• 제목/요약/키워드: Magnetic Resonance Coupling

검색결과 128건 처리시간 0.023초

Advanced techniques of solution nuclear magnetic resonance spectroscopy for structural investigation of protein-protein interaction

  • Sugiki, Toshihiko;Lee, Young-Ho
    • 한국자기공명학회논문지
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    • 제22권4호
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    • pp.76-81
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    • 2018
  • Investigation of the protein-protein interaction mode at atomic resolution is essential for understanding on the underlying functional mechanisms of proteins as well as for discovering druggable compounds blocking deleteriou interprotein interactions. Solution NMR spectroscopy provides accurate and precise information on intermolecular interactions even for weak and transient interactions, and it is also markedly useful for examining the change in the conformation and dynamics of target proteins upon binding events. In this mini-review, we comprehensively describe three unique and powerful methods of solution NMR spectroscopy, paramagnetic relaxation enhancement (PRE), pseudo-contact shift (PCS), and residual dipolar coupling (RDC), for the study on protein-protein interactions.

$^{87}Rb$ NMR Quadrupole Coupling Constants and Asymmetry Parameters in $RbMnCl_3$

  • Woo, Ae-Ja;Park, Young-Sun
    • 한국자기공명학회논문지
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    • 제3권2호
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    • pp.84-89
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    • 1999
  • The 87Rb quadrupole coupling constants (e2qQ/h) and the asymmetry parameters (η) in RbMnCl3 were determined from a nonlinear least-squares fit to the 87Rb NMR powder spectra. The spectra were acquired in the temperature range from 260K to 330K. An important feature in this work is the determination of the quadrupole coupling constants and the asymmetry parameters for two physically nonequivalent Rb sites, Rb(I) and Rb(II), as a function of temperature. In addition, a structural phase transition at room temperature was conformed with the changes in the quadrupole coupling constant and the asymmetry parameter of Rb(II) site.

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Electron Spin Resonance Study on the Miscibility of Poly(ethylene glycol) with Cathonic Dodecyl Trimethylammonium Bromide Micelle

  • Kim Jin-Soo;Lee Don-Keun;Kang Young-Soo
    • 한국자기공명학회논문지
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    • 제9권2호
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    • pp.155-162
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    • 2005
  • The interaction of poly(ethylene glycol)(PEG) with cationic dodecyl trimethyl ammonium bromide (DTAB)micelle was studied with electron spin resonance (ESR) by determining line widths of the ESR spectra and coupling constant of nitrogen($A_N$). The degree of ESR line shape change such as line widths and coupling constant indicated that PEG mixes well with DTAB micelle due to a great hydrophobic interaction with surfactant alkyl chains. This suggests that the PEG can be used as non-ionic surfactant to disperse the exposed oil in the ocean.

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Electron Spin Resonance Study on the Miscibility of Poly(ethylene glycol) with Cationic Dodecyl Trimethylammonium Bromide Micelle

  • Kim, Jin-Soo;Shin, Dong-Ran;Kang, Young-Soo
    • 한국자기공명학회논문지
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    • 제1권1호
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    • pp.59-70
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    • 1997
  • The interaction of poly(ethylene glycol) (PEG) with cationic dodecyl trimethyl ammonium bromide (DTAB) micelle was studied with electron spin resonance (ESR) by determining line widths of ESR spectra and coupling constant of nitrogen(AN). The degree of ESR line shape change such as line widths and coupling constant indicated that PEG mixes well with DTAB micelle due to a great hydrophobic interaction with surfactant alkyl chains. This suggests that the PEG can be used as non-ionic surfactant to disperse the exposed oil in the ocean.

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Cyclotron Resonance of the Wannier-Landau Transition System Based on the Ensemble Projection Technique

  • Jung-Il Park
    • 한국자기공명학회논문지
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    • 제27권4호
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    • pp.28-34
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    • 2023
  • We study the linear-nonlinear quantum transport theory of Wannier-Landau transition system in the confinement of electrons by a square well confinement potential. We use the projected Liouville equation method with the ensemble density projection technique. We select the dynamic value under a linearly oscillatory external field. We derive the dynamic value formula and the memory factor functions in three electron phonon coupling systems and electron impurity coupling systems of two transition types, the intra-band transitions and inter-band transitions. We obtain results that can be applied directly to numerical analyses. For simple example of application, we analyze the absorption power and line-widths of ZnO, through the numerical calculation of the theoretical result in the Landau system.

