• 제목/요약/키워드: MOF

검색결과 215건 처리시간 0.028초

자원이 제약된 장치에서 효율적인 타원곡선 다중 상수배의 구현을 위한 유연한 접근 (A Flexible Approach for Efficient Elliptic Curve Multi-Scalar Multiplication on Resource-constrained Devices)

  • 서석충;김형찬;라마크리시나
    • 정보보호학회논문지
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    • 제16권6호
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    • pp.95-109
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    • 2006
  • 타원곡선 암호시스템은 작은 키 길이로 인하여 스마트카드, 센서 모트와 같은 메모리, 계산 능력이 제약된 장치에서 사용하기에 적합하다. 본 논문에서는 이러한 장치에서 타원곡선 서명 알고리즘 검증 (uP+vQ, u, v: 상수, P, Q: 타원곡선 위의 점)의 주된 계산인 다중 상수배를 효율적으로 계산하기 위한 알고리즘을 제안한다. 제안 알고리즘은 부분 윈도우와 Interleave 방법에 기반을 둔 것으로서 어떠한 크기의 사전계산 테이블이라도 이용할 수 있을 뿐만 아니라, 해당 테이블에서 최적의 nonzero 밀도를 제공한다. 또한 상수 리코딩이 테이블 조회를 사용하지 않고 상수배 계산과 함께 진행되기 때문에 기존의 다른 알고리즘에 비하여 더욱 메모리를 절약할 수 있다. 실험을 통하여 163비트의 u, v와, 233 비트의 u, v에 대하여 uP+vQ를 수행하는 데 필요한 계산량을 사전계산 테이블의 크기에 따라 비교함으로써 최적의 테이블 크기는 각각 7, 15임을 알아낼 수 있었다.

ZIF-8과 탄소기반물질 복합체를 이용한 슈퍼커패시터 및 화학센서의 최신연구동향 (Recent research trend of supercapacitor and chemical sensor using composite of ZIF-8 and carbon-based material)

  • 김상준;이재민;조승근;이은빈;이승기;이정우
    • 한국표면공학회지
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    • 제55권2호
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    • pp.51-62
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    • 2022
  • Metal-organic framework (MOF) is one of the representative porous materials composed of metal ions and organic linkers. In spite of many advantages of the MOFs such as high specific surface area and ease of structure control, drawbacks have become obstacles to the practical use of them with poor electrical conductivity and chemical stability. The ZIF-8, which is consisted of zinc and imidazole linker, is one of the solutions to improve the chemical stability issue. In addition, composites using the ZIF-8 and carbonbased materials are widely used to enhance the electrical conductivity. In this regard, supercapacitor is very attractive field for using the composites, because most of carbon-based materials are porous and conductive. Also, for sensor applications, the ZIF-8 composite is suitable material to meet the requirement in terms of the selectivity and sensitivity. This review summarizes recent progress of the composite materials with the ZIF-8 and the carbon-based materials for the supercapacitors and the chemical sensors. In particular, the composites are classified into ZIF-8-graphene, ZIF-8-carbon nanotube and ZIF-8-other carbon-based material.

Study on Equivalent Consumption Minimization Strategy Application in PTI-PTO Mode of Diesel-Electric Hybrid Propulsion System for Ships

  • Lee, Dae-Hong;Kim, Jong-Su;Yoon, Kyoung-Kuk;Hur, Jae-Jung
    • 해양환경안전학회지
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    • 제28권3호
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    • pp.451-458
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    • 2022
  • In Korea, five major ports have been designated as sulfur oxide emission control areas to reduce air pollutant emissions, in accordance with Article 10 of the "Special Act on Port Air Quality" and Article 32 of the "Ship Pollution Prevention Regulations". As regulations against vessel-originated air pollutants (such as PM, CO2, NOx, and SOx) have been strengthened, the Ministry of Oceans and Fisheries(MOF) enacted rules that newly built public ships should adopt eco-friendly propulsion systems. However, particularly in diesel-electric hybrid propulsion systems,the demand for precise control schemes continues to grow as the fuel saving rate significantly varies depending on the control strategy applied. The conventional Power Take In-Power Take Off(PTI - PTO) mode control adopts a rule-based strategy, but this strategy is applied only in the low-load range and PTI mode; thus, an additional method is required to determine the optimal fuel consumption point. The proposed control method is designed to optimize fuel consumption by applying the equivalent consumption minimization strategy(ECMS) to the PTI - PTO mode by considering the characteristics of the specific fuel oil consumption(SFOC) of the engine in a diesel-electric hybrid propulsion system. To apply this method, a specific fishing vessel model operating on the Korean coast was selected to simulate the load operation environment of the ship. In this study, a 10.2% reduction was achieved in the MATLAB/SimDrive and SimElectric simulation by comparing the fuel consumption and CO2 emissions of the ship to which the conventional rule-based strategy was applied and that to which the ECMS was applied.

