• Title/Summary/Keyword: Magnesium oxide

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Eco-Friendly and Thermal Conductivity Properties of Magnesium oxide Matrix Utilizing Bentonite (벤토나이트를 활용한 산화마그네슘 경화체의 친환경성 및 열저항 특성)

  • Gwon, Oh-Han;Lim, Hyun-Ung;Lee, Dong-Hoon;Lee, Sang-Soo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2016.10a
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    • pp.64-65
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    • 2016
  • This study that prevent cancer using absorbent to inflow Radon gas in the room existing soil and rock is making board to absorb the Radon gas as a fundamental study. So, we use bentonite as a absorbent. So, we use bentonite as a absorbent. Bentonite is a 'clay mineral' composed to montmorillonite of main component that volcanic ash denatured to a clay mineral. Bentonite has fine microparticle of nano level, abundant mineral 66 of kinds, adsorbability, swelling, a positive ion(heavy metal adsorption reaction) as a bentonite's property. Using magnesia cement for oxide of magnesiuma and magnesium chloride as a main binder, we measure Radon gas absorbent efficiency and thermal conductivity.

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Thermal Conductivity Properties of Magnesium Oxide Matrix using Vermiculite and Anthracite (버미큘라이트 및 안트라사이트를 활용한 산화마그네슘 경화체의 열전도율 특성)

  • Lim, Hyun-Ung;Gwon, Oh-Han;Pyeon, Su-Jung;Lim, Gguk-Jeong;Lee, Sang-Soo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2017.05a
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    • pp.80-81
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    • 2017
  • The study conducted a thermal conductivity test of magnesium oxide to manufacture boards using absorbent to produce board of radon gas molecules that are absorbed into the indoor air pollutants, which are currently in question, among other indoor air pollutants. Using material are the vermiculite and anthracite, in case of the vermiculite, which results in large porosity due to the expansion, in case of the anthracite, which characteristic generates pore on the matrix. As a result of the experiment, the lowest value was given to 0.6161 kcal/mh℃ which adding vermiculite 10% and anthracite 40%. However, adding vermiculite 40% and anthracite 10%, slightly higher 0.7229 kcal/mh℃, it is deemed the anthracite has more porosity than the vermiculite and, it judged that pore occurrence during the mixing process, appeared that the heat conductivity go down.

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Thermal fixing of multiple holographic gratings in magnesium oxide lithium niobate crystal

  • Yi, Seung-Wo;Cha, Sung-Do;Shin, Seung-Ho
    • Journal of the Optical Society of Korea
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    • v.1 no.1
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    • pp.19-22
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    • 1997
  • The photorefractive properties of 4% mol magnesium oxide doped lithium niobate have been investigated at room temperature. The recording and erasing time constants were measured as a function of intensity and analyzed by using the two active species (electron-hole) model. The results were used to compute the exposure schedule for multiple hologram recording. We have recorded grating of five holograms by angular multiplexing at room temperature and fixed them by means of a thermal cycling procedure. The highest diffraction efficiency of a fixed grating is up to 50% of an unfixed one.

Strength properties of magnesium oxide matrix according to type of phosphate (인산염 종류에 따른 산화마그네슘 경화체의 강도 특성)

  • Lim, Jeong-Jun;Pyeon, Su-Jeong;Kim, Dae-Yeon;Lee, Sang-Soo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2018.11a
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    • pp.79-80
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    • 2018
  • Recently, the interest in remodeling of new and old buildings is increasing worldwide. As a result, the frequency of use of architectural adhesives has increased. Currently, adhesives used in buildings are made of organic materials in most cases, and epoxy resin adhesives are most widely used. However, epoxy resin adhesives contain formaldehyde and VOCs in the room during construction, which can cause sick house syndrome. In case of building fire, it may cause damage due to carbon monoxide generated from organic materials. It is urgent to study the problem of epoxy fill adhesive made of such organic materials. Therefore, the purpose of this study is to investigate the effect of the adhesion of epoxy resin adhesive, which is a problem of epoxy resin adhesive, which is an existing organic adhesive by using inorganic materials such as magnesia and phosphate, And the inorganic adhesive which does not emit the release amount as an inorganic material.

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The Alkali Metal Interactions with MgO Nanotubes

  • Beheshtian, Javad;Peyghan, Ali Ahmadi;Bagheri, Zargham;Kamfiroozi, M.
    • Bulletin of the Korean Chemical Society
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    • v.33 no.6
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    • pp.1925-1928
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    • 2012
  • Adsorption of alkali metals (Li, Na, and K) on the surface of magnesium oxide nanotubes (MgONTs) with different diameters was investigated using density functional theory. According to the obtained results, the most stable adsorption site was found to be atop the oxygen atom of the tube surface with adsorption energies in the range of -0.25 to -0.74 eV. HOMO-LUMO gap ($E_g$) of the tubes dramatically decreases upon the adsorption of the alkali metals, resulting in enhancement of their electrical conductivity enhancement. The order of $E_g$ decrement caused by the metal adsorption is as follows: K > Na > Li. The results suggest that the MgONTs were transformed from semi-insulator to semiconductor upon the alkali metal adsorption. Increasing the tube diameter, the HOMO/LUMO gap of the pristine tube is enhanced and adsorption energies of the alkali metals are decreased.

