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Dynamic Response of Charge Transfer and Recombination at Various Electrodes in Dye-sensitized Solar Cells Investigated Using Intensity Modulated Photocurrent and Photovoltage Spectroscopy

  • Kim, Gyeong-Ok;Ryu, Kwang-Sun
    • Bulletin of the Korean Chemical Society
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    • v.33 no.2
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    • pp.469-472
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    • 2012
  • Intensity modulated photocurrent spectroscopy and intensity modulated photovoltage spectroscopy were investigated to measure the dynamic response of charge transfer and recombination in the standard, $TiCl_4$-treated and the combined scattering layer electrode dye-sensitized solar cells (DSSCs). IMPS and IMVS provided transit time ($\tau_n$), lifetime ($\tau_r$), diffusion coefficient ($D_n$) and effective diffusion length ($L_n$). These expressions are derived that generation, collection, and recombination of electrons in a thin layer nanocrystalline DSSC under conditions of steady illumination and with a superimposed small amplitude modulation. In this experimental, IMPS/IMVS showed that the main effect of $TiCl_4$ treatment is to suppress the recombination of photogenerated electrons, thereby extending their lifetime. And the Diffusion coefficient of combined scattering layer electrode is $6.10{\times}10^{-6}$ higher than that of the others, resulting in longer diffusion length.

A Study of CIGS Coated Thin-Film Layer using Doctor Blade Process (Doctor blade를 이용한 용액형 CIGS 균일 코팅에 관한 연구)

  • Yu, Jong-Su;Yoon, Seong Man;Kim, Do-Jin;Jo, Jeongdai
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.06a
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    • pp.93.2-93.2
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    • 2010
  • Recently, printing and coating technologies application fields have been expanded to the energy field such as solar cell. One of the main reasons, why many researchers have been interested in printing technology as a manufacturing method, is the reduction of manufacturing cost. In this paper, We fabricated CIGS solar cell thin film layer by doctor blade methods using synthesis of CIS precursor nanoparticles ink on molybdenum (Mo) coated soda-lime glass substrate. Synthesis CIS precursor nanoparticles ink fabrication was mixed Cu, In, Se powder and Ethylenediamine, using microwave and centrifuging. Using multi coating process as we could easily fabrication a fine flatness CIS thin-film layer ($0.7{\sim}1.35{\mu}m$), and reduce a manufacture cost and process steps. Also if we use printing and coating method and solution process in each layer of CIGS solar cell (electrode, buffer), it is possible to fabricate all printed thin-film solar cell.

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Characteristics of nocturnal maximum ozone and meteorological relevance in Pusan coastal area (부산 연안역의 야간 고농도 오존 발생 특성과 기상학적 관련성)

  • 전병일
    • Journal of Environmental Science International
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    • v.8 no.3
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    • pp.287-292
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    • 1999
  • This study was performed to investigate the characteristics of nocturnal maxiumu ozone occurrence and the meteorological relevance using to hourly ozone data and meteorological data for 1995~1996 in Pusan coastal area. Kwangbokdong showed the highest occurrence of nocturnal maximum ozone as 36.9%, and Deokcheondong showed the lowest occurrence(9.2%) for research period in Pusan. The occurrence rates of nocturnal maximum ozone concentration were decreased toward land area. The low maximum temperature, high minimum temperature, low diurnal range, high relative humidity, high wind speed, high could amount, low sunshine and low radiation were closely related to the main meteorological characteristics occuring the nocturnal maximum concnetration of ozone. It was shown that normal daily variation of ozone concentration by strong photochemical reaction at the before day of nocturnal maximum ozone. The concnetration of nocturnal maximum ozone were occured by entrainment of ozone from the upper layer of developed mixing layer. There are no ozone sources near the ground at night, so that the nighttime ozone should be entrained from the upper layer by forced convection.

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A Study on Vibration Control of Multi-layer Structure(I) (다층 층상 구조물의 진동제어에 관한 연구 (I))

  • Jeong, Hae-Jong;Byeon, Jeong-Hwan;Yang, Ju-Ho
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.33 no.2
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    • pp.141-148
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    • 1997
  • This paper is concerned with the vibration control of multi-layer structure for ultra-tall buildings and main tower of large bridge etc. We have modeled the multi-layer structure with the distributed mass system as the lumped mass system of two-degree-of-freedom structure and made experimental equipment. The LQ optimal control theory is applied to the design of the control system. The designed control system is simulated by computer. As a result, the LQ regulator showed good vibration control performance with impact excitation.

