• Title/Summary/Keyword: Ma-hwang

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SHRIMP U-Pb Dating and Chronostratigraphy of the Volcanic Rocks around the Mireukdo Island, Tongyeong, Korea (통영 미륵도 주변 화산암류의 SHRIMP U-Pb 연대측정과 시간층서)

  • Hwang, Sang Koo;Lee, So Jin;Song, Kyo-Young;Yi, Keewook
    • The Journal of the Petrological Society of Korea
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    • v.27 no.1
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    • pp.25-36
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    • 2018
  • The volcanic rocks around Mieukdo Island, Tongyeong, are classified as lower andesitic rocks (Jusasan Subgroup) and rhyolitic rocks (Unmunsa Subgroup), and upper andesitic rocks (Yokji Subgroup) and rhyolitic rocks (Saryang Subgroup). We confirmed their eruption timings and stratigraphic relationships, based on SHRIMP U-Pb zircon dating for zircons from major stratigraphic units of the subgroups. By the SHRIMP U-Pb dating, the samples yield the concordia ages of $88.95{\pm}0.44Ma$(n=11) in Punghwari Tuff and $82.56{\pm}0.95Ma$(n=10) in Chudo Tuff of the lower andesitic rocks, and $73.01{\pm}0.75Ma$(n=11) in Dara Andesite of the upper andesitic rocks. And then samples show a concordia age of $71.74{\pm}0.47Ma$(n=14) in Namsan rhyolite dyke of the upper rhyolitic rocks and an apparent age of $70.7{\pm}3.5Ma$ in granodiorite dyke, These data confirm the eruption or injection timings of the units and allow them to distinguish chronostratigraphy of Jusasan, Unmunsa, Yokji and Saryang Subgroups around the Mireukdo Island. In addition, the subgroups give a clue that can make a chronostratigraphical correlation with different volcanic units of the Late Cretaceous Yucheon Group in the Gyeongsang basin.

Experimental Study on the Thermodynamic Characteristics of Commercial Small-size Moxa Combustion (상용 소형 쑥뜸의 열역학적 특성에 대한 실험적 연구)

  • Lee Geon-Mok;Hwang Yoo-Jin;Lee Gun-Hyee
    • Journal of Acupuncture Research
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    • v.18 no.6
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    • pp.171-187
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    • 2001
  • Objective : Moxibustion has been proved efficacious for many diseases, but isn't widespread in the clinics due to a danger of skin burning, the smoke produced while burning a moxa combustion and so on. Therefore, another type of moxa that can be resolved these troubles is required. To improve the effect of moxibustion and develop the new thermal stimulating treatment, the performance of commercial moxibustion widely used are studied systematically and found out quantitatively. Methods : We have selected two types (small-size moxa A(sMA), small-size moxa B (sMB)) among small-size moxaes used widely in the clinic. We examined combustion time, various temperatures, temperature gradient in each period during a combustion of moxa. Results : 1. The combustion time in the preheating period appeared somewhat longer in sMA than in sMB. 2, The combustion time in the heating period appeared longer in sMA by 26% than in sMB. 3. The average temperature in the heating period was $37.6{\sim}37.8^{\circ}C\;in\;sMA\;and\;36.2{\sim}36.8^{\circ}C$ in sMB and the maximum temperature measured at a center of contact surface in sMA was $48.6^{\circ}C$, higher by over $2.8^{\circ}C$ than that of sMB moxibustion. 4. The average ascending temperature gradient in the heating period was $0.08{\sim}0.1^{\circ}C/sec$ in both moxaes, and the average ascending temperature gradient of heating period in sMB appeared larger. The maximum ascending temperature gradient appeared higher in sMB, and the time reaching maximum ascending temperature gradient appeared much earlier in sMA than in sMB. 5. The combustion time in the retaining period was around 100 sec in sMA and around 275 sec in sMB. 6. The average temperature in the retaining period was $42.2{\sim}46.0^{\circ}C\;in\;sMA\;and\;39.3{\sim}41.4^{\circ}C/sec$ in sMB. The minimum temperature in the retaining period was over $38.80^{\circ}C$ in sMA but just $34.7^{\circ}C$ in sMB. 7. The average descending temperature gradient in sMA was $-0.050{\sim}0.067^{\circ}C/sec$ and in sMB was $-0.030{\sim}0.037^{\circ}C/sec$ 8. The combustion time in the cooling period appeared longer over two times in sMA than in sMB, and the time which the cooling period (minimum temperature) finished at appeared later in sMB by 55 sec. 9. We classified the combustion process that the measured temperature rose over body heat($37^{\circ}C$) into the effective combustion period. The effective combustion time was 233.3 sec in sMA and 300.4 sec in sMB respectively, and was longer by about 29% in sMB. The average temperature and maximum temperature in the effective combustion time appeared higher in sMA. The time taken until the maximum temperature was reached was 225.1 sec in sMA and 244.5 sec in sMB, faster by about 20 sec in sMA. The maximum ascending temperature gradient during the effective combustion period appeared larger about 1.4 times in sMB, but the time when the maximum ascending temperature gradient happened was faster in sMA. Conclusion : It appears that sMB, compared with sMA, is proper if necessary to apply the long time and weak stimulus, because of the gentle stimulus during the relatively longer time. In contrast, sMA that the symmetrical combustion happened is proper if necessary to apply the short time and strong stimulus.

