• 제목/요약/키워드: Magnetic composites

검색결과 186건 처리시간 0.026초

Electrical and Magnetic Properties in [La0.7(Ca1-xSrx)0.3MnO3)]0.99/(BaTiO3)0.01 Composites

  • Kim, Geun-Woo;Bian, Jin-Long;Seo, Yong-Jun;Koo, Bon-Heun
    • 한국재료학회지
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    • 제21권4호
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    • pp.216-219
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    • 2011
  • Perovskite manganites such as $RE_{1-x}A_xMnO_3$ (RE = rare earth, A = Ca, Sr, Ba) have been the subject of intense research in the last few years, ever since the discovery that these systems demonstrate colossal magnetoresistance (CMR). The CMR is usually explained with the double-exchange (DE) mechanism, and CMR materials have potential applications for magnetic switching, recording devices, and more. However, the intrinsic CMR effect is usually found under the conditions of a magnetic field of several Teslas and a narrow temperature range near the Curie temperature ($T_c$). This magnetic field and temperature range make practical applications impossible. Recently, another type of MR, called the low-field magnetoresistance(LFMR), has also been a research focus. This MR is typically found in polycrystalline half-metallic ferromagnets, and is associated with the spin-dependent charge transport across grain boundaries. Composites with compositions $La_{0.7}(Ca_{1-x}Sr_x)_{0.3}MnO_3)]_{0.99}/(BaTiO_3)_{0.01}$ $[(LCSMO)_{0.99}/(BTO)_{0.01}]$were prepared with different Sr doping levels x by a standard ceramic technique, and their electrical transport and magnetoresistance (MR) properties were investigated. The structure and morphology of the composites were studied by X-ray diffraction (XRD) and scanning electronic microscopy (SEM). BTO peaks could not be found in the XRD pattern because the amount of BTO in the composites was too small. As the content of x decreased, the crystal structure changed from orthorhombic to rhombohedral. This change can be explained by the fact that the crystal structure of pure LCMO is orthorhombic and the crystal structure of pure LSMO is rhombohedral. The SEM results indicate that LCSMO and BTO coexist in the composites and BTO mostly segregates at the grain boundaries of LCSMO, which are in accordance with the results of the magnetic measurements. The resistivity of all the composites was measured in the range of 90-400K at 0T, 0.5T magnetic field. The result indicates that the MR of the composites increases systematically as the Ca concentration increases, although the transition temperature $T_c$ shifts to a lower range.

자기력이 자기유동 탄성체의 압축 및 동적 특성에 미치는 영향 (Effect of Magnetic Force on the Compressive and Dynamic Properties of Magnetorheological Elastomers)

  • 류상렬;이동주;이종항
    • Composites Research
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    • 제23권1호
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    • pp.17-22
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    • 2010
  • 자기화 분말 함유량과 분말의 배향, 그리고 자기력 세기를 함수로 한 자기유동 탄성체의 압축 및 동적특성에 대해 연구하였다. 시험편은 순수 실리콘과 분말이 불규칙 배향된 실리콘, 축 방향으로 배향된 실리콘 그리고 축 직각 방향으로 배향된 실리콘으로 구분하였다. 탄성체 내에 포함된 분말의 배향을 위해 복합 탄성체의 성형을 자기장 내에서 실시하였다. 압축 및 동적시험은 자기력이 없는 경우와 자기력의 크기를 다르게 제어하는 경우로 구분하여 수행되었다. 복합 탄성체의 탄성율 및 손실계수는 동일한 자기력 세기에서 분말 함유량의 증가에 따라 증가하였다. 축 방향으로 배향된 복합탄성체의 탄성율과 손실계수는 축 직각 방향 배향 혹은 불규칙 배향에 비해 높게 나타났다.

