• 제목/요약/키워드: Mass and heat transfer

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건조 공정 중 요소 수지 성형재료의 경화 특성에 대한 물질전달 효과 (The Effect of Mass Transfer on the Cure Properties of the Urea Resin Moulding Compounds Under the Drying Process)

  • 김상렬;최일곤;김병철
    • Korean Chemical Engineering Research
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    • 제40권6호
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    • pp.681-686
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    • 2002
  • 산업 현장에서 이론적인 건조방법이 실제와는 차이가 많고 또한 배기가스의 재순환이 폐열을 이용하는 목적으로 열원의 절감에는 경제적이지만 이들 파라미터에 따른 요소수지 성형화에 미치는 영향을 연구한바가 없다. 따라서 요소 수지 성형재료의 경화 특성을 건조와 성형 공정 중의 건조온도와 시간, 배기가스 재 순환률 및 성형온도에 따라 실험하여 다음과 같은 결과를 얻었다. 성형재료의 수분함량은 건조 시간과 건조 온도가 증가함에 감소하고, 건조속도는 배기가스 재 순환률이 증가하면 감소한다. 특히 경화유동도는 배기가스의 재 순환량, 건조온도 및 성형온도가 증가하면 감소한다. 또한 건조온도, 건조시간, 배기가스의 재 순환량 및 성형온도에 따라 수분함량과 경화유동도에 대한 상관식을 구하여 재현성있는 최적의 조건을 구명하였다.

외부 화학증착 공정에서의 가수분해반응으로 인한 실리카 생성에 대한 버크-슈만 해석 (Burke-Schumann analysis of silica formation by hydrolysis in an external chemical vapor deposition process)

  • 송창걸;황정호
    • 대한기계학회논문집B
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    • 제20권5호
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    • pp.1671-1678
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    • 1996
  • In external chemical vapor deposition processes including VAD and OVD the distribution of flame-synthesized silica particles is determined by heat and mass transfer limitations to particle formation. Combustion gas flow velocities are such that the particle diffusion time scale is longer than that of gas flow convection in the zone of particle formation. The consequence of these effects is that the particles formed tend to remain along straight smooth flow stream lines. Silica particles are formed due to oxidation and hydrolysis. In the hydrolysis, the particles are formed in diffuse bands and particle formation thus requires the diffusion of SiCl$\_$4/ toward CH$\_$4//O$\_$2/ combustion zone to react with H$\_$2/O diffusing away from these same zones on the torch face. The conversion kinetics of hydrolysis is fast compared to diffusion and the rate of conversion is thus diffusion-limited. In the language of combustion, the hydrolysis occurs as a Burke-Schumann process. In selected conditions, reaction zone shape and temperature distributions predicted by the Burke-Schumann analysis are introduced and compared with experimental data available. The calculated centerline temperatures inside the reaction zone agree well with the data, but the calculated values outside the reaction zone are a little higher than the data since the analysis does not consider diffusion in the axial direction and mixing of the combustion products with ambient air. The temperatures along the radial direction agree with the data near the centerline, but gradually diverge from the data as the distance is away from the centerline. This is caused by the convection in the radial direction, which is not considered in the analysis. Spatial distribution of silica particles are affected by convection and diffusion, resulting in a Gaussian form in the radial direction.

Runge-Kutta method for flow of dusty fluid along exponentially stretching cylinder

  • Iqbal, Waheed;Jalil, Mudassar;Khadimallah, Mohamed A.;Ayed, Hamdi;Naeem, Muhammad N.;Hussain, Muzamal;Bouzgarrou, Souhail Mohamed;Mahmoud, S.R.;Ghandourah, E.;Taj, Muhammad;Tounsi, Abdelouahed
    • Steel and Composite Structures
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    • 제36권5호
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    • pp.603-615
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    • 2020
  • The present manuscript focuses on the flow and heat transfer of the dusty fluid along exponentially stretching cylinder. Enormous attempts are made for fluid flow along cylinder but the study of fluid behavior along exponentially stretching cylinder is discussed lately. Using appropriate transformations, the governing partial differential equations are converted to non-dimensional ordinary differential equations. The transformed equations are solved numerically using Shooting technique with Runge-Kutta method. The influence of the physical parameters on the velocity and temperature profiles as well as the skin fraction coefficient and the local Nusselt number are examined in detail. The essential observations are as the fluid velocity decreases but temperature grows with rise in particle interaction parameter, and both the fluid velocity and temperature fall with increase in mass concentration parameter, Reynold number, Particle interaction parameter for temperature and the Prandtl number.

