• 제목/요약/키워드: Magnesium

검색결과 2,775건 처리시간 0.027초

멜라민이 코팅된 수산화마그네슘 입자의 제조와 그 복합입자의 난연특성 (Preparation of Mg(OH)2-Melamine Core-Shell Particle and Its Flame Retardant Property)

  • 임형미;윤준호;정상옥;이동진;이승호
    • 한국재료학회지
    • /
    • 제20권12호
    • /
    • pp.691-698
    • /
    • 2010
  • Magnesium hydroxide-melamine core-shell particles were prepared through the coating of melamine monomer on the surface of magnesium hydroxide in the presence of phosphoric acid. The melamine monomer was dissolved in hot water but recrystallized on the surface of magnesium hydroxide by quenching to room temperature in the presence of phosphoric acid. The core-shell particle was applied to low-density polyethylene/ ethylene vinyl acetate (LDPE/EVA) resin by melt-compounding at $180^{\circ}C$ as flame retardant. The effect of magnesium hydroxide and melamine content has been studied on the flame retardancy of the core-shell particles in LDPE/EVA resin according to the preparation process and purity of magnesium hydroxide. Magnesium hydroxide prepared with sodium hydroxide rather than with ammonia solution revealed higher flame retardancy in core-shell particles with LDPE/EVA resin. At 50 wt% loading of flame retardant, core-shell particles revealed higher flame retardancy compared to that of the exclusive magnesium hydroxide in LDPE/EVA composite, and it was possible to satisfy the V0 grade in the UL-94 vertical test. The synergistic flame retardant effect of magnesium hydroxide and melamine core-shell particles was explained as being due to the endothermic decomposition of magnesium hydroxide and melamine, which was followed by the evolution of water from the magnesium hydroxide and porous char formation due to reactive nitrogen compounds, and carbon dioxide generated from melamine.

유화 Chlorosulfonated Polyethylene Rubber (CSM)의 제조 및 특성 연구 (Preparation and Characterization of Emulsified Chlorosulfonated Polyethylene Rubber (CSM))

  • 최세영;이은경;최교창
    • Elastomers and Composites
    • /
    • 제40권1호
    • /
    • pp.12-21
    • /
    • 2005
  • 본 연구에서는 CSM 에멀젼의 물성을 향상시키고자 금속성 가교제인 magnesium carbonate 및 calcium hydroxide를 첨가하여 가교밀도, 열적특성, 표면자유에너지 그리고 인장강도, 파단신율 및 인열강도 특성을 고찰하였다, 금속성 가교제인 magnesium carbonate 및 calcium hyroxide 양이 증가함에 따라 CSM 에멀젼 필름은 가교밀도는 증가하였고, 이에 내수성과 $T_g$ 값도 증가하였다. 금속성 가교제로 magnesium carbonate를 첨가하였을 때 calcium hydroxide에 비해서 다소 높은 가교밀도와 $T_g$ 값을 보였다. 하지만 CSM 에멀젼 필름의 표면에너지 및 기계적 특성들은 다소 다른 거동을 보였다. Magnesium carbonate 0.75% 그리고 calcium hydroxide 1.0% 첨가한 경우가 가장 높은 표면 자유에너지 값과 인장강도 및 인열강도를 보였으나, 그 이상의 양을 첨가하였을 경우에는 오히려 감소함을 확인하였다. 그러므로 본 연구에서 CSM 에멀젼의 물성을 향상시키는데 적용되는 금속성 가교제로서 calcium hydroxide 보다 magnesium carbonate가 더 적당하며, 0.75% 첨가하였을 때 보다 향상된 물성을 얻을 수 있었다.

친환경 마그네슘-공기 전지용 AZ31, AZ61 마그네슘 합금 전극의 전기화학적 특성 (Electrochemical properties of AZ31, AZ61 magnesium alloy electrodes for eco-friendly Magnesium-air battery)

  • 최원경
    • 한국융합학회논문지
    • /
    • 제12권5호
    • /
    • pp.17-22
    • /
    • 2021
  • 환경 친화적인 마그네슘-공기 전지는 이론적 방전용량이 매우 높은 1차전지로 알려진 금속-공기 전지이며 대기 중 산소를 양극 활물질로 사용하고 마그네슘 합금을 연료로 사용하는 관점에서 금속-연료전지로도 불리고 있다. 음극으로 사용하는 마그네슘합금의 성능에 따라 전지 전체 성능이 결정되므로 고성능 전지로 상용화하기 위해서는 음극 재료인 마그네슘 합금 전극의 성능에 대한 연구와 개선이 필요하다. 본 연구는 상용화된 마그네슘 합금(AZ31, AZ61)을 선택하여 마그네슘-공기 전지용 전극재료로서 가능성을 평가하기 위하여 전기화학적인 측정을 실시하고 방전 특성을 조사하였다. 개방회로전위 변화, Tafel 곡선 변화, 순환전류전압곡선 측정을 통해 마그네슘합금들의 전기화학적 특성을 조사하였고 정전류 방전 실험을 통해 AZ61 합금의 우수한 방전 용량(1410mAhg-1)과 가능성을 평가하였다.

