• Title/Summary/Keyword: Mass Balance Model

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Mass Balance Analysis of Air pollutants on Central Part of Korea by Acid Deposition Model (산성우모델에 의한 우리나라 중부지방의 오염물질 수지분석)

  • 이종범;조창래
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 1999.10a
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    • pp.405-406
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    • 1999
  • 산성침착모델은 산성강우 및 광화학 오염물질 농도를 예측할 수 있어 대기질 개선을 위한 도구로서 연구, 개발되어 왔으며, 미국과 캐나나 간의 산성우 문제 해결을 위하여 개발된 RADM(Regional Acid Deposition Model : 지역규모 산성 침착모델)은 우리나라를 포함한 동북아시아 지역에 적용을 위한 연구가 수행된 바 있다(이종범 등, 1999; 환경부, 1998).(중략)

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A Simple Condensation Model on the Vapor Jets in Subcooled Water (과냉각수로 방출되는 증기제트의 응축모델)

  • Kim, Hwan-Yeol;Ha, Kwang-Soon;Bae, Yoon-Yeong;Park, Jong-Kyun;Choi, Sang-Min
    • Proceedings of the KSME Conference
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    • 2001.06d
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    • pp.240-245
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    • 2001
  • Phenomena of direct contact condensation (DCC) heat transfer between steam and water are characterized by the transport of heat and mass through a moving steam/water interface. Application of the phenomena of DCC heat transfer to the engineering industries provides some advantageous features in the viewpoint of enhanced heat transfer. This study proposes a simple condensation model on the steam jets discharging into subcooled water from a single horizontal pipe for the prediction of the steam jet shapes. The analysis model was derived from the mass, momentum and energy equations as well as a thermal balance equation with condensing characteristics at the steam/water interface for the axi-symmetric coordinates. The extremely large heat transfer rate at the steam/water interface was reflected in the effective thermal conductivity estimated from the previous experimental results. The analysis results were compared with the experimental ones. The analysis model predicted that the steam jet shape (i. e. radius and length) was increasing as the steam mass flux and the pool temperature were increasing, which was similar in trend to that observed in the experiment.

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Estimation of Mean Air Exchange Rate and Generation Rate of Nitrogen Dioxide Using Box Model in Residence (주택에서 Box Model을 이용한 평균 환기율 및 이산화질소 발생량 추정)

  • Bae, Hyeon Ju;Yang, Won Ho;Son, Bu Sun;Kim, Dae Won
    • Journal of Environmental Science International
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    • v.13 no.7
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    • pp.645-653
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    • 2004
  • Indoor air quality is affected by source strength of pollutants, ventilation rate, decay rate, outdoor level, and so on. Although technologies measuring these factors exist directly, direct measurements of all factors are not always practical in most field studies. The purpose of this study was to develop an alternative method to estimate these factors by application of multiple measurements. For the total duration of 30 days, daily indoor and outdoor $NO_2$ concentrations were measured in 30 houses in Brisbane, Australia, and for 21 days in 40 houses in Seoul, Korea, respectively. Using a box model by mass balance and linear regression analysis, penetration factor (ventilation divided by sum of air exchange rate and deposition constant) and source strength factor (emission rate divided by sum of air exchange rate and deposition constant) were calculated, Sub-sequently, the ventilation and source strength were estimated. In Brisbane, the penetration factors were $0.59\pm0.14$ and they were unaffected by the presence of a gas range. During sampling period, geometric mean of natural ventilation was estimated to be $l.l0\pm1.5l$ ACH, assuming a residential $NO_2$ decay rate of 0.8 hr^{-1}$ in Brisbane. In Seoul, natural ventilation was $1.15\pm1.73$ ACH with residential $NO_2$ decay rate of 0.94 hr^{-1}$ Source strength of $NO_2$ in the houses with gas range $(12.7\pm9.8$ ppb/hr) were significantly higher than those in houses with an electric range $(2.8\pm2,6$ ppb/hr) in Brisbane. In Seoul, source strength in the houses with gas range were $l6.8\pm8.2$ ppb/hr. Conclusively, indoor air quality using box model by mass balance was effectively characterized.

