• Title/Summary/Keyword: Magnetic material

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Production of 4-Ethyl Malate through Position-Specific Hydrolysis of Photobacterium lipolyticum M37 Lipase

  • Lim, Chae Ryeong;Lee, Ha young;Uhm, Ki-Nam;Kim, Hyung Kwoun
    • Journal of Microbiology and Biotechnology
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    • v.32 no.5
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    • pp.672-679
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    • 2022
  • Microbial lipases are used widely in the synthesis of various compounds due to their substrate specificity and position specificity. 4-Ethyl malate (4-EM) made from diethyl malate (DEM) is an important starting material used to make argon fluoride (ArF) photoresist. We tested several microbial lipases and found that Photobacterium lipolyticum M37 lipase position-specifically hydrolyzed DEM to produce 4-EM. We purified the reaction product through silica gel chromatography and confirmed that it was 4-EM through nuclear magnetic resonance analysis. To mass-produce 4-EM, DEM hydrolysis reaction was performed using an enzyme reactor system that could automatically control the temperature and pH. Effects of temperature and pH on the reaction process were investigated. As a result, 50℃ and pH 4.0 were confirmed as optimal reaction conditions, meaning that M37 was specifically an acid lipase. When the substrate concentration was increased to 6% corresponding to 0.32 M, the reaction yield reached almost 100%. When the substrate concentration was further increased to 12%, the reaction yield was 81%. This enzyme reactor system and position-specific M37 lipase can be used to mass-produce 4-EM, which is required to synthesize ArF photoresist.

Total value recovery in the copper smelting and refining operations

  • Kim Joe. Y.;Kong Bong S.
    • 한국지구물리탐사학회:학술대회논문집
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    • 2003.11a
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    • pp.590-597
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    • 2003
  • Processing and smelting of copper containing sulphide concentrates result in the accumulation of impurities into various process streams. All primary copper smelters and refineries around the world produce significant amounts of slag, dust, sludge, residues and others, which contain copper and precious metals. The recovery of these valuable metals is essential to the overall economics of the smelting process. Physical, chemical and mineralogical characterization of particular slag and Cottrell dusts from primary smelters and $Dor\'{e}$ furnace (TBRC) slag and Pressure Leached Anode slimes from a copper refinery have been carried out to understand the basic behind the recovery processes. Various process options have been evaluated and adapted for the treatment of slag from different smelting furnaces and Cottrell dusts as well as the intermediate products from copper refineries. Besides the hydro- or pyro-metallurgical treatments, the above mentioned physical separation options such as magnetic, gravity separation, flotation and precipitation flotation processes have been successfully identified and adapted as the possible process options to produce a Cu-rich or precious metal-rich concentrates for in-house recycling and other valued by-product for further treatment. The results of laboratory, pilot plant and production operations are presented, and incorporation of several alternative flowsheet is discussed in this paper.

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Transport Loss Characteristic of the Bifilar Pancake Type Fault Current Limiting Coil using Coated Conductor (Coated Conductor를 사용한 무유도 팬케이크형 한류 코일의 통전 손실 특성)

  • Park, Dong-Keun;Bang, Joo-Seok;Yang, Seong-Eun;Ahn, Min-Cheol;Sim, Ki-Deok;Yoon, Yong-Soo;Nam, Kwan-Woo;Seok, Bok-Yeol;Ko, Tae-Kuk
    • Progress in Superconductivity and Cryogenics
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    • v.9 no.3
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    • pp.21-25
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    • 2007
  • Superconducting fault current limiter (SFCL) is attractive apparatus to reduce fault current in power grid. Since it is applied to the alternating current (AC) power line, the SFCL has losses in the normal operation. Recently, coated conductor (CC) is noticeable material employed for resistive bifilar winding type SFCL in many research groups. Bifilar structure is expected to have low AC loss by magnetic field offset as compared with the single tape structure in the same length. This paper reports about characteristic of bifilar pancake type coil for SFCL application in AC loss aspect. The bifilar coil is wound using CC with facing on HTS sides each other. Transport AC loss measurement and characteristic analysis of the bifilar coil using CC have been performed at 77K. The test results are compared with the Norris equations and the test results of non-inductively wound paralleled solenoid type coil which is suggested and tested in this group at present.