Influence of Machining on Magnetic Properties of Soft Magnetic Composites

  • Igarashi, Kazunori;Miyahara, Masahisa;Morimoto, Koichiro
    • 한국분말야금학회:학술대회논문집
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    • 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part2
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    • pp.1175-1176
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    • 2006
  • Influences of machining on magnetic properties of soft magnetic composites (SMC's) with addition of two kinds of binder, i.e., organic binder and inorganic one, were investigated. Machining does not affect DC magnetic properties of the SMC compacts. This can be ascribed to their particular structure in which the ironpowder particles are highly isolated by the binder. On the other hand, decrease in resistivity and resultant increase in eddy current loss was confirmed in the machined compacts containing inorganic binder. It is supposed that the brittleadditive binder existing between the iron particles is partly broken, and iron-to-iron contact is formed on the machined surface.

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철계 연자성 합금 분말을 함유한 고무 복합재의 전파흡수특성 (Microwave Absorbing Properties of Rubber Composites Containing Soft Magnetic Fe-Alloy Particles)

  • 조한신;김성수
    • 한국분말재료학회지
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    • 제20권2호
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    • pp.125-128
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    • 2013
  • Magnetic and dielectric properties of rubber composites are controlled by using two kinds of high-permeability metal particles with different electrical conductivity (Sendust, Permalloy), and their effect on microwave absorbance has been investigated, focusing on the quasi-microwave frequency band (0.8-2 GHz). Noise absorbing sheets are composite materials of magnetic flake particles of high aspect ratio dispersed in polymer matrix with various filler amount of 80-90 wt.%. The frequency dispersion and magnitude of complex permeability is almost the same for Sendust and Permalloy composite specimens. However, the complex permittivity of the Permalloy composite (${{\varepsilon}_r}^{\prime}{\simeq}250$, ${{\varepsilon}_r}^{{\prime}{\prime}}{\simeq}50$) is much greater than that of Sendust composite (${{\varepsilon}_r}^{\prime}{\simeq}70$, ${{\varepsilon}_r}^{{\prime}{\prime}}{\simeq}0$). Due to the large dielectric permittivity of Permalloy composite, the absorbing band is shifted to lower frequency region. However, the investigation of impedance matching reveals that the magnetic permeability is still small to satisfy the zero-reflected condition at the quasi-microwave frequency band, resulting in a small microwave absorbance lower than 10 dB.

폐 스테인레스강 단섬유로 강화한 알루미늄 복합분말의 자기펄스압 성형 및 소결 특성 (Magnetic Pulsed Compaction and Sintering Characteristics of Al Composite Powders Reinforced with Waste Stainless Steel Short Fibers)

  • 현창용;원철현;박재순
    • 한국분말재료학회지
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    • 제14권6호
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    • pp.380-385
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    • 2007
  • Characteristics of Al-based composites with waste stainless steel short fiber, fabricated by magnetic pulsed compaction and sintering were investigated. The compacts prepared by magnetic pulsed compaction showed high relative density and homogeneous microstructure compared with that by conventional press compaction. The relative density of sintered composites at $430^{\circ}C$ for 1 h exhibited the same value with compacts and decreased with increase in STS short fiber content. The reaction between Al and STS phase was confirmed by the microstructural analysis using EDS. The sintered composites, prepared by magnetic pulsed compaction, showed increased hardness value with increasing STS fiber content. Maximum yield strength of 100 MPa and tensile strength of 232 MPa were registered in the AI-based composite with 30 vol% STS short fiber.