Analysis of Crushing/Classification Process for Recovery of Black Mass from Li-ion Battery and Mathematical Modeling of Mixed Materials (폐배터리 블랙 매스(black mass) 회수를 위한 파쇄/분급 공정 분석 및 2종 혼합물의 수학적 분쇄 모델링)

  • Kwanho Kim;Hoon Lee
    • Resources Recycling
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    • v.31 no.6
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    • pp.81-91
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    • 2022
  • The use of lithium-ion batteries increases significantly with the rapid spread of electronic devices and electric vehicle and thereby an increase in the amount of waste batteries is expected in the near future. Therefore, studies are continuously being conducted to recover various resources of cathode active material (Ni, Co, Mn, Li) from waste battery. In order to recover the cathode active material, black mass is generally recovered from waste battery. The general process of recovering black mass is a waste battery collection - discharge - dismantling - crushing - classification process. This study focus on the crushing/classification process among the processes. Specifically, the particle size distribution of various samples at each crushing/classification step were evaluated, and the particle shape of each particle fraction was analyzed with a microscope and SEM (Scanning Electron Microscopy)-EDS(Energy Dispersive Spectrometer). As a result, among the black mass particle, fine particle less than 74 ㎛ was the mixture of cathode and anode active material which are properly liberated from the current metals. However, coarse particle larger than 100 ㎛ was present in a form in which the current metal and active material were combined. In addition, this study developed a PBM(Population Balance Model) system that can simulate two-species mixture sample with two different crushing properties. Using developed model, the breakage parameters of two species was derived and predictive performance of breakage distribution was verified.

Calibration and Sensitivity Analysis of the RICEWQ Model (RICEWQ 모형의 보정 및 민감도 분석)

  • Chung, Sang-Ok;Park, Ki-Jung;Son, Seung-Ho
    • Journal of The Korean Society of Agricultural Engineers
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    • v.50 no.2
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    • pp.3-10
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    • 2008
  • The main objectives of this study are to calibrate the RICEWQ model with Korean field data and then analyse the sensitivity of the parameters to identify sensitive parameters. The RICEWQ is widely used to predict pesticide fate in a paddy plot. An experimental paddy plot of 0.2 ha($100{\times}20\;m$) at Seobyeon-dong, Daegu, Korea was selected, and field observations for water and pesticide balance were performed from 4 June to 2 September 2006. The molinate, which is a herbicide widely used for weed control in rice culture, was selected. The RICEWQ model was successfully calibrated both for the water and pesticide mass balance. The calibrated model showed a RMSE of 0.537 cm for ponded water depths and a RMSE of 0.036 mg/L for the molinate concentrations in the ponded water. The most sensitive parameters for molinate concentrations in ponded water were the metabolism degradation rate in water, volatilization coefficient, and release rate for slow release formulation. In contrast, the RICEWQ model was not sensitive to parameters such as hydrolysis degradation rate in water and degradation rate in unsaturated soil.

General Derivation of Two-Fluid Model (2상 유동 모델의 일반적인 유도)

  • Hee Cheon No
    • Nuclear Engineering and Technology
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    • v.16 no.1
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    • pp.1-10
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    • 1984
  • General time-volume averaged conservation equations and jump conditions for two-phase flows are derived here. The time-averaged equations for a single phase region in two-phase flow are obtained from local instant balance equations by a technique often used for single phase turbulent flow equations. The results obtained by integrating the time averaged equations over a flow volume are spatially averaged twice; first, they are averaged over a single phase region of the k-th phase and then averaged over the total volume of the k-th phase, in a flow volume. The mass, momentum, and energy conservation equations are obtained from the general time-volume averaged equations. The advantages of the present model are explained by comparing it with Ishii's model (1) and Banerjee's model (2). Finally, the assumptions and approximate terms of the equations of the THERMIT-6S are clarified.