An analytical study on free vibration of magneto electro micro sandwich beam with FG porous core on Vlasov foundation

  • Kazem Alambeigi;Mehdi Mohammadimehr;Mostafa Bamdad
    • Advances in nano research
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    • v.15 no.5
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    • pp.423-439
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    • 2023
  • The aim of this paper is to investigate the free vibration behavior of the micro sandwich beam composing of five layers such as functionally graded (FG) porous core, nanocomposite reinforced by carbon nanotubes (CNTs) and piezomagnetic/piezoelectric layers subjected to magneto electrical potential resting on silica aerogel foundation. The effect of foundation has been taken into account using Vlasov model in addition to rigid base assumption. For this purpose, an iterative technique is applied. The material properties of the FG porous core and FG nanocomposite layers are considered to vary throughout the thickness direction of the beams. Based on the Timoshenko beam theory and Hamilton's principle, the governing equations of motion for the micro sandwich beam are obtained. The Navier's type solution is utilized to obtain analytical solutions to simply supported micro sandwich beam. Results are verified with corresponding literatures. In the following, a study is carried out to find the effects of the porosity coefficient, porous distribution, volume fraction of CNT, the thickness of silica aerogel foundation, temperature and moisture, geometric parameters, electric and magnetic potentials on the vibration of the micro sandwich beam. The results are helpful for the design and applications of micro magneto electro mechanical systems.

A Study on Design of an Electromagnetic and Optical Characteristics in Transparent Conductor Coated Structures (투명 전도성 코팅체의 전자기적, 광학적 성능 설계 및 분석에 관한 연구)

  • Sung Sil Cho;Young Joon Yoon;Min Je Hwang;Kwang Sik Choi;Ic Pyo Hong
    • Journal of the Korea Institute of Military Science and Technology
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    • v.27 no.1
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    • pp.15-23
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    • 2024
  • In order to avoid the high observability due to the cavity resonance or electromagnetic wave leakages from the bridge of a battleship or the cockpit of an aircraft, this paper presents a transparent conductive oxide coated structure to prevent the incoming/outgoing electromagnetic waves. Currently, most of the RCS reduction technologies were focused on radar absorbing material such as paints based on conductive or magnetic materials in the fuselage, and there is not much research on countermeasures for achieving the low observability of materials that required optical transparency in actual weapon systems. In this study, the transmission/reflection and absorption performance of the ITO coated structure according to the change of the surface resistance of the transparent conductor were analyzed. Finally, the relationship between the electromagnetic and optical characteristics was established through fabrication and measurement.

Synthesis and physical properties of Pb10-xCux(PO4)6O: A weak diamagnetic material

  • Yoonseok Han;Taehee Lee;Junwon Rhie;Jaegu Song;Seung-Yeop Paek;Seokmin Choi;Yongmin Kim;Sungmin Park;Hanoh Lee;Tuson Park
    • Progress in Superconductivity and Cryogenics
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    • v.26 no.2
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    • pp.5-8
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    • 2024
  • Recently, Lee et al. claimed that LK-99 isthe first room-temperature superconductor at ambient pressure, which quickly captured the attention of both the scientific community and the general public. We tried to replicate Pb10-xCux(PO4)6O, called as LK-99, and characterized its physical properties by measuring the electrical resistance and Meissner effect. The electrical resistance results for different batches exhibited structural phase transitions at different temperatures, and the magnetic measurements indicated weak diamagnetism at 300 K, which is weaker than that of water. Taken together with the structural analysis, these results suggest that the resistivity transitions are incurred by Cu-S compound generated as a byproduct during the synthesis of LK-99 and LK-99 is not a room-temperature superconductor.

An Experimental Study on the Development of Electromagnetic Shielding Concrete Wall for Shielding High-altitude Electromagnetic Pulse (HEMP) (고고도 전자기파(HEMP)차폐를 위한 전자파 차폐 콘크리트 벽체 개발에 관한 실험적 연구)

  • Choi, Hyun-Jun;Kim, Hyung-Chul;Lim, Sang-Woo;Lee, Han-Seung
    • Journal of the Korea Concrete Institute
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    • v.29 no.2
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    • pp.169-177
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    • 2017
  • Rather than causing damage from heat, blast, and radiation of a regular nuclear weapon, recently, it is predicted that North Korea has been inventing high altitude electromagnetic pulse (HEMP) missile in order to incapacitate electronic equipment. HEMP shielding facility is used for military purpose today. Despite the electromagnetic shielding effects from high quality compression plates, problems may include such as the possibility of electromagnetic influx resulting in the welding of the compression plates, and difficulties and high cost of construction. Therefore, in this study, a high electrical conducting material was added to the concrete experimental subject to ensure the shielding effect through electromagnetic waves to for the concrete structure, instead of building a shielding facility separately for the structure. Also, among the experimental subjects, 100 ${\mu}m$ of Iron-Aluminum alloy metal spraying coat was applied to two types with the highest shielding effect, and to two types with the lowest shielding effect. The result of the experiment indicates that experimental subjects added with a high electrical conductivity material did not meet the minimum shielding criteria of MIL-STD-118-125-1 standard, but all the experimental material applied to the metal spraying coating satisfied the minimum shielding criteria. In conclusion, it is considered that 100 µm of Iron-Aluminum alloy metal spraying coat contains high efficiency in the HEMP shielding.