Metal-organic frameworks-driven ZnO-functionalized carbon nanotube fiber for NO2 sensor

  • Woo, Sungyoon;Jo, Mingyeong;Lee, Joon-Seok;Choi, Seung-Ho;Lee, Sungju;Jeong, Hyeon Su;Choi, Seon-Jin
    • 센서학회지
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    • 제30권6호
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    • pp.369-375
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    • 2021
  • In this study, heterogeneous ZnO/CNTF composites were developed to improve the NO2-sensing response, facilitated by the self-heating property. Highly conductive and mechanically stable CNTFs were prepared by a wet-spinning process assisted by the liquid crystal (LC) behavior of CNTs. Metal-organic frameworks (MOFs) of ZIF-8 were precipitated on the surface of the CNTF (ZIF-8/CNTF) via one-pot synthesis in solution. The subsequent calcination process resulted in the formation of the ZnO/CNTF composites. The calcination temperatures were controlled at 400, 500, and 600 ℃ in an N2 atmosphere to confirm the evolution of the microstructures and NO2-sensing properties. Gas sensor characterization was performed at 100 ℃ by applying a DC voltage to induce Joule heating through the CNTF. The results revealed that the ZnO/CNTF composite after calcination at 500 ℃ (ZnO/CNTF-500) exhibited an improved response (Rair/Rgas = 1.086) toward 20 ppm NO2 as compared to the pristine CNTF (Rair/Rgas = 1.063). Selective NO2-sensing properties were demonstrated with negligible responses toward interfering gas species such as H2S, NH3, CO, and toluene. Our approach for the synthesis of MOF-driven ZnO/CNTF composites can provide a new strategy for the fabrication of wearable gas sensors integrated with textile materials.

ZIF-67을 이용한 이기능성 촉매의 최신연구 동향 (Recent Research Trend of Zeolitic Imidazolate Framework-67 for Bifunctional Catalyst)

  • 김상준;조승근;박길령;이은빈;이재민;이정우
    • 한국재료학회지
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    • 제32권2호
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    • pp.98-106
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    • 2022
  • Metal-organic frameworks (MOFs) are widely used in various fields because they make it easy to control porous structures according to combinations of metal ions and organic linkers. In addition, ZIF (zeolitic imidazolate framework), a type of MOF, is made up of transition metal ions such as Co2+ or Zn2+ and linkers such as imidazole or imidazole derivatives. ZIF-67, composed of Co2+ and 2-methyl imidazole, exhibits both chemical stability and catalytic activity. Recently, due to increasing need for energy technology and carbon-neutral policies, catalysis applications have attracted tremendous research attention. Moreover, demand is increasing for material development in the electrocatalytic water splitting and metal-air battery fields; there is also a need for bifunctional catalysts capable of both oxidation/reduction reactions. This review summarizes recent progress of bifunctional catalysts for electrocatalytic water splitting and metal-air batteries using ZIF-67. In particular, the field is classified into areas of thermal decomposition, introduction of heterogeneous elements, and complex formation with carbon-based materials or polyacrylonitrile. This review also focuses on synthetic methods and performance evaluation.