초전도 코일을 적용한 WPT 특성 (Characteristics of Wireless Power Transmission applying the superconducting coil)

  • 정인성;최효상
    • 전기학회논문지
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    • 제62권6호
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    • pp.762-766
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    • 2013
  • Interest in Wireless Power Transmission (WPT) technology has been increasing worldwide recently. This trend is proved by commercialized products such as electric toothbrush, wireless razor, and wireless charger for mobile phone battery. Studies for enhancing the applicability of the technology have been continuously conducted. Currently the WPT technology is based on the technologies using microwave, inductively coupling, and magnetic resonance. In the meantime, development of the microwave-based WPT faces difficulty due to health hazards involved in the technology, and application of the WPT technology using inductively coupling is restricted by area due to the problem of transmission length. In comparison, the WPT technology using magnetic resonance draws attention in terms of efficiency and transmission length. In this study, the sending coil based on the WPT technology using magnetic resonance system was replaced with an HTS coil to enhance transmission efficiency. Since the HTS coil has a zero resistance, power transmission loss can be minimized. At the same time, size of the current density could be increased to 100 times or more than typical coils. In addition, through impedance matching of LC device, maximal resonance properties were induced and consequently, frequency selection quality characteristics or Q was enhanced. As a result, the WPT type using the HTS coil showed a longer transmission length and better transmission efficiency compared with the WPT type using typical coils.

공진 코일의 크기와 부하 저항이 자계 공명 무선 전력 전송 장치의 전달 효율에 주는 영향에 관한 연구 (A Study on the Effect of Resonant Coil Size and Load Resistance on the Transmission Efficiency of Magnetic Resonance Wireless Power Transfer System)

  • 박정흠
    • 조명전기설비학회논문지
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    • 제26권7호
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    • pp.45-51
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    • 2012
  • In this paper, the wireless power transfer system using the magnetic resonance was designed and the effect of resonant coil radius and load resistance to this system was analyzed by the circuit analysis method. As a result, the calculated transmitted-power is similar to measured one, and the coil size has a small effect to the coupling coefficients in the resonant frequency band. In addition, the fact that the calculated transmitted-power according to the source frequency is similar to measured one confirms that the circuit analysis methode in this paper is valid. The input side transmission efficiency ${\eta}_i$ including only the loss in the power transfer circuit is almost 90[%] with the large coil in the 10[cm] transfer distance, and 65[%] with the small coil in 1[cm]. The source side transmission efficiency ${\eta}_s$ is 30~40[%] at both coil when load resistance below 4.7[${\Omega}$] has been connected. Considering that the maximum ${\eta}_s$ is 50[%], this is valid in the practical applications.

자기공명형 무선전력송신을 위한 공진 주파수 설계에 관한 연구 (A Study On Design of Resonance Frequency for Wireless Power Transfer with Magnetic Resonance Type)

  • 안준선
    • 한국정보전자통신기술학회논문지
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    • 제5권4호
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    • pp.206-210
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    • 2012
  • 본 논문은 최근 주목받고 있는 무선 전력송신 방식 중 자기공명을 이용한 무선전력 송신에 관한 것으로 특히 자기 공명식 무선 전력 송신시 주파수 설계에 관한 것이다. 본 논문에서는 무선 전력 송신 주파수를 설계하기 위한 전력 송수신 시스템의 수학적 모델링을 개발 하였으며, 이를 검증하기 위한 시뮬레이션 모델을 개발하였다. 시뮬레이션은 수학적 모델에 기반한 방법과, 소자기반의 방법을 병용 함으로써 그 신뢰성을 확보하였으며, 시뮬레이션 결과에 대한 고찰을 기술 하였다.

Chemical Shift and Quadrupolar Interactions in Solids

  • Kim Jin-Eun
    • 한국자기공명학회논문지
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    • 제10권1호
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    • pp.1-37
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    • 2006
  • General expressions for solid state NMR lines are described for transitions under static, magic angle spinning, and variable angle spinning conditions in the case where the principal axis system for the anisotropic chemical shift tensor is noncoincident with that of the quadrupole coupling tensor. It is demonstrated that solid state NMR powder pattern simulation program VMAS based on the conventional grid point method of integrating over the Euler angle space is fast enough in comparison with the POWDER simulation package and Gauss-point method.

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Computer-Aided Crafting of Pulse Shapes for Broadband Heteronuclear Decoupling in the presence of Homonuclear Coupling

  • Lee, Chang-Jae
    • 한국자기공명학회논문지
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    • 제3권1호
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    • pp.36-43
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    • 1999
  • We present a pulse shape tailored for broadband decoupling for a system of spin-1/2's with scalar couplings as well. In crafting the pulse shape Coherent Averaging Theory and Fourier expansion method are used. The Fourier expansion coefficients are optimized numerically by applying the Simulated Annealing Method. The decoupling performance of the shaped pulse thus designed is then compared with the well-known composite pulse sequence, DIPSI-2. It is shown that the shaped pulse performs well even at the conditions where the DIPSI sequence begins to fail.

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