The influence of magnetic field on the alignment of steel fiber in fresh cementitious composites

  • Li, Hui;Li, Lu;Li, Lin;Zhou, Jian;Mu, Ru;Xu, Mingfeng
    • Computers and Concrete
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    • 제30권5호
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    • pp.323-337
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    • 2022
  • This paper proposes a numerical model to simulate the rotational behavior of steel fiber in fresh cement-based materials in the presence of a magnetic field. The results indicate that as the aspect ratio of fiber increases, the required minimum magnetic field intensity to make fiber rotate in viscous fluid increases. The optimal magnetic field intensity is 0.03 T for aligning steel fiber in fresh cement-based materials to ensure that the applying time of the magnetic field can be conducted concurrently with the vibrating process to increase the aligning efficiency. The orientation factor of steel fiber in cement mortar can exceed 0.85 after aligning by 0.03 T of the uniform magnetic field. When the initial angle of the fiber to the magnetic field direction is less than 10°, the magnetic field less than 0.03 T cannot make the fiber overcome the yield stress of fluid to rotate. The coarse aggregate in steel fiber-reinforced concrete is detrimental to the rotation and alignment of the steel fiber. But the orientation factor of ASFRC under the 0.03T of the magnetic field can also exceed 0.8, while the orientation factor of SFRC without magnetic field application is around 0.6.

FeCo 자성 금속 중공형 섬유 고분자 복합재의 전자파 차폐 특성 연구 (Characterization of FeCo Magnetic Metal Hollow Fiber/EPDM Composites for Electromagnetic Interference Shielding)

  • 최재령;정병문;최우혁;조승찬;박가현;김원정;이상관;이상복
    • Composites Research
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    • 제28권6호
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    • pp.333-339
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    • 2015
  • 무전해 도금을 통해 제조한 FeCo 자성 금속 중공형 섬유와 EPDM 고분자를 이용하여 전자파 차폐 복합재를 제작하였다. 열처리 공정을 통하여 섬유의 종횡비를 제어하였으며 중공형 구조로 섬유를 제조한 후, 이를 EPDM 수지에 첨가하여 복합재를 제조하였다. 자성 금속 중공형 섬유의 종횡비가 클수록 낮은 표면 저항 특성과 우수한 전자파 차폐 성능을 나타내었다. 약 $100{\mu}m$ 길이의 자성 금속 중공형 섬유를 이용한 두께 $150{\mu}m$ 전자파 차폐 복합재의 경우 밀도 $1.18g/cm^3$, 약 30 ohm/sq의 표면 저항, 그리고 30 dB의 전자파 차폐 성능을 나타내었다. 이는 종횡비가 큰 섬유에 의한 퍼콜레이션 임계치 이상의 전도성 네트워크 형성과 더불어, 낮은 표면 저항에 기인한 임피던스 차이에 의한 반사 손실 증가, 흡수 손실, 그리고 다중 내부 반사 손실에 의하여 우수한 전자파 차폐 성능을 나타내는 것으로 판단된다.

이축 압출기를 이용하여 제조된 PMMA/MWNT 복합체의 특성 분석 (Characterization of PMMA/MWNT Composites Fabricated by a Twin Screw Extruder)

  • 우종석;이건웅;계형산;신경철;방대석
    • Elastomers and Composites
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    • 제42권3호
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    • pp.151-158
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    • 2007
  • 최근 들어 전기적, 기계적 성질이 우수한 다중벽탄소나노튜브(Multi-Walled Carbon Nanotubes)/고분자 복합재료에 대한 연구가 활발히 진행 중이다. 본 연구에서는 모듈라 치합형 동방형 회전 이축 압출기(Modular Intermeshing Co-Rotating Twin Screw Extruder, L/D=42)를 이용하여 PMMA/MWNT 복합체를 제조하였다. 이렇게 제조된 PMMA/MWNT 복합체의 표면저항을 측정한 결과 MWNT의 함량이 4 wt% 일 때 $10^4{\Omega}/sq$를 나타내어 전자파차폐(Electronic Magnetic Interference) 물질로 응용할 수 있는 가능성을 확인하였다. 그리고 열중량 분석기 (Thermogravimetric Analysis), 시차주사열량계(Differential Scanning Calorimeter)를 이용한 열적특성, 주사전자현미경(Scanning Electron Microscopy)을 통하여 형태학적 변화를 분석하였다. 또한 유변학적 특성을 알아보기 위해 용융흐름지수(Melt Flow Index)를 측정하였다.