3-Hydroxy-3-methylglutaryl Coenzyme A reductase 활성에 미치는 마그네슘과 칼슘의 영향 (The Effect of Dietary Calcium and Magnesium on the 3-Hydroxy-3-methylglutaryl Coenzyme A Reductase)

  • 정영태;남현근
    • 한국식품영양과학회지
    • /
    • 제12권3호
    • /
    • pp.212-218
    • /
    • 1983
  • 토끼에 마그네슘 칼슘이 첨가된 식이를 급여하여 토끼의 liver microsomal protein에 함유된 HMG-CoA reductase의 활성과 혈청 콜레스테롤, 트리글리세리드, 마그네슘 및 칼슘의 양을 측정하여 다음과 같은 결과를 얻었다. 1. 혈청 마그네슘의 경우 대조군이 9.5mg% 인데, 마그네슘 첨가군은 평균 8.27이었고, 칼슘을 첨가하여 사육한 실험군에서 상당히 낮은 값 T-D : 3.5, T-E : 3.0, T-F : 4.0, T-G : 7.3으로 평균 4.45를 보였다. 2. 혈청 칼슘의 경우 대조군이 15.3mg %인데, 마그네슘 첨가 실험군은 평균 14.6이나 칼슘 첨가 실험군에 있어서 평균 14.1로서 큰 차이가 없었다. 3. 혈청 트리글리세리드의 경우 대조군 82.8에 비하여 마그네슘첨가 실험군은 평균 60.3이었으나, 칼슘 첨가 실험군은 평균 69.5로서 다소 높은 값을 보여 주었다. 4. 혈청 콜레스테롤의 경우 대조군이 80mg%인데 반하여, 마그네슘 첨가 실험군은 평균 64.3이었고, 칼슘 첨가 실험군은 평균 56.3으로 상당히 낮은 값을 보여 주었다. 5. microsomal protein의 HMG-CoA reductase의 활성의 경우는 대조군이 0.995nmol/min/mg 인데, 마그네슘 첨가 실험군은 평균 0.948을 보였고 칼슘 첨가 실험군은 평균 0.849를 보여 주었다.

  • PDF

저압주조방식에 의한 AZ91D 마그네슘 휠 특성 (The characteristic of low pressure casting AZ91D Magnesium alloy wheel)

  • 김광희
    • 한국산학기술학회논문지
    • /
    • 제13권11호
    • /
    • pp.4963-4967
    • /
    • 2012
  • 본 연구에서는 마그네슘 합금 AZ91D를 소재로 18인치 휠을 개발하고 동일사양의 알루미늄 휠과 해외 시판중인 마그네슘 휠과 기계적인 성질을 비교하였다. 저압주조 방식에 의해 18인치 마그네슘 휠 시제품을 제작하여 동일 사양의 알루미늄 휠 대비 26% 의 경량화를 이룩하였고, 신판 마그네슘 휠 대비 동등 수준의 연신율, 인장강도, 경도를 달성하였다. 향 후 주조와 열처리 공정 개선을 통해 항복강도 향상이 필요한 것으로 판단된다.

Nd:YAG 레이저의 펄스 제어에 의한 마그네슘 합금 용접부의 결함 방지에 관한 연구 (Study of Defect Prevention on Weld Zone of Magnesium Alloy by Pulse Control of Nd:YAG Laser)

  • 김종도;이정한;김장수
    • 한국정밀공학회지
    • /
    • 제27권1호
    • /
    • pp.99-104
    • /
    • 2010
  • Magnesium and magnesium alloys, the lightest structural materials, have been received plenty of global attention recently. These alloys could be applied in various fields, especially the electronics industry, because of their excellent electromagnetic interference shielding. However, the welding technique of magnesium alloys has not been established. This study is related to the welding of AZ31B magnesium alloy by a short-pulsed a Nd:YAG laser. Two types of pulse waves, square pulse and variable pulse, were used to control weld defects. Results show that the crack and porosity, generated in the weld, had not been controlled by general square pulse. But through the application of variable pulse, the defects could be prevented and the good weld zone was obtained.