경막 결정화기에서 벤젠-시클로헥산 혼합물로부터 벤젠의 결정성장속도 (Layer Growth Rate of Benzene Layer from Benzene-Cyclohexane Mixtures in Layer Crystallizer)

  • 김광주;이정민;유승곤
    • 공업화학
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    • 제7권2호
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    • pp.308-314
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    • 1996
  • 경막형 결정화기에서 벤젠-시클로헥산 혼합물로부터 벤젠의 결정성장속도가 조사되었다. 결정성장속도는 경막결정화기의 냉각벽에 부착되는 결정의 양으로부터 얻어진 결정두께와 시간에 대한 상관관계식으로부터 결정되었다. 결정성장속도와 결정의 표면온도와, 용융액의 온도의 차로 정의되는 과냉각정도와의 상관관계가 얻어졌다. 이 이성분 공융계에 대한 결정성장속도는 과냉각정도의 2승에 비례하였다. 경막결정화기의 열전달 및 물질전달 속도에 근거하여 결정의 표면온도 및 결정두께를 예측할 수 있는 모델식이 제시되었다. 5wt% 및 10wt%의 시클로헥산을 포함한 벤젠-시클로헥산 혼합물에 대하여 여러 다른 냉각온도에서 실험적으로 얻어진 결정두께의 자료와 모델식으로 계산된 결과가 비교되었다.

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냉각유로 형상변화에 따른 유동 및 열저항 최적화 연구 (Optimizing the Configurations of Cooling Channels with Low Flow Resistance and Thermal Resistance)

  • 조기현;안호선;김무환
    • 대한기계학회논문집B
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    • 제35권1호
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    • pp.9-15
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    • 2011
  • 본 연구에서는 3 차원 전산 열유동해석을 통하여 형상법칙에 근거하여 개발된 냉각판의 열수력학적인 특성을 분석하였다. 서펜타인 형상을 포함하여 최적화, 최적화되지 않은 1, 2 차 형상 총 5 개 형상을 대상으로 동일한 구속조건을 부여함으로써 유동저항, 열저항 및 분지유로에서의 유동균일도를 상호 비교함으로써 냉각판의 성능평가를 수행하였다. 그 결과, 최적화된 1, 2 차 형상 구조가 최적화되지 않은 경우와 비교하여 훨씬 적은 압력손실을 나타내었으며, 압력손실을 기준으로 최적화된 2 차 형상 구조가 가장 우수한 유동 구조를 나타내었다. 또한, 최적화된 1, 2 차 형상구조의 열저항 및 유동 분배성능도 기존에 사용되는 유로형상과 비교하여 모두 우수한 성능을 보였다.

압력용기로부터 압력방출장치를 통한 가스 방출에 관한 포괄적 고찰 (Comprehensive Consideration on the Discharge of Gases from Pressurized Vessels through Pressure Relief Devices)

  • 정창복
    • 한국안전학회지
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    • 제35권6호
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    • pp.32-45
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    • 2020
  • The problem of determining the discharge rates of gases from pressurized vessels through pressure relief devices was dealt with comprehensively. First, starting from basic fluid flow equations, detailed modeling procedures were presented for isentropic nozzle flows and frictional flows in a pipe, respectively. Meanwhile, physical explanations were given to choking phenomena in terms of the acoustic velocity, elucidating the widespread use of Mach numbers in gas flow models. Frictional flows in a pipe were classified into adiabatic, isothermal, and general flows according to the heat transfer situation around the pipe, but the adiabatic flow model was recommended suitable for gas discharge through pressure relief devices. Next, for the isentropic nozzle flow followed by adiabatic frictional flow in the pipe, two equations were established for two unknowns that consist of the Mach numbers at the inlet and outlet of the pipe, respectively. The relationship among the ratio of downstream reservoir pressure to upstream pressure, mass flux, and total frictional loss coefficient was shown in various forms of MATLAB 2-D plot, 3-D surface plot and contour plot. Then, the profiles of gas properties and velocity in the pipe section were traced. A method to quantify the relationship among the pressure head, velocity head, and total friction loss was presented, and was used in inferring that the rapid increase in gas velocity in the region approaching the choked flow at the pipe outlet is attributed to the conversion of internal energy to kinetic energy. Finally, the Levenspiel chart reproduced in this work was compared with the Lapple chart used in API 521 Standatd.

지상 및 미소중력 환경에서 물리적 승화법 공정에 미치는 불순물의 영향 분석: 염화제일수은에 대한 응용성 (Numerical Analysis for Impurity Effects on Diffusive-convection Flow Fields by Physical Vapor Transport under Terrestrial and Microgravity Conditions: Applications to Mercurous Chloride)

  • 김극태;권무현
    • 공업화학
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    • 제27권3호
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    • pp.335-341
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    • 2016
  • 본 연구에서는 지상 및 미소중력환경하에서 물리적 승화법 공정에서의 확산-대류유동에 미치는 불순물의 영향을 이론적으로 $Hg_2Cl_2-I_2$ 시스템에 적용하여 규명하는 것이다. 이론적 해석은 증기상에서 확산-대류 흐름, 열 및 물질전달을 속도 벡터 흐름, 유선, 온도, 농도 분포를 통하여 제시된다. 결정 영역에서의 전체 몰플럭스는 중력가속도와 성분 $I_2$, 불순물에 상당히 민감하게 반응한다. 성분 $I_2$을 증가시켰을 때, 농도 대류효과는 확산-대류 유동흐름을 안정화시키는 경향이 있다. 지상중력가속도의 0.001환경에서는 유동흐름은 1차원포물선의 흐름 구조를 나타내며, 확산지배형태를 보여주고 있다. $10^{-3}$지상중력가속도 이하에서는 대류 영향은 무시할 수 있다.

