• 한국신재생에너지학회:학술대회논문집
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• 2009.06a
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• pp.386-388
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• 2009

차세대 에너지로 연료전지가 각광을 받고 있는 현재, 세계 각국에서는 연료전지의 상용화를 위해 노력하고 있다. 그러나 촉매분야에서 백금계 촉매의 사용량의 문제에 따른 매장량 한계점과 귀금속이라는 문제점이 존재하기 때문에 이에 대하여 대책강구가 필요한 시점이다. 이에 백금 촉매의 활성을 증대하고자 나노 크기의 제어 연구가 진행되고 있다. 또한, 촉매의 구조적인 면에 따라 촉매의 활성이 달라지는 점을 착안하여 백금계의 나노 형상 조절 연구와 백금계 촉매를 대체할 비백금계의 촉매 개발 연구가 활발히 진행되어지고 있다. 이에 본 연구는 백금계 촉매 중 Pd을 polyol process에 의한 나노 형상 조절을 통하여 단위 질량당(or 단위 부피당) 촉매의 활성을 높이고자 하였다. Polyol process에서는 환원제, 계면활성제, 온도, 시간, 기타 첨가제에 따라 나노 형상이 다르게 조절되는데, 이에 계면활성제로 PVP를 사용하고, 반응속도 및 형상조절을 위해 다양한 첨가제를 이용하여 polygonal Pd NPs을 형성하였다. 본 나노 형상 조절에서는 첨가제와 온도가 가장 큰 영향을 미치는 요인으로 착안하여 그에 따른 polygoanl Pd NPs의 사이즈 조절을 통해 전기화학 특성이 차이의 연구에 중점을 두었다. 이에 따라 나노 형상 조절이 된 Pd촉매를 이용하여 상용화된 촉매(Pd/C(XC-72R))에 비하여 전기화학적인 특성의 차이와 Pd 촉매의 촉매적 특성의 효과를 보고자 한다.

• Journal of the Korean Wood Science and Technology
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• v.48 no.2
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• pp.245-252
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• 2020

This study was performed to analyze the mechanical properties of tropical hybrid cross-laminated timber (CLT) with bamboo laminated board as the core layer in order to evaluate the possibility of its use as a CLT material. Bamboo board was used as the core layer and the tropical species Acacia mangium willd., from Indonesia, was used as the lamination in the outer layer. The modulus of elasticity (MOE), modulus of rupture (MOR), and shear strength of the hybrid CLT were measured according to APA PRG 320-2018 Standard for Performance-Rated Cross-Laminated Timber. The results show that the bending MOE of the hybrid CLT was found to be 2.76 times higher than SPF (Spruce Pine Fir) CLT. The reason why the high MOE value was shown in bamboo board and hybrid CLT applied bamboo board is because of high elasticity of bamboo fiber. However, the shear strength of the hybrid CLT was 0.8 times lower than shear strength of SPF CLT.

• Journal of the Korea Furniture Society
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• v.18 no.1
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• pp.39-46
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• 2007

This study was carried out to investigate the wood properties for efficient utilization of warm temperate tree species of Quercus acuta Thunb. grown in Korea. Fundamental wood properties in the anatomical, physical, mechanical and chemical characteristics were examined. Quercus acuta Thunb. is a radial-porous, straight grained and fine textured wood. The heartwood is not clearly distinguished from the sapwood. In physical properties, it has a high oven-dry specific gravity of $0.85{\pm}0.02$, and high shrinkage from green to air-dried condition of $7.05{\pm}0.52%$ in radial and $11.13{\pm}0.48%$ in tangential direction. Mechanical properties determined are strong with the MOR of $1,065{\pm}90kgf/cm^2$, and tensile strength parallel to grain of $1,490{\pm}258kgf/cm^2$ and shear strength of $175{\pm}13kgf/cm^2$. Also, this wood has high extractive contents: 11.11% for cold and 13.51% for hot water.

• Journal of the Korean Wood Science and Technology
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• v.22 no.3
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• pp.17-25
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• 1994

This study was carried out to compare the properties of Com-Ply Boards with those of OSBs. These two kinds of boards were made of same flakes. Com-Ply Boards were covered with three different thickness veneers, such as 4mm, 3mm, and 2.5mm. All manufactured Com-Ply Boards and OSBs were 12mm thick. In MOR, all Com-Ply Boards were higher than OSB, and especially 3mm-veneer and 2.5mm-veneer Com-Ply Board were highest. But OSB showed 420kg/$cm^2$. 3mm-veneer Com-Ply Board showed the highest internal bonding 7.0kg/$cm^2$ and then 2.5mm-veneer showed 6.8kg/$cm^2$, and OSB showed 6.6kg/$cm^2$. Screw holding strength showed the high value 23.9kg/$cm^2$, 25.5kg/$cm^2$, and 29.3kg/$cm^2$ respectively at 3mm-veneer, 2.5mm-veneer Com-Ply Board and OSB. Thickness swelling of Com-Ply Boards was lower than that of OSB, but Water absorption of OSB was lower. Finally it was very encouraging that all properties of OSB without veneer, whose cost is higher than flake and whose properties is better, were not worse than those of Com-Ply Board with veneer. It seems That more researches on OSB will be required.

