분석)

  • Lee, Jeong-Hyun;Lee, Jae-Sug
    • Microbiology and Biotechnology Letters
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    • v.38 no.3
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    • pp.315-321
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    • 2010
  • Malassezia furfur is an important causal factor for seborrheic dermatitis. Nowadays, the drugs available to treat this fungal infection are few. Several studies have documented the biological activity of essential oils. However, its antifungal properties are not completely understood, especially its anti-Malassezia activity. The aim of this study were to evaluate the effect of the plant essential oils on the growth of M. furfur using disk diffusion method and analyze by Gas chromatography-mass spectrometry (GC-MS) most active essential oils. In first screening, the 17 plant essential oils have possesses inhibitory activity against M. furfur at 2 mg/mL. Among the plant essential oils, oil of Citrus auranifoli was most active against M. furfur and its activity showed dose dependency. This anti-malassezial activity was high than that of itraconazole at 2 mg/mL. Oil of Citrus auranifolia also was phytochemically examined by GC-MS analysis, its main constituents were identified as limonene, ${\gamma}$-terpinene and terpinolene. It can be concluded that essential oils of Citrus auranifolia may have interesting applications to control fungal-derived diseases.

Characteristics of Atmospheric Dry Deposition of Nitrogen-containing Compounds (대기 중 질소산화물의 건식침적 특성)

  • Yi, Seung-Muk;Han, Young-Ji;Cheong, Jang-Pyo
    • Journal of Korean Society of Environmental Engineers
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    • v.22 no.4
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    • pp.775-784
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    • 2000
  • Nitrate dry deposition fluxes were directly measured using knife-leading-edge surrogate surface (KSS) covered with greased strips and a water surface sampler (WSS). The average gaseous flux ($8.3mg/m^2/day$) was much higher than the average particulate one ($3.0mg/m^2/day$). The best fit gas phase mass transfer coefficient (MTC) of $HNO_3$ was obtained by linear regression analysis between measured gaseous flux containing nitrogen compounds and measured ambient $HNO_3$ concentration. The result showed that the MTCs of $HNO_3$ were approximately two times higher than those of $SO_2$. Especially, during the ozone action day, measured gaseous fluxes containing nitrogen compounds were much higher than those ones calculated as the product of measured ambient $HNO_3$ concentration and gas phase MTC of $HNO_3$, which is calculated from MTC of $SO_2$ using Graham's diffusion law. This result indicated that other nitrogen compounds except $HNO_3$ contributed to gaseous flux containing nitrogen compounds into the water surface sampler. The theoretical calculations suggest the contributions of nitrous acid ($HNO_2$) and PAN to the gaseous dry deposition flux of nitrogen containing compounds to the WSS.

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Long-term Trends of Visibility and Air Quality in Seoul, Ganghwa, Susan, Gwangju, Jeju (서울, 강화, 서산, 광주, 제주지역에서의 장기간 대기오염 및 시정 변화경향에 대한 연구 : 1990년 1월~2001년 7월)

  • Han, J.S.;Moon, Kwang-Joo;Kong, B.J.;Hong, Y.D.;Lee, S.J.;Shin, J.Y.
    • Journal of Environmental Impact Assessment
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    • v.13 no.4
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    • pp.197-211
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    • 2004
  • Visibility impairment was known as an indicator of the increased air pollution. In many previous studies, it is known that both directly emitted fine particles mainly from vehicles and secondary aerosols from photochemical reactions could contribute to this visibility impairment in addition to the meteorological condition. Furthermore, the visibility showed different change patterns according to the geographical condition. In order to research into the influence of these factors on visibility, this study analyzed the visibility at 15:00, observed from 1990 to 2001 in Seoul, Ganghwa, Susan, Gwangju, Jeju. As a result, the visibility was increased in Seoul except the rainfall period, but in Susan, Gwangju, Jeju, it decreased with the relative humidity (RH). Especially, in Seoul, the number of low visibility days was larger than other sites and variations of the visibility were sensitive to the concentration of air pollutants, such as TSP, $NO_2$, $O_3$. The visibility impairment was mainly observed in meteorological condition of RH<50% and relatively stationary front. Therefore it is inferred that photochemical smog could lead to the low visibility in Seoul. On the other hands, in Ganghwa and Susan, when RH was 60~70%, the low visibility observed under the influence of the transports of air pollutants from nearby cities as well as humid air mass from coastal region. And in Jeju, sea fog and humid air mass caused the visibility impairment when the RH was larger than 80%. Finally, during the observational period, some cases of low visibility phenomena were simultaneously observed in the vast region including Seoul, Susan, Ganghwa. It not only includes the visibility aggravation by Asian Dust, but also could be caused by the movement and diffusion of flying dust or secondary aerosols. Moreover, the result shows that these phenomena could be mainly influenced by meteorological factors covering the wide regions.