고분자 제습로터의 저온재생 성능시험 (Performance Test of Low Temperature Regeneration Polymeric Desiccant Rotor)

  • 이진교;이대영;오명도
    • 대한설비공학회:학술대회논문집
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    • 대한설비공학회 2009년도 하계학술발표대회 논문집
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    • pp.629-632
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    • 2009
  • The polymeric desiccant rotor is made from the super absorbent polymer by ion modification. The moisture sorption capacity of the super desiccant polymer(SDP) is 4 to 5 times larger than those of common desiccant meterials such as silica gel or zeolite. It is also known that SDP can be regenerated even at the relatively low temperature. To fabricate the desiccant rotor, firstly the SDP was laminated by coating the SDP on polyethylene sheet. Then corrugated and rolled up into a rotor. The diameter, the depth, the dimensions of the corrugated channel, etc. were pre-determined from numerical simulation on the heat and mass transfer in the desiccant rotor. The dehumidification performance was tested in a climate chamber. The relevant tests were carried out at the process air inlet temperature of $32^{\circ}C$, the regeneration air inlet temperature of $60^{\circ}C$ and the inlet dew-point temperature of both the process air and the regeneration air of $18.5^{\circ}C$, when the rotation period is long, the moisture sorption is not effective. In the desiccant rotor developed in this study, the optimum rotation period is found about 350s at the regeneration temperature of $60^{\circ}C$. It was found from further experiments that the optimum rotation tends to decreases as the regeneration temperature increases. Meanwhile, the outlet temperature of the process air deceases monotonically as the rotation period increases.

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사과의 건조조건(乾燥條件)에 따른 건조특성(乾燥特性) (The Drying Characteristics of Apples at Various Drying Conditions)

  • 정신교;최용희;손태화;최종욱
    • 한국식품과학회지
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    • 제18권1호
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    • pp.61-65
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    • 1986
  • 홍옥(紅玉)을 시료(試料)로 하여 건조조건(乾燥條件)을 다르게하여 건조특성(乾燥特性), 수분이동현상(水分移動現像), 건조중(乾燥中) 시료온도(試料溫度) 및 내부수분(內部水分)의 분포(分布)를 조사하였다. 사과의 수분확산계수(水分擴散係數)는 $1.1470{\sim}2.2148{\times}10^{-5}cm^2/sec$, 확산활성화(擴散活性化)에너지는 6.6 kcal/g mole 이었으며 Fick's law에서 아래의 식을 유도할 수 있었다. $${\In}\;{\Delta}t=In\;{\Delta}to-{\frac{D{\pi}^2{\theta}}{4d^2}}$$ 건조중(乾燥中) 내부수분분포(內部水分分布)의 이론치(理論値)와 실측치(實測値)는 거의 일치하였다.

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300MW급 IGCC를 위한 건식 분류층 석탄 가스화 공정의 동적 상태 모사 (The Process Simulation of Entrained Flow Coal Gasification in Dynamic State for 300MW IGCC)

  • 김미영;주용진;최인규;이중원
    • 한국수소및신에너지학회논문집
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    • 제21권5호
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    • pp.460-469
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    • 2010
  • To develop coal gasfication system, many studies have been actively conducted to describe the simulation of steady state. Now, it is necessary to study the gasification system not only in steady state but also in dynamic state to elucidate abnormal condition such as start-up, shut-down, disturbance, and develop control logic. In this study, a model was proposed with process simulation in dynamic state being conducted using a chemical process simulation tool, where a heat and mass transfer model in the gasifier is incorporated, The proposed model was verified by comparison of the results of the simulation with those available from NETL (National Energy Technology Laboratory) report under steady state condition. The simulation results were that the coal gas efficiency was 80.7%, gas thermal efficiency was 95.4%, which indicated the error was under 1 %. Also, the compositions of syngas were similar to those of the NETL report. Controlled variables of the proposed model was verified by increasing oxygen flow rate to gasifier in order to validate the dynamic state of the system. As a result, trends of major process variables were resonable when oxygen flow rate increased by 5% from the steady state value. Coal flow rate to gasifier and quench gas flow rate were increased, and flow rate of liquid slag was also increased. The proposed model in this study is able to be used for the prediction of gasification of various coals and dynamic analysis of coal gasification.