• Journal of the Korean Ceramic Society
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• v.22 no.4
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• pp.33-39
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• 1985

A composition containing a-$Si_3N_4$ with 5w/0 $Y_2O_3$ and 4w/0 $Al_2O_3$ was hot-pressed at 1, $650^{\circ}C$ and 350kg/$cm^2$ for 1.5hrs and specimens of the same composition were pressureless-sintered at 1, 75$0^{\circ}C$ for 1.5 and 5hrs. By X-ray diffraction it was found that hot-pressed specimens were consisted of $\alpha$-and $\beta$-$Si_3N_4$ and sintered specimens were consisted of $\beta$-$Si_3N_4$ and $Si_3N-4Y_2O_3$ which was crystallized out from the grainboundary phase. The 5-hr sintered specimens had higher degree of crystallization than the 1.5 hr sintered specimens. Among these three different specimens the 5-hr sintered specimens showed the highest strength by hot MOR test at 1, 00$0^{\circ}C$. The SPT diagram for the 5-hr sintered $Si_3N_4$ was constructed by measurements of the stress rate dependence of fracture strength.

• Journal of the Korean Ceramic Society
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• v.52 no.1
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• pp.23-27
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• 2015

Recently, the use of ion-exchange strengthened glass has increased sharply, as it is now used as the cover glass for smart phone devices. Therefore, many researchers are focusing on methods that can be used to strengthen ion-exchange glass. However, research on how the improved strength can be maintained under thermal environment of device manufacturing is still insufficient. We tested the degradation of the characteristics of ion-exchange soda-lime glass samples, including their surface compressive stress characteristics, the depth of the ion-exchange layer (DOL), flexural strength, hardness, and modulus of rupture (MOR) values. Degradation of the characteristics of the ion-exchange glass samples occurred when they were heat-treated at a temperature that exceeded $350^{\circ}C$.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.6 no.2
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• pp.203-212
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• 1996

Applicability of SiC coating through CVD process and PCS(polycarbosilane) impregnation for the oxidation resistance and mechanical properties of C/C composite was studied. The SiC layer coated by CVD was deposited uniformly on the C/C composite, whereas the SiC converted from PCS impregnation wetted around individual carbon fiber. The PCS-impregnated C/C composite exhibited a significant increase of bending strength in comparison with as received C/C composite. This increase in the mechanical property could be attributed to the high bonding strength between fibers due to an impregnated SiC phase. The PCS-impregnated C/C showed 25% improvement in density, 3.5 times higher MOR and 2.8 times higher oxidation resistance compared to the as-received C/C. The increments due to PCS impregnation were more effective than CVD process.

• Journal of the Korean Ceramic Society
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• v.15 no.3
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• pp.157-167
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• 1978

The batch compositions and physical properties of slag-ceramics were studied with respect to their formability from the molten state and conditions of nucleation and crystal growth treatment. The selected batch compositions for nucleation and growth studies were slag, 56%; silica sand, 28%; $Na_2O＋MgO$, 8% and $TiO_2＋$chromite, 8%. The optimum nucleation condition was the temperature of 75$0^{\circ}C$ with 6 hrs. holding time and the optimum growth condition was the temperature 975$^{\circ}C$ with zero holding time. The slag-ceramics prepared under the above conditions showed the best developed microtexture. The grown crystals were identified as diopside with the average grain size of 5.7$\mu\textrm{m}$, and the amount of crystal grown were about 53% by weight. The prepared specimens of slag-ceramics showed the microhardness, 793kg/$\textrm{mm}^2$; MOR, 1,050 kg/$\textrm{cm}^2$ and thermal expansion coefficient, $85{\div}10^{-7}$cm/cm/$^{\circ}C$($25^{\circ}C$~$700^{\circ}C$).

• Journal of the Korea Furniture Society
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• v.15 no.2
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• pp.19-27
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• 2004

As glulam is a woody material, it is necessary to be more careful in a gluing process. It takes 6-7 hours at $40-60^{\circ}C$ to harden PRF resin used in making structural glulam, and about 24 hours at room temperature. In the present process which can not use a press continuously, reducing the hardening time is necessary to increase production. The experiment was done to compare the adhesive properties of PRF resin and MUF resin through bending test, block shear strength test and water soaking test. In comparing the bending strength of prediction MOE is 1.2 times higher that actual MOE. PRF and MUF do not show significant difference in MOE and MOR, and in block shear strength test, such as shear strength and wood failure rate. However, in water soaking and boiling water soaking tests PRF and MUF show the significant difference in delamination rate.

• Journal of the Korean Wood Science and Technology
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• v.33 no.5 s.133
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• pp.66-75
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• 2005

Soybean-based adhesives have recently been reconsidered as alternatives to petroleum-based adhesives due to the uncertainty of availability of petrochemical products and the increased demand for wood adhesives. This study was conducted to investigate the adhesive properties of alkaline phenolic soy (APS) resin for hybrid poplar flakeboard. The APS resin was formulated by crosslinking an alkaline soy flour hydrolyzate with lab-prepared PF resin in the soy hydrolyzate to PF resin weight ratios of 70/30, 60/40, and 50/50. The APS resins were used to fabricate homogeneous hybrid poplar flakeboards with different resin solid levels (5%, 7%, and 9%), press temperatures (175 and $200^{\circ}C$), and press times of 8 and 10 minutes. The IB, wet MOR, and dimensional stability properties of board improved with increasing press time, press temperature, and PF level in APS resins. Increasing press time can be used to offset poor IB strength associated with a 9% resin solid level and the excessive moisture content in the mat. The following conditions were concluded to meet the requirements of the CSA standard for exterior-grade flakeboard: a 50% PF level, a 5% resin content, a $200^{\circ}C$ press temperature, and an 8 minute press time.