Moisture Content Change of Korean Red Pine Logs During Air Drying: II. Prediction of Moisture Content Change of Korean Red Pine Logs under Different Air Drying Conditions (소나무 원목의 천연건조 중 함수율 변화: II. 소나무 원목의 천연건조 중 함수율 변화 예측)

  • HAN, Yeonjung;CHANG, Yoon-Seong;EOM, Chang-Deuk;LEE, Sang-Min
    • Journal of the Korean Wood Science and Technology
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    • v.47 no.6
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    • pp.732-750
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    • 2019
  • Air drying was carried out on 15 Korean red pine logs to provide a prediction model of the moisture content (MC) change in the wood during drying. The final MC was 17.4% after 880 days since the beginning of air drying in the summer for 6 Korean red pine logs with 68.7% initial MC. The final MC was 16.0% after 760 days since the beginning of air drying in the winter for 9 Korean red pine logs with 35.8% initial MC. A regression model with R-squared of 0.925 was obtained as a result of multiple regression analyses with initial MC, top diameter, temperature, relative humidity, and wind speed as independent variable and and MC change during air drying as dependent variable. The initial MC and top diameter, which is the characteristic of Korean red pine, have greater effect on the MC decrease during air drying compared to meteorological factors such as the temperature, relative humidity, and wind speed. Two-dimensional mass transfer analysis was performed to predict the MC distribution of Korean red pine logs during air drying. Two prediction models with different air drying days and different meteorological factors for the determination of the diffusion coefficient and surface emission coefficient were presented. The error between the different two methods ranged from 0.1 to 0.8% and the difference from the measured value ranged from 2.2 to 3.6%. By measuring the internal MC during air drying of Korean pine logs with various initial MC and diameter, and calculating the moisture transfer coefficient in wood for each meteorological condition, the error of the prediction model can be reduced.

Altitude training as a powerful corrective intervention in correctin insulin resistance

