• Title/Summary/Keyword: MWCNT effect

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Effect of nanoparticle material for heat transfer enhancement (열전달 향상을 위한 나노물질 코팅재료의 영향에 대한 연구)

  • Jeon, Yong-Han;Kim, Nam-Jin
    • Design & Manufacturing
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    • v.13 no.1
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    • pp.42-47
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    • 2019
  • Nucleate boiling heat transfer is one of the most important phenomenon in the various industries. Especially, critical heat flux (CHF) refers to the upper limit of the pool boiling heat transfer region. Therefore, many researchers have found that CHF can be significantly increased by adding very small amounts of nanoparticles. In this study, the CHF and heat transfer coefficient were tested under the pool boiling state using copper and multi wall carbon nanotube nanoparticles. The results showed that two different types of nanoparticles deposited on the surface of two specimens made of the same material increased the heat flux in the nanoparticles with high conductivity, and there was no difference in the critical heat flux when the same material nanoparticles were deposited on the two different specimen surfaces.

Experimental studies on elastic properties of high density polyethylene-multi walled carbon nanotube nanocomposites

  • Fattahi, A.M.;Safaei, Babak;Qin, Zhaoye;Chu, Fulei
    • Steel and Composite Structures
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    • v.38 no.2
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    • pp.177-187
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    • 2021
  • The effect of nanoparticle volume fraction on the elastic properties of a polymer-based nanocomposite was experimentally investigated and the obtained results were compared with various existing theoretical models. The nanocomposite was consisted of high density polyethylene (HDPE) as polymeric matrix and 0, 0.5, 1 and 1.5 wt.% multi walled carbon nanotubes (MWCNTs) prepared using twin screw extruder and injection molding technique. Nanocomposite samples were molded in injection apparatus according to ASTM-D638 standard. Therefore, in addition to morphological investigations of the samples, tensile tests at ambient temperature were performed on each sample and stress-strain plots, elastic moduli, Poisson's ratios, and strain energies of volume units were extracted from primary strain test results. Tensile test results demonstrated that 1 wt.% nanoparticles presented the best reinforcement behavior in HDPE-MWCNT nanocomposites. Due to the agglomeration of nanoparticles at above 1 wt.%, Young's modulus, yielding stress, fracture stress, and fracture energy were decreased and Poisson's ratio and failure strain were increased.

Performance Evaluation of Cement Composites Mixed with Multi-Wall Carbon Nanotube and Nanosilica (다중벽 탄소나노튜브와 나노실리카를 혼입한 시멘트 복합체의 성능 평가)

  • Kim, Seong Woo;Son, Jeong Jin;Kim, Ji-Hyun;Chung, Chul-Woo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2023.05a
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    • pp.185-186
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    • 2023
  • Recently, a lot of nano-scale material technology development and research have been conducted in construction fields to improve the compressive strength and durability of cement-based Composites. There are some studies that have confirmed the properties and application effects of cement-based complex using each nanomaterial, but development and research using both materials are relatively limited. This study sought to confirm the effect of multi-wall carbon nanotubes (MWCNT) and nanosilica, which are representative construction nanomaterials, on the compressive strength, voids, and microstructure formation of cement. The purpose was to produce a cement composite by changing the mixing rate of the two nanomaterials, and to find the optimal mixing amount considering its mechanical and rheological properties.

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Electromagnetic-wave Shielding by Nano Particles-contained Glass Fiber Reinforced Composite Materials (나노입자 첨가 유리섬유강화 복합재료의 전자기파 차폐특성)

