• Bulletin of the Korean Chemical Society
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• 제30권5호
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• pp.1021-1025
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• 2009

A novel supramolecular network containing binuclear copper unit $[Cu(phen)_{2}({\mu}-ID\;A)Cu(phen){\cdot}(NO_{3})](NO_{3}){\cdot}4(H_{2}O)$ (1) was synthesized through the self-assembly of iminodiacetic acid ($H_2IDA$) and 1,10-phenanthroline (phen) in the condition of pH = 6. It has been characterized by the infrared (IR) spectroscopy, elemental analysis, single crystal X-ray diffraction, and thermogravimetric analysis (TGA). 1 shows a 2-D supramolecular structure assembled through strong and unique $\pi-\pi$ packing interactions. Density functional theory (DFT) calculations show that theoretical optimized structures can well reproduce the experimental structure. The TGA and powder X-ray diffraction (PXRD) curves indicate that the complex 1 can maintain the structural integrity even at the loss of free water molecules. The magnetic property is also reported in this paper.

• 전기학회논문지
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• 제59권2호
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• pp.306-310
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• 2010

On account of small size and light weight, a high-speed machine is regarded as a key technology for many future applications of drive systems. In high-speed applications, permanent magnet synchronous motors have a number of merits such as high efficiency and high power density. Therefore, they are suitable for driving the air-blower of a fuel cell electric vehicle (FCEV) where space and energy savings are critical. Particularly, a surface-mounted permanent magnet synchronous motor (SPMSM) of them is mainly used as a high-speed machine. However, the motor has a fatal flaw due to a retaining can to maintain the mechanical integrity of a rotor assembly. The can results in the increase of magnetic air-gap length in the SPMSM. Thus, in this paper, an interior permanent magnet synchronous motor (IPMSM) is applied in order to drive the air-blower of FCEV instead of the SPMSM, and the experimental results of two models are compared to verify the capability of the IPMSM for high-speed applications.

• 천문학회보
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• 제36권1호
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• pp.35.2-35.2
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• 2011

We have investigated a coronal jet near the limb on 2010 June 27 by Hinode/X-Ray Telescope (XRT), EUV Imaging Spectrograph (EIS), SDO/Atmospheric Imaging Assembly (AIA), and STEREO. From EUV (AIA and EIS) and soft X-ray (XRT) images we identify the erupting jet feature in cool and hot temperatures. Using the high temporal and multi wavelength AIA images, we found that the hot jet preceded its associated cool jet and their structures are well consistent with the numerical simulation of the emerging flux-reconnection model. From the spectroscopic analysis, we found that the jet structure changes from blue shift to red one with time, which may indicate the helical structure of the jet. The STEREO observation, which enables us to observe this jet on the disk, shows that there was a dim loop associated with the jet. On the other hand, we found that the structure of its associated active region seen in STEREO is similar to that in AIA observed 5 days before. Based on this fact, we compared the jet morphology on the limb with the magnectic fields extrapolated from a HMI vector magnetogram of this active region observed on the disk. Interestingly, the comparison shows that the open and closed magnetic field configuration correspond to the jet and the dim loop, respectively, as the Shibata's jet model predicted.

• 지구물리와물리탐사
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• 제12권1호
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• pp.41-48
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• 2009

자연적인 자기장은 전기 전도도가 높은 물에서는 감쇠한다. 이러한 이유로, 해양 지전류 탐사법에서 장주기(1000 - 100000 초) 자료를 측정하였나. 맨들 구조가 해저 지전류측정의 주된 적용 대상이었다. 반면에 지각구조를 밝히기 위해서, 예를 들어, 메카트러스트 지진지역이나 천연자원조사와 같은 분야에서는 보다 짧은 주기의 전자기장에 대한 자료가 중요하다. 예를 들어 전자의 조사를 위해서는 1000초 보다 자은 주기를 가지는 전자기장 자료가 필요하다. 그러나, 이러한 용도를 위한 적절한 해저 전자력계 (OBEM)가 없기 때문에 높은 샘플링 속도와 조립과 회수 과정을 용이하게 하기 위한 팔-접힘 구조를 가지는 소규모 OBEM과 해저 전위계 (OBE)를 개발하였다. 자기장 측정을 위하여 플럭스게이트 센서를 이용하였다. 개발된 장비의 현장 성능을 평가하기 위한 현장측정이 이루어졌다. 모든 장비는 전자기 측정자료를 획득한 채로 회수되었다. 첫번째 실험의 결과, 개발된 시스템은 동작과 측정 모두 그 기능이 정상적으로 잘 이루어지고 있음을 확인하였다. 돗토리 근해에서의 또 다른 현장실험 결과는 새로운 OBEM과 OBE 시스템으로 획득된 전자기 자료가 탐사 목적에 충분한 양질의 자료라는 주장을 뒷받침해 주었다. 이러한 견과들은 개발된 장비들이 해저면 전자기장 측정에 대한 장비적인 장애를 모두 해결하고 있음을 확증하고 있다.