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Preparation and Surface-Active Properties of Vinyl Acetate Cotelomers (I) (비닐아세테이트 코텔로머의 제조 및 계면활성(I))

  • Lee, Eon-Pil;Kang, Se-Mi;Hwang, Dae-Youn;Jung, Young-Jin;Choi, Hae-Wook;Choi, Young-Ho;Lee, Jae-Ho
    • Fashion & Textile Research Journal
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    • v.14 no.4
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    • pp.677-683
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    • 2012
  • 1-octanethiol and vinyl acetate telomers ($R_8S$-nVAc) were synthesized and hydrolyzed with sodium hydroxide subsequently, 1.2-epoxyhexane was then introduced to the telomers. In addition, we prepared cotelomers of multi-alkylated nonionic surfactants with a molecular structure of xRnMA-yVA (x; hydrophobic group, y; hydrophilic group, MA; methacrylic ester, VA; vinyl alcohol, R; and alkyl group) and cross-linked with sodium tetraborate decahydrate. Their active surface properties were investigated by several techniques such as surface tension, foaming property, and emulsification power measurements. The surface tension of $R_8S$-8.8VA decreased without the introduction of 1.2-Epoxy hexane, and the degree of emulsification and foaming abilities of $R_8S$-8.8VA increased without the introduction of 1.2-Epoxy hexane. However, the differences were insignificant. The epoxy groups were attached to a $R_8S$-8.8VA cotelomer with a limited variation of the active surface properties. The surface tension of $1.1R_6MA$-8.8VA decreased after cross-linking subsequently, the degree of emulsification and foaming abilities of $1.1R_6MA$-8.8VA increased after cross-linking. However, there was no clear difference between them. The B-O bonds were attached to a $1.1R_6MA$-8.8VA cotelomer with a limited variation of the active surface properties.

Isolation and In vitro and In vivo Antifungal Activity of Phenylacetic acid Produced by Micromonospora aurantiaca Strain JK-1

  • Kim, Hyo-Jin;Hwang, In-Sun;Kim, Beom-Seok;Hwang, Byung-Kook
    • The Plant Pathology Journal
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    • v.22 no.1
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    • pp.75-89
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    • 2006
  • The actinomycete strain JK-1 that showed strong inhibitory activity against some plant pathogenic fungi and oomycetes was isolated from Jung-bal Mountain in Ko-yang, Korea. The strain JK-1 produced spores singly borne on sporophores and the spores were spherical and 0.9-1.2 11m in diameter. The cell wall of the strain JK-1 contained meso-diaminopimelic acid. The actinomycete strain JK-1 was identified as the genus Micromonospora based on the morphological, physiological, biochemical and chemotaxonomic characteristics. From the 168 rDNA analysis, the strain JK-1 was assigned to M aurantiaca. The antibiotic MA-1 was purified from the culture broth of M aurantiaca JK-1 using various purification procedures, such as Diaion HP20 chromatography, C18 flash column chromatography, silica gel flash column chromatography and Sephadex LH-20 column chromatography. $^{1}H-$, $^{13}C-NMR$ and EI mass spectral analysis of the antibiotic MA-1 revealed that the antibiotic MA-1 is identical to phenylacetic acid. Phenylacetic acid showed in vitro inhibitory effects against fungal and oomycete pathogens Alternaria mali, Botrytis cinerea, Magnaporthe grisea, Phytophthora capsici and yeast Saccharomyces cerevisiae at < 100 $\mug$ $ml^{-1}$. In addition, phenylacetic, acid completely inhibited the growth of Sclerotinia sclerotiorum, Bacillus subtilis, Candida albicans, Xanthomonas campestris pv. vesicatoria at < $\mug$ $ml^{-1}$. Phenylacetic acid strongly inhibited conidial germination and hyphal growth of M grisea and C. orbiculare. Phenylacetic acid showed significantly high levels of inhibitory' effect against rice blast and cucumber anthracnose diseases at 250 $\mug$ $ml^{-1}$. The control efficacies of phenylacetic acid against the two diseases were similar to those of commercial compounds tricyclazole, iprobenfos and chlorothalonil .n the greenhouse.