Synthesis of (E,E)-2,4-Dienols from (E)-$\beta$-Chloro-$\gamma$-hydroxy-vinylmercurials and Olefins by Palladium(Ⅱ) Salt

  • Kim, Jin-Il;Lee, Jong-Tae;Choi, Cheol-Kyu
    • Bulletin of the Korean Chemical Society
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    • v.7 no.3
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    • pp.235-237
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    • 1986
  • Reaction of $(E)-{\beta}-chloro-{\gamma}$-hydroxyvinylmercurials, prepared by mercuration of propargyl alcohol and 2-methyl-3-butyne-2-ol, with olefins in the presence of a catalytic amount of $Li_2PdCl_4$ and 2 equiv of cupric chloride in methanol at $50^{\circ}C$ gave the corresponding (E,E)-2,4-dienols in moderate yields. However, addition of 1 equiv of inorganic bases such as magnesium oxide to the reaction mixture brings a rapid and clean vinylation and gave high yields of the dienols at room temperature. In the case of hindered (E)-2-chloro-3-chloromercuri-2-buten-1,4-diol prepared from 2-butyne-1,4-diol, reaction with olefins gave the dienols only in low yields even in the presence of 2 equiv of magnesium oxide.

Curing Properties of HTPB-based Solid Propellants (HTPB계 고체추진제의 경화 특성에 관한 연구)

  • Su-A Jeon;Jee-Hun Ahn;Hang-seok Seo;Han-Jun Kim;Eui-yong Park
    • Journal of the Korean Society of Propulsion Engineers
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    • v.26 no.6
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    • pp.28-33
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    • 2022
  • In this study, the curing characteristics of commonly used Hydroxyl terminated polybutadiene(HTPB)-based solid propellant according to the curing temperature and Equivalent ratio change were investigated. In addition, the effect of curing reaction according to their ratio and content in the Triphenyl bismuth(TPB), Maleic anhydride(MA) and Magnesium oxide(MgO) catalyst systems was confirmed. Finally, moisture was added for each propellant mixing process to check the effect of moisture on propellant curing.

Physical and Mechanical Properties of Magnesium Oxide Matrix depending on Addition Ratio of Magnesium Chloride (염화마그네슘 첨가율에 따른 산화마그네슘 경화체의 물리 및 역학적 특성)

  • Kim, Heon-Tae;Jung, Byeong-Yeol;Lee, Sang-Soo;Song, Ha-Young
    • Journal of the Korea Institute of Building Construction
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    • v.14 no.4
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    • pp.308-313
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    • 2014
  • Recently, for longevity of resident building, the main trend is that the change of the inside space organization of resident building from wall construction to rhamen construction, which resulted in increase in use of lightweight composite panel. Thus, in this study, authors analyzed the engineering property of oxide of magnesium depending on the magnesium chloride addition ratio. The results of this research is expected to contribute on providing a fundamental material for the surface materials of lightweight composite panel. As the result of the experiment, as fluidity increased, air content decreased and initial set and final set as the magnesium chloride addition ratio increase. In the aspect of flexural strength and compressive strength, the test specimen showed the highest strength at 40% of the magnesium chloride addition ratio. At 20% of the magnesium chloride addition ratio, the test specimen showed the lowest water absorption rate. As the magnesium chloride addition ratio increases, the expansibility tends to increase as well in the aspect of shrinkage strain. After observing microstructure, we can see hydration products in the form of needle. It appeared high flexural strength because the hydration products have mineral fibrous tissue shape, which also contribute to the cause of the expansibility.

Protective Metal Oxide Coatings on Zinc-sulfide-based Phosphors and their Cathodoluminescence Properties

  • Oh, Sung-Il;Lee, Hyo-Sung;Kim, Kwang-Bok;Kang, Jun-Gill
    • Bulletin of the Korean Chemical Society
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    • v.31 no.12
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    • pp.3723-3729
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    • 2010
  • We investigated the high-excitation voltage cathodoluminescence (CL) performance of blue light-emitting (ZnS:Ag,Al,Cl) and green light-emitting (ZnS:Cu,Al) phosphors coated with metal oxides ($SiO_2$, $Al_2O_3$, and MgO). Hydrolysis of the metal oxide precursors tetraethoxysilane, aluminum isopropoxide, and magnesium nitrate, with subsequent heat annealing at $400^{\circ}C$, produced $SiO_2$ nanoparticles, an $Al_2O_3$ thin film, and MgO scale-type film, respectively, on the surface of the phosphors. Effects of the phosphor surface coatings on CL intensities and aging behavior of the phosphors were assessed using an accelerating voltage of 12 kV. The MgO thick film coverage exhibited less reduction in initial CL intensity and was most effective in improving aging degradation. Phosphors treated with a low concentration of magnesium nitrate maintained their initial CL intensities without aging degradation for 2000 s. In contrast, the $SiO_2$ and the $Al_2O_3$ coverages were ineffective in improving aging degradation.

Anodic Oxide Films Formed on AZ31 Magnesium Alloy by Plasma Electrolytic Oxidation Method in Electrolytes Containing Various NaF Concentrations

  • Moon, Sungmo;Kwon, Duyoung
    • Journal of the Korean institute of surface engineering
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    • v.49 no.3
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    • pp.225-230
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    • 2016
  • The present work was conducted to investigate the effects of NaF concentration in phosphate and silicate-containing alkaline electrolyte on the morphology, thickness, surface roughness and hardness of anodic oxide films formed on AZ31 Mg alloy by plasma electrolytic oxidation (PEO) method. The PEO films showed flat surface morphology with pores in the absence of NaF in the electrolyte, but nodular features appeared on the PEO film surface prepared in NaF-containing electrolyte. Numerous pores ranging from 1 to $20{\mu}m$ in size were observed in the PEO films and the size of pores decreased with increasing NaF concentration in the electrolyte. Surface roughness and thickness of PEO films showed increases with increasing NaF concentration. Hardness of the PEO films also increased with increasing NaF concentration. It was noticed that hardness of inner part of the PEO films is lower than that of outer part of them, irrespective of the concentration of NaF. The low hardness of PEO films was explained by the presence of a number of small size pores less than $2{\mu}m$ near the PEO film/substrate interface.