  • Chen, Shu-Man;Kuo, Chia-Hua
    • Korean Journal of Exercise Nutrition
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    • v.16 no.2
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    • pp.65-71
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    • 2012
  • Oxygen is the final acceptor of electron transport from fat and carbohydrate oxidation, which is the rate-limiting factor for cellular ATP production. Under altitude hypoxia condition, energy reliance on anaerobic glycolysis increases to compensate for the shortfall caused by reduced fatty acid oxidation [1]. Therefore, training at altitude is expected to strongly influence the human metabolic system, and has the potential to be designed as a non-pharmacological or recreational intervention regimen for correcting diabetes or related metabolic problems. However, most people cannot accommodate high altitude exposure above 4500 M due to acute mountain sickness (AMS) and insulin resistance corresponding to a increased levels of the stress hormones cortisol and catecholamine [2]. Thus, less stringent conditions were evaluated to determine whether glucose tolerance and insulin sensitivity could be improved by moderate altitude exposure (below 4000 M). In 2003, we and another group in Austria reported that short-term moderate altitude exposure plus endurance-related physical activity significantly improves glucose tolerance (not fasting glucose) in humans [3,4], which is associated with the improvement in the whole-body insulin sensitivity [5]. With daily hiking at an altitude of approximately 4000 M, glucose tolerance can still be improved but fasting glucose was slightly elevated. Individuals vary widely in their response to altitude challenge. In particular, the improvement in glucose tolerance and insulin sensitivity by prolonged altitude hiking activity is not apparent in those individuals with low baseline DHEA-S concentration [6]. In addition, hematopoietic adaptation against altitude hypoxia can also be impaired in individuals with low DHEA-S. In short-lived mammals like rodents, the DHEA-S level is barely detectable since their adrenal cortex does not appear to produce this steroid [7]. In this model, exercise training recovery under prolonged hypoxia exposure (14-15% oxygen, 8 h per day for 6 weeks) can still improve insulin sensitivity, secondary to an effective suppression of adiposity [8]. Genetically obese rats exhibit hyperinsulinemia (sign of insulin resistance) with up-regulated baseline levels of AMP-activated protein kinase and AS160 phosphorylation in skeletal muscle compared to lean rats. After prolonged hypoxia training, this abnormality can be reversed concomitant with an approximately 50% increase in GLUT4 protein expression. Additionally, prolonged moderate hypoxia training results in decreased diffusion distance of muscle fiber (reduced cross-sectional area) without affecting muscle weight. In humans, moderate hypoxia increases postprandial blood distribution towards skeletal muscle during a training recovery. This physiological response plays a role in the redistribution of fuel storage among important energy storage sites and may explain its potent effect on changing body composition. Conclusion: Prolonged moderate altitude hypoxia (rangingfrom 1700 to 2400 M), but not acute high attitude hypoxia (above 4000 M), can effectively improve insulin sensitivity and glucose tolerance for humans and antagonizes the obese phenotype in animals with a genetic defect. In humans, the magnitude of the improvementvaries widely and correlates with baseline plasma DHEA-S levels. Compared to training at sea-level, training at altitude effectively decreases fat mass in parallel with increased muscle mass. This change may be associated with increased perfusion of insulin and fuel towards skeletal muscle that favors muscle competing postprandial fuel in circulation against adipose tissues.

Comparison of Chemical Compositions and Antimicrobial Activities of Essential Oils from Three Conifer Trees; Pinus densiflora, Cryptomeria japonica, and Chamaecyparis obtusa

  • Lee, Jeong-Ho;Lee, Byung-Kyu;Kim, Jong-Hee;Lee, Sang-Hee;Hong, Soon-Kwang
    • Journal of Microbiology and Biotechnology
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    • v.19 no.4
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    • pp.391-396
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    • 2009
  • The chemical compositions, and antibacterial and antifungal effects of essential oils extracted from three coniferous species, Pinus densiflora, Cryptomeria japonica, and Chamaecyparis obtusa, were investigated. Gas chromatography mass analysis of the essential oils revealed that the major components and the percentage of each essential oil were 16.66% $\beta$-phellandrene and 14.85% $\alpha$-pinene in P. densiflora; 31.45% kaur-16-ene and 11.06% sabinene in C. japonica; and 18.75% bicyclo [2,2,1] heptan-2-ol and 17.41% 2-carene in Ch. obtusa. The antimicrobial assay by agar disc diffusion method showed that $2.2{\mu}g$ of Ch. obtusa oil inhibited most effectively the growth of Escherichia coli ATCC 33312 and Klebsiella oxytoca ATCC 10031, whereas the C. japonica oil gave weak antimicrobial activity. The minimal inhibitory concentration(MIC) values for bacterial strains were in the range of 5.45-21.8 mg/ml depending on essential oils, but most Gram-negative bacteria were resistant even at 21.8 mg oil/ml. P. densiflora oil showed the most effective antifungal activity and the MIC values for Cryptococcus neoformans B42419 and Candida glabrata YFCC 062CCM 11658 were as low as 0.545 and 2.18 mg/ml, respectively. Cryp. neoformans B42419 was the most sensitive to all essential oils in the range of 0.545-2.18 mg/ml. Our data clearly showed that the essential oils from the three conifers had effective antimicrobial activity, especially against fungi.