고분자 첨가제인 난연제로서의 수산화마그네슘계 물질의 합성과 특성 (Synthesis and Characteristics of Magnesium Hydroxide Group Flame Retardant for Polymer Addtives)

  • 이동규;강국현;이진화
    • 한국응용과학기술학회지
    • /
    • 제26권4호
    • /
    • pp.385-393
    • /
    • 2009
  • Different types magnesium hydroxide groups have been obtained using the hydrothermal precipitation technique from magnesium sulfate and calcium carbonate solution. The Mg atom coordinated around O atom of ${SO_4}^{2-}$ in another layer to form a multi-layer structure crystal. The influence of synthesis parameters on the morphological characteristics and size of magnesium hydroxide groups precipitated in aqueous were investigated such as different of additive and pH. Magnesium hydroxide groups were decomposed gradually and converted finally to MgO particles after heated in air temperature up to $1050^{\circ}C$. The particle size and it's distribution morphology, crystal phase and thermal behavior of the samples were characterized through XRD, SEM, EDS, and TG/DTA.

채식 수유부의 모유중 수유기간별 칼슘, 인, 마그네슘 함량에 관한 연구 (A Longitudinal Study on Calcium, phosphorous and Magnesium Contents in the Breast Milk of Lacto-ove-vegetarian)

  • 이연주
    • Journal of Nutrition and Health
    • /
    • 제26권8호
    • /
    • pp.974-981
    • /
    • 1993
  • The longitudinal changes on contents of calcium, phosphorous and magnesium of breast milk of 23 Korean lacto-ovo-vegetarians(primiparae=11, multiparae=12) at 0.5, 1, 2 and 3 months postpartum have been studied. The mean ash content of breast milk per 100ml was 0.21g in total lactating women(n=23), and it decreased significantly during lactation(p<0.05). The mean calcium, phosphorous and magnesium contents of breast milk per 100ml were 26.83mg, 14.01mg and 2.72mg, respectively. Body calcium and phosphorous contents decreased significantly during lactation(p<0.05), but magnesium content tended to increase during lactation. There were no significant differences in ash, calcium, phosphorous and magnesium contents between primiparae and multiparae. The ratio of calcium to phosphorus was about 1.95:1 in breast milk and 0.62 : 1 in maternal dietary intake. In calcium and phosphorous, no correlation was found between maternal dietary intake and the concentration in breast milk. This study suggests that the contents of calcium, phosphorous and magnesium in lacto-ovo-vegetarian breast milk are not different from the concentrations of those in non-vegetarian.

  • PDF

주부들의 심리적 자작 증세와 혈청칼슘 및 마그네슘 농도와의 관련성 (The Relationship of Serum Calcium and Magnesium Levels to Depression and Anxiety Symptoms in Homemarkers)

  • 박귀선
    • Journal of Nutrition and Health
    • /
    • 제31권1호
    • /
    • pp.102-107
    • /
    • 1998
  • This study was conducted to investigate the relationship of serum calcium and magnesium levels to depression and anxiety symptoms in 80 homemarker. Fasting blood samples were collected and serum calcium and magnesium concentrations were measured. At the same time, psychological conditions of subjects were estimated by questionnaire. As the result of psychological test, eighty homemarkers were divided into two groups according to psychologicaltest scores. The subjects in one group got high pssycholgoical test scores as high score group (HSG) and the others got low physchological test scores as low score group(LSG). Serum calcium and magnesium concentrations were significantly(p<0.05) lower in HSG than in HSG than in LSG. Many a subject who belonged to HSG appeared to have depression and anxiety symptoms. Drepression and anxiety scores of the subjects with calcium supplementation were significantly (p<0.05) lower than those without calcium supplementation . After calcium supplementation, depressiion and anxiety scores were significantly (p<0.05) decreased in HSG and serum calcium and magnesium concentrations in HSG were significantly increased to normal ranges . This results suggested that psychological conditions of homemarkers might be affected by serum calcium and magnesium levels.

  • PDF

마그네시아 製造에 關한 硏究 간수, 海水로 부터 水酸化마그네슘 製造 (Studies on Magnesia Production. Production of Magnesium Hydroxide from Bittern and Sea Water)

  • 맹중재;장인순
    • 대한화학회지
    • /
    • 제9권1호
    • /
    • pp.49-54
    • /
    • 1965
  • One of the difficult and time consuming problems in the production of magnesia from sea water is a settling rate of magnesium hydroxide. In this experiments, authors attempted to accelerate its settling rate by addition of various sedimenting agents as C.M.C., Separan and Starch, and sought for optimum calcination temperature for domestic dolomite, as alkali source, mole ratio of dolomite milk to bittern. It is observed through experiments that the small amounts of sedimenting agents, C.M.C., Separan, starch, 20 mg/l, 40 mg/l, 400mg/l, respectively increase the settling rate of magnesium hydroxide by 8 times or more. The following conditions resulted in good yield of magnesium hydroxide from sea water with relatively tolerable calcium oxide contaminated for the magnesium clinker. Calcinating temperature, $1,100{\sim}1,200^{\circ}C$, mole ratio of 10% dolomite milk to magnesium salts in sea water or bittern, 1. 2 : 1.

  • PDF