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2010년도 춘계학술대회 초록집
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• pp.146.2-146.2
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• 2010

PEMFC를 구성하는 여러 부품 중 핵심부품은 MEA(Membrane Electrode Assembly)으로서 실제 연료전지 반응이 일어나며 연료전지의 성능을 결정하는 부품이다. 그러나 PEMFC의 특성 상 촉매로 귀금속인 Pt가 사용됨에 따라 경제성이 확보된 MEA의 성능을 얻기 위해선 현재 Pt 담지량을 0.3mg/$cm^2$ 이하로 크게 감소시키면서 Pt촉매의 고분산화와 미반응 사이트의 감소가 필요하다. 본 연구에서는 Pt 촉매의 미반응 사이트를 줄이고자 전기영동법에 의해 카본전극(carbon black + GDL) 상에 Pt 나노입자를 직접 석출시켜 Pt/C 촉매 전극을 제조 하였다. 본 실험에서는 가장 좋은 Pt 나노입자의 석출거동을 나타낸 30mA/$cm^2$, pH 2, duty cycle 25% 조건을 기준으로 하여 electro-deposition time을 통한 석출량 제어와 carbon paper의 wet proofing 정도에 따른 Pt의 석출거동을 조사하였으며, 종래의 방법으로 제조한 Pt/C 촉매전극의 전기화학적 특성과 비교 분석하였다. 전기영동 석출법에 사용된 Pt나노입자는 $H_2PtCl_6{\cdot}6H_2O$로부터 화학적 환원법으로 합성한 2~3nm 입경을 갖는 Pt콜로이드를 사용하였으며, magnetic stirring과 항온 ($20^{\circ}C$)을 유지하여 실험하였다. 전기영동 석출량 제어는 electro-deposition time을 5~25분까지 5분 간격으로 나누어 실험하였고 카본전극을 구성하는 carbon paper의 wet proofing 정도가 Pt 나노입자 석출거동에 미치는 영향을 조사하기 위하여 20, 40, 60%의 서로 다른 wet proofing 값을 갖는 carbon paper를 사용하여 Pt/C 촉매 전극을 제조하였다. 전기영동법으로 석출된 카본블랙 전극 상 Pt나노입자의 분산도와 담지량는 각각 FE-SEM과 TGA 장비를 사용하여 측정하였고, 제조된 Pt/C 촉매 전극의 전기화학적 촉매 특성은 cyclic voltammetry(CV)법으로 측정하였다.

• 천문학회보
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• 제36권2호
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• pp.89.1-89.1
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• 2011

We have investigated a coronal jet near the limb on 2010 June 27 by Hinode/X-Ray Telescope (XRT), EUV Imaging Spectrograph (EIS), Solar Optical Telescope (SOT), SDO/Atmospheric Imaging Assembly (AIA), and STEREO. From EUV (AIA and EIS) and soft X-ray (XRT) images we identify the erupting jet feature in cool and hot temperatures. It is noted that there was a small loop eruption in Ca II images of the SOT before the jet eruption. Using high temporal and multi wavelength AIA images, we found that the hot jet preceded its associated cool jet. The jet also shows helical-like structures during the rising period. According to the spectroscopic analysis, the jet structure changes from blue shift to red one with time, implying the helical structure of the jet. The STEREO observation, which enables us to observe this jet on the disk, shows that there was a dim loop associated with the jet. Comparing the observations from the AIA and STEREO, the dim loop corresponds to the jet structure which implies the heated loop. Considering that the structure of its associated active region seen in STEREO is similar to that in AIA observed 5 days before, we compared the jet morphology on the limb with the magnetic fields extrapolated from a HMI vector magnetogram observed on the disk. Interestingly, the comparison shows that the open field corresponds to the jet which is seen as the dim loop in STEREO. Our observations (XRT, SDO, SOT, and STEREO) are well consistent with the numerical simulation of the emerging flux reconnection model.