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The Study on the Composition in Pharmacopunctures of Eight Principles by Gas Chromatography/Mass Spectrometry (Gas Chromatography/Mass Spectrometry를 이용한 팔강약침액 성분에 대한 연구)

  • Kim, Hyub;Ahn, Byung-Soo
    • Journal of Pharmacopuncture
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    • v.11 no.3
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    • pp.79-91
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    • 2008
  • Objective: The purpose of this study was to investigate the composition for pharmacopunctures of eight principles hydrodistillation layer. Methods: The study was determined the hydrodistillation layer for pharmacopunctures of eight principles by hydrodistillation method. The effective components in hydrodistillation layer for pharmacopunctures of eight principles were extracted with ethyl ether or dichloromethane, and then analyzed by Gas Chromatography/Mass Spectrometry(GC/MS). Results: 1. Analyzed pharmacopunctures of eight principles by GC/MS, a lot of differences according to extraction solvent by each pharmacopunctures of eight principles and specific peak patterns were seen. 2. The main compound in pharmacopunctures of eight principles was a kind of hexaoxacyclohydrocarbon that has long hydrocarbon chain.

A Sutdy on Improvement of Geomeric Accuracy by using Fuzzy Algorithm in Surface Grinding (퍼지 알고리즘을 이용한 평면연삭의 형상정도 향상에 관한 연구)

  • 천우진;김남경;하만경;송지복
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 1993.10a
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    • pp.149-154
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    • 1993
  • In heavy grinding that is on of the high efficient grinding method, meaningful deformation is generated by high temperature. So, after machining, geomeric error generated od the workpiece. The most important factor on the geometric error is temperature difference between upper layer and lower layer (T $_{d}$) . Relations between Td and grinding condition and maximum geometric error and grinding condition are obtained by experiment. This relations are used in fuzzy algorithm for improvement geometric accuracy. The main results are follows : (1) The linear relation between maximum geometric error and grinding condition is ovtained by experiment. (2) The linear relation between maximum temperature difference between upper layer and lower layer and grinding condition is ovtained by experiment. (3) Control peth of wheel for improvement geometric accuracy is obtained by using the fuzzy algorithm.m.

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Mathematical Modeling for the Depth of Deformed Layer in Machining (가공변질층 깊이의 수학적 모델링)

  • 박영우
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 1995.10a
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    • pp.247-250
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    • 1995
  • The development and empirical validation of a mathematical model for predicting the depth of deformed layer in a machined surface are presented. The main assumption for develioping this model is that there is a linear relationship between plastic strain and the depth to which it extends. The model relates the work required to shear the workpice material to the work needed to compress the workpiece material ahead of the cutting tool. The results show that the percent difference between the calculated and the measured depth of deformed layer ranges form 4 percent to 19 percent. An improvement of the model is suggested through application of actual distribution data of plastic strain.

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Dynamic Analysis of Sand-Clay Layered Ground Considering Viscous Effect of Clay

  • Kim, Yong-Seong
    • Journal of The Korean Society of Agricultural Engineers
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    • v.48 no.7
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    • pp.45-52
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    • 2006
  • A cyclic viscoelastic-viscoplastic constitutive model for clay is incorporated into an effective stress based seismic response analysis to describe viscous effect of clay layer to sand layer during earthquake. The seismic response against main shock of 1995 Hyogoken Nambu Earthquake is analyzed in the present study. Acceleration responses in both clay layer and just upper liquefiable sand layer are damped due to viscous effect of clay. A cyclic viscoelastic-viscoplastic constitutive model for clay was implemented into a FEM code, and $Newmark{\beta}$ method was employed for the time discretization in the finite element formulation. Seismic responses were simulated by numerical method with recorded data at Port Island, Kobe, Japan. As results of this study, it was found that a cyclic viscoelastic-viscoplastic constitutive model can give good description of dynamic behavior characteristics including viscoelastic effect.

A novel anti-glare layer on a polarizer for better image and durability

  • Lee, J.H.;Kim, H.J.;Park, C.H.;Kwon, K.S.;Choi, H.C.;Kang, I.B.
    • 한국정보디스플레이학회:학술대회논문집
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    • 2006.08a
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    • pp.1429-1431
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    • 2006
  • We developed new anti-glare(AG) layer which has improved image quality and solved mechanical problems. Conventional silica-type AG has some restrictions related to sparkling, causing mechanical defects. The new anti-glare layer is designed with adjusted optical factors and polymer type. Therefore new anti-glare layer meets two main characteristics at once using unmatched optical property between scattering in material and surrounding.

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