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Estimation of Nitrogen Mass Balance in Sihwa-ho Watershed, 2010 (2010년 시화호유역 질소 물질수지 산정)

  • Choi, Jung-Kil;Lee, Hyo-Jin;Kim, Tea-ha;Choi, Jea-hun;Woo, Jun-Sik;Lee, Kang-Wung
    • Journal of Environmental Science International
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    • v.27 no.3
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    • pp.179-193
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    • 2018
  • Nitrogen budgets in Sihwa-ho in 2010 were estimated using a mass balance approach. Major nitrogen fluxes sources can be divided into three sections: cities, agricultural area, and forest. Surplus nitrogen 2,030~2,214 ton/yr (2,123 ton/yr in average) was discharged to Sihwa Lake. 20% of the surplus nitrogen is removed from the wetland and 60% is removed tidal flats. Therefore net nitrogen discharge from Sihwa basin is estimated to be 650~708 ton/yr (679 ton/yr in average). Wet and dry nitrogen deposition and load from non-point sources ware estimated to be 97 ton/yr and 69 ton/yr, deposition is using CAMx model. So estimated total nitrogen discharge into Sihwa-ho was 817~875 ton/yr (846 ton/yr in average). The atmospheric load explains 11.1~11.9% (11.5% in average) of the total nitrogen load Sihwa-ho.

Estimation of Transport and Mass balance of Tributyltin in Masan Bay (마산만의 Tributyltin 거동 및 물질수지 산정)

  • Kim Dong-Myung
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.5 no.4
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    • pp.48-56
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    • 2002
  • It was peformed to estimate the sensitivity analyses and mass balance for tributyltin in Masan Bay, using the model builded by stella program. The results of the sensitivity analysis for dissolved tributyltin and tributyltin in the particulate organic carbon showed that not only organic carbon partition coefficient but also settling rate is important. In the case of tributyltin in phytoplankton, bioconcentration factor of phytoplankton is most important. The results of the mass balance showed that standing stocks of tributyltin in water, in phytoplankton and in particulate organic carbon are 3.29×10⁴g, 1.16×10²g and 3.17×10³g, respectively. In the case of flux, partition to particulate organic carbon showed most high value, 1.64×10³g/4ay, and next were deposition to sediment, 1.64×10³g/day and transportation to open sea by tide, 1.64×10³g/day.

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Modeling Dynamics of Nonconservative Pollutants in Streams with Pools and Riffles

  • Seo, Il-Won;Yu, Dae-Young
    • Proceedings of the Korea Water Resources Association Conference
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    • 1993.07a
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    • pp.175-182
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    • 1993
  • The complex nature of low flow transport and tranformation of nonconservative pollutants in natural streams with pools and riffles has been investigated using a numerical solution of a proposed mathematical model that is based on a set of mass balance equations describing hydrodynamic processes (advection, dispersion, and mass exchange mechanicms in streams and in storage zones) and chemical processes (reaction or decay). In this study, a mathematical model (named "Storage-Transformation Model") has been developed to predict adequately the non-Fickian nature of mixing and transformation mechanisms for decaying substances in natural streams under low flow conditions. Comparisons between the concentration-time curves predicted usingthe proposed model and the measured stream data shows that the Storage-Transformation Model yields better agreements in the goneral shape, peak concentration and time to peak than the 1-D dispersion model. The result of this study also demonstrates the differences between transport in pool-and-riffle streams versus transport in more uniform channels. The proposed model shows significant improvement over the conventional 1-D disperision model in predicting natural mixing and stroage processes in streams through pools and riffles.

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Application of Computer-coupled Mass Spectrometer for Continuous On-line Monitoring of Cell Growth and Growth Rate (세포증식과 증식속도의 On-line Monitoring을 위한 Computer- coupled Mass Spectrometer의 응용)

  • 남수완;최춘순;김정회
    • Microbiology and Biotechnology Letters
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    • v.17 no.3
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    • pp.241-246
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    • 1989
  • Continuous on-line monitoring of cell concentration and growth rate in aerobic batch fermentation process was carried out by analyzing the exhaust gas composition of tormentor with a quadrupole mass spectrometer. From the mass spectrometric analyses of major gaseous components, i.e. $N_2$, $O_2$, $CO_2$ and $H_2O$, and the material balance equations for oxygen and carbon dioxide, oxygen uptake rate (OUR) rind carbon dioxide evolution rate (CER) were instantaneously calculated using a computer (16-bit IBM PC-AT) interfaced to a quadrupole mass spectrometer. The calculated OUR and CER data were used for the estimation of cell concentration and growth rate of Candida utilis during batch culture. It was found that the cell concentration could be satisfactorily estimated from the data of OUR arid CER during the culture and this method could be successfully und for the continuous monitoring of cell growth and growth rate.

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