MOF-Derived FeCo-Based Layered Double Hydroxides for Oxygen Evolution Reaction

  • Fang Zheng;Mayur A. Gaikwad;Jin Hyeok Kim
    • 한국재료학회지
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    • 제33권10호
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    • pp.377-384
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    • 2023
  • Exploring earth-abundant, highly effective and stable electrocatalysts for electrochemical water splitting is urgent and essential to the development of hydrogen (H2) energy technology. Iron-cobalt layered double hydroxide (FeCo-LDH) has been widely used as an electrocatalystfor OER due to its facile synthesis, tunable components, and low cost. However, LDH synthesized by the traditional hydrothermal method tends to easily agglomerate, resulting in an unstable structure that can change or dissolve in an alkaline solution. Therefore, studying the real active phase is highly significant in the design of electrochemical electrode materials. Here, metal-organic frameworks (MOFs) are used as template precursors to derive FeCo-LDH from different iron sources. Iron salts with different anions have a significant impact on the morphology and charge transfer properties of the resulting materials. FeCo-LDH synthesized from iron sulfate solution (FeCo-LDH-SO4) exhibits a hybrid structure of nanosheets and nanowires, quite different from other electrocatalysts that were synthesized from iron chloride and iron nitrate solutions. The final FeCo-LDH-SO4 had an overpotential of 247 mV with a low Tafel-slope of 60.6 mV dec-1 at a current density of 10 mA cm-2 and delivered a long-term stability of 40 h for the OER. This work provides an innovative and feasible strategy to construct efficient electrocatalysts.

키리바시 타라와의 지속가능발전목표 달성 지원을 위한 해수플랜트 기술 활용 (Application of Seawater Plant Technology for supporting the Achievement of SDGs in Tarawa, Kiribati)

  • 최미연;지호;이호생;문덕수;김현주
    • 적정기술학회지
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    • 제7권2호
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    • pp.136-143
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    • 2021
  • 키리바시를 포함한 태평양 도서국가들은 기후 변화, 지하수 오염 및 식생 변화로 인한 해수면 상승 및 해안 침식으로 인해 생활 공간의 감소 뿐만 아니라 필수 자원 부족으로 고통받고 있다. 이러한 문제를 해결하기 위한 글로벌 활동은 SDGs 이행을 위한 UN의 노력으로 진행되고 있다. 태평양 도서 국가들이 풍부한 해양 자원을 이용하여 기후 변화에 대응하고 적응할 수 있도록 모색해 왔다. 즉, 해수 플랜트는 이러한 태평양 도서 국가에서 SDG # 14를 기반으로 SDG #2, #6 및 #7을 달성하는 데 도움을 줄 수 있다. 선박해양플랜트연구소(KRISO)는 2016년에 설립한 지속가능 해수이용 아카데미(SSUA)를 통해 키리바시 SSUA협회를 결성하고, 해양수산부(MOF)의 해양수산 ODA사업으로 키리바시에 해수플랜트를 지원하였다. 키리바시 SSUA협회는 해수 및 태양에너지를 이용하는 해수플랜트를 이용하여, 2018년부터 2020년까지 지역 사회에 식수와 채소를 공급하는 공익사업을 하고 있다. 역량강화 과정을 통해 키리바시 SSUA협회는 기술 이전을 받았고, 지역사회에 수경재배 시스템의 설치, 모종과 비료 보급, 재배관리 기술지도 및 모니터링을 실시하였다. 협회는 3년 동안 140여 가구에 수경재배 시스템(일부는 태양광발전 패널 제공)을 보급하고, 다양한 채소를 재배하여 자가 소비 또는 판매하게 하였다. 또한, 태양광발전 연계 해수담수화 시스템을 설치하여 식수를 공급하도록 하고 있다. 만족도 조사를 통해 대부분의 수혜 가구가 만족하였고, 주변 지역 및 도서로 보급확산을 희망하고 있음을 알 수 있었다. 따라서, 키리바시 SSUA협회는 공동체 이용 및 관리 체계화를 지원하는 자활사업을 추진할 계획이며, 이러한 활동은 태평양 도서국가들의 SDGs 달성을 지원하기 위한 ODA 프로그램으로 확산될 수 있을 것이다.

신정부 국정과제 및 지질자원 분야 R&D 정책 방향 분석 (New Governmental National Agenda and New Executive Bodies' R&D Strategic Goals on Geoscience and Mineral Resources)

  • 안은영;이재욱;박정규
    • 자원환경지질
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    • 제46권5호
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    • pp.469-476
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    • 2013
  • 신정부 출범과 함께 박근혜 정부 140대 국정과제가 발표되었으며 미래창조과학부, 산업통상자원부, 해양수산부, 국토교통부, 환경부 등의 정부부처 또한 업무계획을 발표하였다. 정부 정책의 변화를 분석하고 그에 따른 연구개발을 추진하는 것은 공공 연구개발 기관의 주요 임무일 것이다. 이에 본고에서는 신정부의 R&D 정책 변화와 지질자원 관련 정부부처 R&D 정책 방향 및 전략 계획을 분석하였다. 분석 결과 일자리 중심의 창조경제와 안정 통합의 사회 구축을 위해 창조경제 생태계 조성, 창의와 혁신을 통한 과학기술 발전, 융합확산을 통한 성장동력 창출 및 안정적 에너지 시스템 구축, 환경창조산업 육성, 국민이 행복한 국토 창조를 실현하고자 하는 것을 확인할 수 있었다. 지질자원 분야에서도 원천기술/융복합기술을 중심의 새로운 가치를 창출하고, 미래 환경변화 트렌드와 고객 니즈에 부합하는 창의적 과제 발굴이 요구된다.

