• Advanced Composite Materials
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• 제18권2호
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• pp.153-166
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• 2009

A matrix method for evaluating effective electro-magneto-thermo-elastic properties of a generally anisotropic multilayered composite is presented. Physical variables are categorized into two groups: one that satisfies the continuity across the interface between layers and another that satisfies an average inter-layer compatibility (which is also exact). The coupled electro-magneto-thermo-elastic constitutive equation is accordingly reassembled into submatrices, which leads to the derivation of concise and exact matrix expressions for effective properties of a multilayered composite having the coupled physical effects. Comparing the results for a purely elastic multiplayer with those from other theoretical approaches validates the developed method. Examples are given for a PZT-graphite/epoxy composite and a $BaTiO_3-CoFe_2O_4$ multiplayer which exhibit piezo-thermoelastic and magnetoelectric properties, respectively. The result shows how a strong magnetoelectric effect can be achieved by combining piezoelectric and piezomagnetic materials in a multilayered structure. The magnetoelectric coefficient of the $BaTiO_3-CoFe_2O_4$ multiplayer is compared with those for fibrous and particulate composites fabricated with the same constituents.

• 한국세라믹학회지
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• 제39권9호
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• pp.813-817
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• 2002

Magnetoelectric(ME) laminate composites of $Pb(Mg_{1/3}Nb_{2/3})O_3-PbTiO_3 (PMN-PT)$ and Terfenol-D were prepared by sandwiching single crystals of PMN-PT between Terfenol-D disks. The magnetoelectric voltage coefficient (dE/dH) of the composite was determined to be 10.30 V/cm${\cdot}$Oe, at 1 kHz and under a dc magnetic bias of 0.4 T. The value of dE/dH is ∼80 times higher than either that of naturally occurring magnetoelectrics or artificially-grown magnetoelectric composites. This superior magnetoelectric voltage coefficient is attributed to the high piezoelectric voltage constant as well as the high elastic compliance of PMN-PT single crystal and the large magnetostrictive response of Terfenol-D.

• 세라미스트
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• 제23권1호
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• pp.38-53
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• 2020

Magnetoelectric (ME) composites composed of magnetostrictive and piezoelectric materials derive interfacial coupling of magnetoelectric conversion between magnetic and electric properties, thus enabling to detect ultra-low magnetic field. To improve the performance of ME composite sensors, various research teams have explored adopting highly efficient magnetostrictive and piezoelectric phases, tailoring of device geometry/structure, and developing signal process technique. As a result, latest ME composites have achieved not only outstanding ME conversion coefficient but also sensing of ultra-low magnetic field below 1pT. This article reviews the recent research trend of ME composites for sensing of ultra-low magnetic field.

• 한국전기전자재료학회논문지
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• 제23권11호
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• pp.869-874
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• 2010

Magnetoelectric composites with compositions (1-x)[0.5PZT-0.25PNN-0.25PZN](ferroelectric) - x[$(Ni_{0.9}Zn_{0.1})Fe_2O_4$](ferrite) in which x varies as 0, 0.1, 0.2, 0.4, 0.6, 0.8, 1.0 were prepared by conventional ceramic process. The presence of two phases (ferroelectric phase with large grain and ferrite phase with small grain) in the particulate ceramic composites was confirmed by XRD, SEM and EDX. The ferroelectric and magnetic properties of the composites were studied by measuring the P-E and M-H hysterisis loop on the composite composition (x=0, 0.1, 0.2, 1), they were strongly affects of the phase content in composite. The magnetoelectric votage was measured as a function of DC magnetic field and the maximum magnetoelectric voltage coefficient of 14 mV/cm Oe was observed in x=0.2(80 mol% ferroelectric and 20 mol% ferrite phase).

• Journal of Magnetics
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• 제16권3호
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• pp.271-275
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• 2011

This paper proposes a magnetoelectric (ME) composite transducer structure consisting of a magnetostrictive H-type Fe-Ni fork substrate and piezoelectric PZT plates. The fork composite structure has a higher ME voltage coefficient compared to other ME composite structures due to the higher quality (Q) factor. The ME sensitivity of the fork structure reaches 12 V/Oe (i.e., 150 V/cm Oe). The fork composite with two PZT plates electrically connected in series exhibits over 5 times higher ME voltage coefficient than the output of the rectangle structure in the same size. The experiment shows the composite of a Fe-Ni fork substrate and PZT plates has a significantly enhanced ME voltage coefficient and a higher ME sensitivity relative to the prior sandwiched composite laminates. By the use of a lock-in amplifier with 10 nV resolution, this transducer can detect a weak magnetic field of less than $10^{-12}$ T. This transducer can also be designed for a magnetoelectric energy harvester due to its passive high-efficiency ME energy conversion.