Preparation of Novel Natural Polymer-based Magnetic Hydrogels Reinforced with Hyperbranched Polyglycerol (HPG) Responsible for Enhanced Mechanical Properties (과분지 폴리글리세롤(HPG) 강화를 통해 기계적 물성이 향상된 새로운 천연 고분자 기반 자성 하이드로젤의 제조)

  • Eun-Hye Jang;Jisu Jang;Sehyun Kwon;Jeon-Hyun Park;Yujeong Jeong;Sungwook Chung
    • Clean Technology
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    • v.29 no.1
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    • pp.10-21
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    • 2023
  • Hydrogels that are made of natural polymer-based double networks have excellent biocompatibility, low cytotoxicity, and high water content, assuring that the material has the properties required for a variety of biomedical applications. However, hydrogels also have limitations due to their relatively weak mechanical properties. In this study, hydrogels based on an alginate di-aldehyde (ADA) and gelatin (Gel) double network that is reinforced with additional hydrogen bonds formed between the hydroxyl (-OH) groups of the hyperbranched polymer (HPG) and the functional groups present inside of the hydrogels were successfully synthesized. The enhanced mechanical properties of these synthesized hydrogels were evaluated by varying the amount of HPG added during the hydrogel synthesis from 0 to 25%. In addition, magnetite nanoparticles (Fe3O4 NPs) were synthesized within the hydrogels and the structures and the magnetic properties of the hydrogels were also characterized. The hydrogels that contained 15% HPG and Fe3O4 NPs exhibited superparamagnetic behaviors with a saturation magnetization value of 3.8 emu g-1. These particular hydrogels also had strengthened mechanical properties with a maximum compressive stress of 1.1 MPa at a strain of 67.4%. Magnetic hydrogels made with natural polymer-based double networks provide improved mechanical properties and have a significant potential for drug delivery and biomaterial application.

Effects of Magnetic Resonance Imaging on the Human Body : Analysis of differences according to Dental Implant Material (자기공명영상이 인체에 미치는 영향 : 치아임플란트 재료에 따른 차이 분석)

  • Choe, Dea-yeon;Kim, Dong-Hyun
    • Journal of the Korean Society of Radiology
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    • v.12 no.4
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    • pp.481-489
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    • 2018
  • In MRI examination, when irradiating the human body with RF Pulse to acquire images, the portion of the irradiated RF Pulse energy is absorded into the human body, and this will affect the temperature of the human body. If a metal is inserted into the human body even if the same RF Pulse energy is applied, the SAR value increases and the body temperature changes due to the increase in the electromagnetic wave conductivity of the metal. So we measure and compared with the change in the SAR and temperature in the implant material of the dental implant in Brain MRI examinations. Experiments were performed on a human head model using a 64MHz and 128 MHz RF Pulse frequency generated by a 3.0 Tesla MRI apparatus. And then changed material of dental implants to Titanium and $Al_2O_3$. Using the XFDTD program, the changes in SAR and body temperature around the head were examined. When with Titanium the SAR value and temperature of Brain increased, but with $Al_2O_3$ showed lower SAR and temperature as compared with Titanium. The dental implants were low in SAR and temperature of the head in $Al_2O_3$, which are electrical insulators with low electrical conductivity, compared to Titanium, which is an electrical conductor. It is necessary to study the biologic effect of patient with brain MRI when titanium dental implant material is inserted in the future. Because the maximum value of SAR is much higher than the limit when dental implant material is Titanium. In addition, it is necessary to use an implant of $Al_2O_3$ material to reduce the SAR value and temperature of the Brain in Brain MRI examination.

Magnetic Properties of NixFe100-x(x=40~50) Permalloy Powders and Dust Cores Prepared by Gas-Atomization (가스 분무법으로 제조된 NixFe100-x(x=40~50) 퍼멀로이 분말 및 압분 코아의 자기적 특성)

  • Noh, T.H.;Kim, G.H.;Choi, G.B.;Kim, K.Y.
    • Journal of the Korean Magnetics Society
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    • v.12 no.6
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    • pp.218-223
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    • 2002
  • We investigated the magnetic properties of High Flux-type $Ni_{x}Fe_{100-x}$(x=40∼50, wt.%) permalloy powders and dust cores. The powder was prepared by conventional gas atomization in mass production scale. At the composition of $Ni_{x}Fe_{55}$, saturation magnetization was maximum. In case of lower Ni content than X=45, the $M_{s}$, decreased largely with the decrease in Ni content, which is due to the invar effect. The permeability of compressed powder cores increased with the decrease in Ni content, which was considered to be due to the decrease in the magnetostriction. In addition, the dust core with Ni=45% showed the lowest core loss because of the increase in electrical resistivity leading to the low eddy current loss. From the better frequency dependence of permeability, larger Q value and superior DC bias characteristics of Ni=45% than those of Ni=50% core, it was confirmed that the 45%Ni-55%Fe powder alloy was better material for the dust core than commercial High Flux core materials.