• ETRI Journal
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• 제38권5호
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• pp.981-987
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• 2016

We present a cost-effective dual polarization quadrature phase-shift coherent receiver module using a silica planar lightwave circuit (PLC) hybrid assembly. Two polarization beam splitters and two $90^{\circ}$ optical hybrids are monolithically integrated in one silica PLC chip with an index contrast of $2%-{\Delta}$. Two four-channel spot-size converter integrated waveguide-photodetector (PD) arrays are bonded on PD carriers for transverse-electric/transverse-magnetic polarization, and butt-coupled to a polished facet of the PLC using a simple chip-to-chip bonding method. Instead of a ceramic sub-mount, a low-cost printed circuit board is applied in the module. A stepped CuW block is used to dissipate the heat generated from trans-impedance amplifiers and to vertically align RF transmission lines. The fabricated coherent receiver shows a 3-dB bandwidth of 26 GHz and a common mode rejection ratio of 16 dB at 22 GHz for a local oscillator optical input. A bit error rate of $8.3{\times}10^{-11}$ is achieved at a 112-Gbps back-to-back transmission with off-line digital signal processing.

• Bulletin of the Korean Chemical Society
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• 제34권2호
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• pp.558-564
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• 2013

A simple and effective method is introduced to synthesize a series of polystyrene-b-poly(oligo(ethylene oxide) monomethyl ether methacrylate)-b-polystyrene (PSt-b-POEOMA-b-PSt) triblock copolymers. The structures of PSt-b-POEOMA-b-PSt copolymers were characterized by Fourier-transform infrared spectroscopy (FTIR) and nuclear magnetic resonance ($^1H$ NMR) spectroscopy. The molecular weight and molecular weight distribution of the copolymer were measured by gel permeation chromatography (GPC). Furthermore, the self-assembling and drug-loaded behaviours of three different ratios of PSt-b-POEOMA-b-PSt were studied. These copolymers could readily self-assemble into micelles in aqueous solution. The vitamin E-loaded copolymer micelles were produced by the dialysis method. The micelle size and core-shell structure of the block copolymer micelles and the drug-loaded micelles were confirmed by dynamic light scattering (DLS) and transmission electron microscopy (TEM). The thermal properties of the copolymer micelles before and after drug-loaded were investigated by different scanning calorimetry (DSC). The results show that the micelle size is slightly increased with increasing the content of hydrophobic segments and the micelles are still core-shell spherical structures after drug-loaded. Moreover, the glass transition temperature (Tg) of polystyrene is reduced after the drug loaded. The drug loading content (DLC) of the copolymer micelles is 70%-80% by ultraviolet (UV) photolithography analysis. These properties indicate the micelles self-assembled from PSt-b-POEOMA-b-PSt copolymers would have potential as carriers for the encapsulation of hydrophobic drugs.

• Molecules and Cells
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• 제38권2호
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• pp.180-186
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• 2015

Escherichia coli AcrAB-TolC is a multidrug efflux pump that expels a wide range of toxic substrates. The dynamic nature of the binding or low affinity between the components has impeded elucidation of how the three components assemble in the functional state. Here, we created fusion proteins composed of AcrB, a transmembrane linker, and two copies of AcrA. The fusion protein exhibited acridine pumping activity, suggesting that the protein reflects the functional structure in vivo. To discern the assembling mode with TolC, the AcrBA fusion protein was incubated with TolC or a chimeric protein containing the TolC aperture tip region. Three-dimensional structures of the complex proteins were determined through transmission electron microscopy. The overall structure exemplifies the adaptor bridging model, wherein the funnel-like AcrA hexamer forms an intermeshing cogwheel interaction with the ${\alpha}$-barrel tip region of TolC, and a direct interaction between AcrB and TolC is not allowed. These observations provide a structural blueprint for understanding multidrug resistance in pathogenic Gram-negative bacteria.

• 천문학회보
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• 제44권1호
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• pp.53.1-53.1
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• 2019

We apply a non-equilibrium ionization (NEI) model to a supra-arcade plasma sheet, shocked plasma, and current sheet. The model assumes that the plasma is initially in ionization equilibrium at low temperature, and it is heated rapidly by a shock or magnetic reconnection. The model presents the temperature and characteristic timescale responses of the Atmospheric Imaging Assembly (AIA) on board Solar Dynamic Observatory and X-ray Telescope (XRT) on board Hinode. We compare the model ratios of the responses between different passbands with the observed ratios of a supra-arcade plasma sheet on 2012 January 27. We find that most of observations are able to be described by using a combination of temperatures in equilibrium and the plasma closer to the arcade may be close to equilibrium ionization. We also utilize the set of responses to estimate the temperature and density for shocked plasma associated with a coronal mass ejection on 2010 June 13. The temperature, density, and the line of sight depth ranges we obtain are in reasonable agreement with previous works. However, a detailed model of the spherical shock is needed to fit the observations. We also compare the model ratios with the observations of a current sheet feature on 2017 September 10. The long extended current sheet above the solar limb makes it easy to analyze the sheet without background corona. We find that the sheet feature is far from equilibrium ionization while the background plasma is close to equilibrium. We discuss our results with the previous studies assuming equilibrium ionization.