  • 정우균;안성훈;원명식
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2004.10a
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    • pp.1331-1334
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    • 2004
  • The research on electromagnetic shielding has been advanced for military applications as well as for commercial products. Utilizing the reflective properties and absorptive properties of shielding material, the replied signal measured at the rear surface or at the signal source can be minimized. The shielding effect was obtained from materials having special absorptive properties or from structural characteristics such as stacking sequence. Recently researchers studied the electromagnetic properties of nano size particles. In this research {glass fiber}/{epoxy}/{nano particle} composites(GFR-Nano composites), was fabricated using various nano particles, and their properties in electromagnetic shielding were compared. For the visual observation of the nano composite materials, SEM(Scanning Electron Microscope) and TEM(Transmission Electron Microscope) were used. For the measurement of electromagnetic shielding, HP8719ES S-parameter Vector Network Analyser System was used on the frequency range of 8 GHz~12GHz. Among the nano particles, carbon black and Multi-Walled Carbon Nano-Tube (MWCNT) revealed outstanding electromagnetic shielding. Although silver nano particles (flake and powder) were expected to have effective electromagnetic shielding due to their excellent electric conductivities, test showed little shielding effect.

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Effect of Fe3O4 loading on the conductivities of carbon nanotube/chitosan composite films

  • Marroquin, Jason;Kim, H.J.;Jung, Dong-Ho;Rhee, Kyong-Yop
    • Carbon letters
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    • v.13 no.2
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    • pp.126-129
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    • 2012
  • Nanocomposite films were made by a simple solution casting method in which multi-walled carbon nanotubes (MWCNT) and magnetite nanoparticles ($Fe_3O_4$) were used as dopant materials to enhance the electrical conductivity of chitosan nanocomposite films. The films contained fixed CNT concentrations (5, 8, and 10 wt%) and varying $Fe_3O_4$ content. It was determined that a 1:1 ratio of CNT to $Fe_3O_4$ provided optimal conductivity according to dopant material loading. X-ray diffraction patterns for the nanocomposite films, were determined to investigate their chemical and phase composition, revealed that nanoparticle agglomeration occurred at high $Fe_3O_4$ loadings, which hindered the synergistic effect of the doping materials on the conductivity of the films.

Comparison of Electromagnetic-wave Shielding Effect in Glass Fiber Reinforced Nano Composites (유리섬유강화 나노 복합재료의 전자기파 차폐효과 비교)

  • Jung Woo-Kyun;Won Myung-Sik;Ahn Sung-Hoon
    • Journal of the Korean Society for Precision Engineering
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    • v.22 no.10 s.175
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    • pp.121-128
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    • 2005
  • The research on electromagnetic shielding has been advanced for military applications as well as for commercial products. Utilizing the reflective properties and absorptive properties of shielding material, the replied signal measured at the rear surface or at the signal source can be minimized. The shielding effect was obtained from materials having special absorptive properties and structural characteristics such as stacking sequence. Recently researchers studied the electromagnetic properties of nano size particles. In this research {glass fiber}/{epoxy}/{nano particle} composites(GFR-Nano composites) was fabricated using various nano particles, and their properties in electromagnetic shielding were compared. For the visual observation of the nano composite materials, SEM(Scanning Electron Microscope) and TEM(Transmission Electron Microscope) were used. For the measurement of electromagnetic shielding, HP8719ES S-parameter Vector Network Analyser System was used on the frequency range of 8 GHz${\~}$12GHz. Among the nano particles, carbon black and Multi-Walled Carbon Nano-Tube (MWCNT) revealed outstanding electromagnetic shielding. Although silver nano particles (flake and powder) were expected to have effective electromagnetic shielding due to their excellent electric conductivities, test results showed little shielding characteristics.

The Photodegradation Effect of Organic Dye for Metal Oxide (Cr2O3, MgO and V2O3) Treated CNT/TiO2 Composites

  • Chen, Ming-Liang;Bae, Jang-Soon;Yoon, Hee-Seung;Lim, Chang-Sung;Oh, Won-Chun
    • Bulletin of the Korean Chemical Society
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    • v.32 no.3
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    • pp.815-820
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    • 2011
  • Three kinds of organometallic compounds (chromium acetylacetonate, magnesium acetate and vanadyl acetylacetonate) were used as transition metal precursor, titanium n-butoxide and multi-walled carbon nanotube as titanium and carbon precursor to prepare metal oxide-CNT/$TiO^2$ composites. The surface properties and morphology of metal oxide-CNT/$TiO^2$ composites were by Brauer-Emett-Teller (BET) surface area measurement, scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD) and energy dispersive X-ray (EDX) analysis. The photocatalytic activity of prepared metal oxide-CNT/$TiO^2$ composites was determined by the degradation effect of methylene blue in an aqueous solution under irradiation of visible light.