Enhancement of Compatibility and Toughening of Commingled Packaging Film Wastes (혼합 폐포장 필름의 상용성 증진과 강인화)

  • Jeon Byeong-Hwan;Yoon Hogyu;Hwang Seung-Sang;Kim Jungahn;Hong Soon-Man
    • Polymer(Korea)
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    • v.29 no.2
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    • pp.127-134
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    • 2005
  • The relationships among mechanical properties, rheological properties, and morphology by reactive extrusion based on commingled pckaging film wastes contains polypropylene (PP) pckaging film system [PP/polyethylene (PE)/aluminum (Al)/poly(ethylene terephthalate) (PET)] and Nylon packaging film system[Nylon/PE/linear-low density polyethylene (LLDPE)] were investigated to improve the compatibility and toughness of these wastes using various compatibilizers such as ethylene vinylacetate (EVA), styrene-ethylene/butylene-styrene triblock copolymer (SEBS), styrene-ethylene/butylene-styrene-graft-maleic anhydride copolymer (SEBS-g-MA), polyethylene-graft-maleic anhydride (PE-g-MA), polypropylene-graft-maleic anhydride (PP-g-MA) , polyethylene-graft-acrylic acid (PE-g-AA) and polypropylene-graft-acrylic acid (PP-g-AA). Compared with simple melt blend system, the blends showed improvement of about $50\%$ increase in physical properties when SEBS and EVA were added. However, SEBS-g-MA thermoplastic elastomer which is highly reactive with amine terminal group of nylon, resulted in about $200\%$ increase in impact strength. This compatibilization effect resulted from the increase of interfacial adhesion and the reduction of domain size of dispersed phase in PP/Nylon blend system.

Synthesis and Characterization of IPA-co-HDO-co-(TPA/MA) Anion-Exchange Membrane for All-Vanadium Redox Flow Battery (전바나듐계 레독스-흐름 전지용 IPA-co-HDO-co-(TPA/MA) 음이온교환막의 합성 및 특성)

  • Jung, Jae-Chul;Kwak, Noh-Seok;Hwang, Taek-Sung
    • Polymer(Korea)
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    • v.35 no.6
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    • pp.593-598
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    • 2011
  • The IPA-co-HDO-co-(TPA/MA) copolymers for all-vanadium redox flow battery were synthesized by melt condensation polymerization using isophthalic acid(IPA), 1,6-hexandiol (HDO), terephthalic acid(TPA) and maleic anhydride(MA). The amination of chloromethylated IPA-co- HDO-co-(TPA/MA)(CIHTM) copolymer was carried out using trimethylamine, and the anion exchange membrane was also prepared by UV crosslinking reaction. The structure and thermal stability of IHTM copolymers were confirmed by FTIR, $^1H$ NMR, and TGA analysis. The anion membrane properties such as water uptake, ion exchange capacity, electric resistance and electrical conductivity, were measured by gravimetry, titration and LCR meter. The efficiency of the all-vanadium redox flow battery was analyzed. The ion exchange capacity, electric resistance and electrical conductivity were 1.10 meq/g, $1.98{\Omega}{\cdot}cm^2$, and 0.009 S/cm, respectively. The efficiency of charge-discharge, voltage, and energy for the allvanadium redox flow battery were 96.5, 74.6, 70.0%, respectively.

K-Ar Age and Geochemistry of Hydrothermal Alteration in the Barton Peninsula, King George Island, Antarctica (남극 킹조지섬 바톤반도의 열수변질작용에 관한 K-Ar 연대와 지구화학)

  • Hur, Soon-Do;Lee, Jong-Ik;Hwang, Jeong;Choe, Moon-Young
    • Ocean and Polar Research
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    • v.23 no.1
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    • pp.11-21
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    • 2001
  • K-Ar ages of the altered rocks from the Barton Peninsula are belows; altered tuffaceous andesite from southwestern part is 42 Ma, altered rocks contacted with quartz vein from southern part are 28 and 33 Ma, and advanced argillic altered andesite from northeastern part are 33 and 35 Ma. Those K-Ar ages are 10 My younger than granitic rocks of the Barton Peninsula. Hydothermal alteration of the Barton Peninsula was originated from mixing of magmatic water from parent magma of granitic rocks with meteoric water. The Al content in the hostrock is relatively constant during hydrothermal alteration, on the contrary the Mg content is in proportion to total alkali. The variation of total alkali and Mg contents in hydrothermal alteration indicates that those elements was washed out during hydrothermal alteration. The sequences of hydrothermal alteration of the Barton Peninsula is chloritization of amphiboles, sericitization of feldspars and kaolitization of sericite.

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