Influence of piston bowl geometry on the in-cylinder flow of HCCI Engine (HCCI 엔진의 실린더 내 유동에 대한 피스톤 보울 형상의 영향)

  • Nam, Seung Man;Lee, Kye Bock
    • Journal of Energy Engineering
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    • v.22 no.4
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    • pp.399-405
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    • 2013
  • The gas motion inside the engine cylinder plays a very important role in determining the thermal efficiency of an internal combustion engine. A precise information of in-cylinder three dimensional complex gas motion is crucial in optimizing engine design. Homogeneous charge compression ignition (HCCI) engine is a combustion concept, which is a hybrid between Otto and Diesel engine. The turbulent diffusion leads to increased rates of momentum, heat and mass transfer. The in-cylinder turbulence flow was found to affect the present HCCI combustion mainly through its influence on the wall heat transfer. This study investigates the effect of piston geometry shape on the turbulent flow characteristics of in-cylinder from the numerical analysis using the LES model and the results obtained can offer guidelines of the combustion geometries for better combustion process and engine performance.

Intimate Understanding for Growth Mode of Graphene on Copper

  • Song, U-Seok;Jeon, Cheol-Ho;Kim, Su-Yeon;Kim, Yu-Seok;Kim, Seong-Hwan;Lee, Su-Il;Jeong, Dae-Seong;Park, Jong-Yun
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.08a
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    • pp.181-181
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    • 2012
  • Direct synthesis of graphene using a chemical vapor deposition (CVD) has been considered a facile way to produce large-area and uniform graphene film, which is an accessible method from an application standpoint. Hence, their fundamental understanding is highly required. Unfortunately, the CVD growth mechanism of graphene on Cu remains elusive and controversial. Here, we present the evidences for two different growth modes of graphene on Cu investigated by varying carbon feedstock (C2H2 and CH4) and working pressure. The number of uniform graphene layer grown by C2H2 increased with increasing its injection time. A combined secondary ion mass spectrometry (SIMS) and X-ray diffraction (XRD) study revealed a carbon-diffused Cu layer created below surface region of Cu substrate with the expansion of Cu lattice. The graphene on Cu was grown by the diffusion and precipitation mode not by the surface adsorption mode, because similar results were observed in graphene/Ni system. The carbon-diffused Cu layer was also observed after graphene growth under high CH4 pressure. Based on various previous results and ours, we have successfully found that there are two selective growth modes for graphene on Cu substrate, and a desired mode can be chosen by tuning working pressure corresponding to the kind of carbon feedstock. We believe that this finding will shed light on high quality graphene growth and its multifaceted applications.

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A Study on the Metal surface Design from Mokumegane technique (모꾸메가네 기법을 활용한 금속표면 디자인 연구)

  • Yoon, Jae-Won
    • Journal of Digital Convergence
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    • v.10 no.10
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    • pp.431-437
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    • 2012
  • In today's modern society, since the Industrial Revolution took place, still lots of goods have been produced in quantity. However, human's instinct has been growing bigger and bigger that he or she wants to possess the works or products of scarcity and aesthetic value of a sculpture handmade by craftsmen, not mass-produced with the same design patterns. Accordingly, it is required that an artist be concerned about the value of figuring out and pursuing an individual's lifestyle, his/her needs and inherent desires. Moreover, by means of visualization technique, an artist should provide the public with several scenarios about the future, letting them choose the one they want democratically. Therefore, with the help of Mokumegane technique, one of the traditional metal crafts techniques, which shows certain organic patterns joining different metals, this research aims for the inheritance of traditional techniques and the objective preparation for high-quality crafts market, studying the patterns expressed on the surface of metals, which are hard to find through machines.