Rheological Properties and Foaming Behaviors of Modified PP/Nano-filler Composites (개질 폴리프로필렌/나노필러 복합체의 유변학적 특성 및 발포거동)

  • Yoon, Kyung Hwa;Lee, Jong Won;Kim, Youn Cheol
    • Polymer(Korea)
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    • v.37 no.4
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    • pp.494-499
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    • 2013
  • Modified polypropylene (m-PP) was fabricated by furfuryl sulphide (FS) as branching agent and m-PP/nano-filler composites were prepared with silicate and multi-walled carbon nanotube (MWCNT), using a twin screw extruder. The chemical structures and thermal properties of the m-PP were investigated by FTIR and DSC. The chemical structure of the m-PP was confirmed by the existence of =C-H stretching peak of the branching agent at 3100 $cm^{-1}$. There was no district change in melting temperature in case of m-PP, but a certain increase in crystallization temperature was notified and the increase was in the range of $10-20^{\circ}C$. The rheological properties, filler dispersion and foaming behaviors of the m-PP/nano-filler composites were investigated by dynamic rheometer, X-ray diffractometer (XRD) and scanning/transmission electron microscope (SEM/TEM). m-PP/nano-filler composites showed a high complex viscosity at a low frequency, an increase in melt elasticity, and a high shear thinning effect. Compared to pure PP, m-PP and m-PP/nano-filler composites were sufficient to enhance the foaming behavior.

Water - Assisted Efficient Growth of Multi-walled Carbon Nanotubes by Thermal Chemical Vapor Deposition

  • Choi, In-Sung;Jeon, Hong-Jun;Kim, Young-Rae;Lee, Nae-Sung
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2009.06a
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    • pp.418-418
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    • 2009
  • Vertically aligned arrays of multi-walled carbon nanotube (MWCNT) on layered Si substrates have been synthesized by water-assisted thermal chemical vapor deposition (CVD). We studied changes in growth by parameters of growth temperature, growth time, rates of gas and annealing time of catalyst. Also, We grew CNTs by adding a little amount of water vapor to enhance the growth of CNTs. $H_2$, Ar, and $C_2H_2$ were used as carrier gas and feedstock, respectively. Before growth, Fe served as catalyst, underneath which AI were coated as an underlayer and a diffusion barrier, respectively, on the Si substrate. The water vapor had a greater effect on the growth of CNTs on a smaller thickness of catalyst. When the water vapor was introduced, the growth of CNTs was enhanced than without water. CNTs grew 1.29 mm for 10 min long by adding the water vapor, while CNTs were 0.73 mm long without water vapor for the same period of time. CNTs grew up to 1.97 mm for 30 min prior to growth termination under adding water vapor. As-grown CNTs were characterized by using scanning electron microscopy (SEM), high resolution transmission electron microscopy (HRTEM), and Raman spectroscopy.

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Photo Catalytic Activity of CNT-TiO2 Nano Composite in Degrading Anionic and Cationic Dyes

  • Kim, Sang-Jin;Im, Ji-Sun;Kang, Phil-Hyun;Kim, Tae-Jin;Lee, Young-Seak
    • Carbon letters
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    • v.9 no.4
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    • pp.294-297
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    • 2008
  • A CNT-$TiO_2$ nano composite was prepared from titanium chloride ($TiCl_4$) via sol-gel process using multi walled carbon nano tube (MWCNT) followed by calcination at $450^{\circ}C$. Spectral analysis revealed that the formed $TiO_2$ resided on the carbon in anatase form. The effect of adsorption was investigated using aqueous solution of methylene blue and procion blue dye. The photochemical reaction of CNT-$TiO_2$ composite in aqueous suspensions was studied under UV illumination in batch process. The reaction was investigated by monitoring the discoloration of the dyes employing UV-Visible spectro-photometeric technique as a function of irradiation time. The catalyst composites were found to be efficient for the photodegradation of the dye.