• 한국전기전자재료학회논문지
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• 제34권4호
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• pp.229-241
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• 2021

Since 2010, polymer-based magnetoelectric (ME) composites have been developed with detailed investigations of multiferroic properties such as piezoelectric, magnetostrictive, and magnetoelectric, etc. In particular, as a piezoelectric polymer, poly(vinylidene fluoride) and its co-polymers have been widely used in ME composites for energy harvesting, health monitoring, environment treatment, and bio-medical applications. In this study, main research trend and selected experimental results of polymer-based ME composites are briefly reviewed with respect to composite structure as well as application field. A conclusion was drawn that the polymer-based ME composites would be feasible as flexible devices or functional membranes in the near future.

• 센서학회지
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• 제22권6호
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• pp.379-386
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• 2013

The influences of the load resistance $R_L$ on the magnetoelectric (ME) characteristics of $NiZnFe_2O_4+PZT$ composite were investigated in the non-resonance frequency range. The ME coefficient peak increases with increasing $R_L$, but the frequency indicating the ME coefficient peak decreases with increasing $R_L$. The maximum output power peak is approximately $9.3{\times}10^{-10}mW/Oe$ near $R_L=3.3M{\Omega}$ at f=280 Hz, and the ME coefficient seems to be saturated at $R_L>20M{\Omega}$. This frequency shift effect of $R_L$ shows that the frequency range for an ME sensor application can be modulated with the appropriate value of $R_L$. The ME output voltage has a good linear response to the ac field Hac and shows fair stability over a range of temperatures. The measured non-linearity of this sample is approximately 0.8%. This sample will allow for a low-strength magnetic ac-field sensor. The result from this sample will serve as basic data for a signal-processing circuit system.

• 한국전기전자재료학회논문지
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• 제34권6호
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• pp.480-486
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• 2021

Magnetoelectric (ME) composite is composed of a piezoelectric material and a magnetostrictive material. Among various ME structures, 2-2 type layered ME composites are anticipated to be used as high-sensitivity magnetic field sensors and energy harvesting devices especially operating at its resonance modes. Rosen type piezoelectric transducer using piezoelectric material is known to amplify a small electrical input voltage to a large electrical output voltage. The output voltage of these Rosen type piezoelectric transducers can be further enhanced by modifying them into ME composite structures. Herein, we fabricated Rosen type ME composites by sandwiching Rosen type PMN-PZT single crystal between two Ni layers and studied their ME coupling. However, the voltage step-up ratio at the resonance frequency was found to be smaller than the value calculated with α_ME value. The ATILA FEA (Finite Elements Analysis) simulation results showed that the position of the nodal point was changed with the presence of a magnetostrictive layer. Thus, while designing a Rosen type ME composite with high performance in a resonant driving situation, it is necessary to optimize the position of the nodal point by optimizing the thickness or length of the magnetostrictive layer.

• Journal of Magnetics
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• 제20권4호
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• pp.347-352
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• 2015

The magnetoelectric (ME) characteristics for Terfenol-D/PZT laminate composite dependence on bias magnetic field is investigated. At low frequency, ME response is determined by the piezomagnetic coefficient $d_{33,m}$ and the elastic compliance $s_{33}^H$ of magnetostrictive material, $d_{33,m}$ and $s_{33}^H$ for Terfenol-D are inherently nonlinear and dependent on $H_{dc}$, leading to the influence of $H_{dc}$ on low-frequency ME voltage coefficient. At resonance, the mechanical quality factor $Q_m$ dependences on $H_{dc}$ results in the differences between the low-frequency and resonant ME voltage coefficient with $H_{dc}$. In terms of ${\Delta}E$ effect, the resonant frequency shift is derived with respect to the bias magnetic field. Considering the nonlinear effect of magnetostrictive material and $Q_m$ dependence on $H_{dc}$c, it predicts the low-frequency and resonant ME voltage coefficients as a function of the dc bias magnetic field. A good agreement between the theoretical results and experimental data is obtained and it is found that ME characteristics dependence on $H_{dc}$ are mainly influenced by the nonlinear effect of magnetostrictive material.

• Journal of Magnetics
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• 제16권2호
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• pp.157-160
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• 2011

The magnetostrictive material is magnetized in magnetic field and produces a nonuniform demagnetizing field inside and outside it. The demagnetization is decided by the permeability of magnetostrictive material and its size. The magnetoelectric performances are determined by the synthesis of the applied and demagnetizing fields. An analytical model is proposed to predict the magnetoelectric voltage coefficient (MEVC) of magnetostrictive/piezoelectric laminate composite using equivalent circuit method, in which the nonuniform demagnetizing field is taken into account. The theoretical and experimental results indicate that the MEVC is positively connected with the permeability and the piezomagnetic coefficient of magnetostrictive material. To obtain the maximum MEVC, both the permeability and the piezomagnetic coefficient of magnetostrictive material should be taken into account in selecting the suitable magnetostrictive material.