온열과 냉의 국소적용에 의한 체표면 온도와 근전도 활동의 변화 (Changes of Surface Temperature and Electromyography Activities by Local Heat and Cold)

  • 최석주;임상완;김수현;문달주
    • 대한임상전기생리학회지
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    • 제5권2호
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    • pp.61-72
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    • 2007
  • INTRODUCTION: Local heat and cold application has been frequently used as means of muscle relaxation and blood circulation or reinforcing muscle strength, relaxing muscle tension in clinical situation. In particular, it has been known that long-term heat and cold application for relaxing muscle tension inhibits muscle spasticity or tension. But, it has been rarely reported that what influences of heat and cold application on activation of muscle action potential. Therefore, this study aims to analyze surface temperature and electromyography activities according to the heat and cold application. METHODE: Subjects of this research were 10 normal men and women (5 men, 5 women). Hot pack and cold pack was applied to vastus medialis muscle of thigh and rectus femoris muscle for 20 min. Surface temperature of vastus medialis muscle and rectus femoris muscle was measured, knee joint of subjects was in $45^{\circ}$ flexion, sitting on a chair, maximal isometric contraction was induced, surface electromyography (sEMG) signals were collected and root mean square (RMS) and median frequency (MOF) were analyzed. All measurements were conducted before and immediately after experiment, 10 min., 20 min. and 30 min. after experiment. Data were analyzed with SPSS 12.0 program, comparison of changes in superficial temperature and sEMG signals through repeated measurement was conducted with repeated measures ANOVA and significance level $\alpha$ was 0.05. RESULTS: Changes of surface temperature of vastus medialis muscle according to cold application were radically decreased immediately after application, but it was recovered after 30 min. of application and it showed significant difference (F4. 36=72.216, P<0.001). Surface temperature of rectus femoris also showed radical decrease immediately after application, but it was recovered after 30 min. of application and showed significant difference (F4. 36=88.930, P<0.001). Changes of surface temperature of vastus medialis muscle according to heat application were radically increased immediately after application, but it was recovered after 30 min. of application and it showed significant difference (F4. 36=27.267, P<0.001). Surface temperature of rectus femoris also showed radical decrease immediately after application, but it was recovered after 30 min. of application and showed significant difference (F4. 36=19.774, P<0.001). Changes of sEMG by heat and cold application were no statistical difference. Surface temperature of skeletal muscle after heat and cold application showed significant change for 30 min., but it was found that increase or decrease of surface temperature had not great influence on sEMG activities.

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성능기반의 항만시설물 유지관리 의사결정체계 개발을 위한 데이터 연계방안 도출에 관한 연구 (A Study on the Development of the Data Linkage Method for Performance-based on Port Facility Maintenance Decision Marking System)

  • 김용희;강윤구
    • 한국산학기술학회논문지
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    • 제21권11호
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    • pp.9-18
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    • 2020
  • 최근 항만시설물의 효율적인 관리·운영을 위하여 전 생애주기에 걸친 통합관리 플랫폼 및 성능기반의 유지관리 의사결정체계 개발에 관한 연구가 활발히 진행되고 있다. 본 연구의 목적은 시설물을 성능의 관점에서 관리·운영하여 시설물의 장수명화와 효율적인 예산집행을 추구하는데 있다. 이를 위해서는 통합 플랫폼과 의사결정체계에서 분석할 충분한 양의 기초 데이터의 확보가 필수적이다. 이에 본 연구는 통합플랫폼 및 의사결정체계 개발의 기초데이터로 필요한 항만시설물 설계 및 유지관리 정보를 확보하기 위하여 현재 해양수산부에서 운영 중인 항만시설물 유지관리시스템(POMS; Port Facility Management System)과의 데이터 연계방안을 도출하는데 목적이 있다. 이를 위하여 POMS의 데이터베이스를 분석하였으며 이 중 통합플랫폼과 의사결정체계를 운영하는데 필요한 데이터 항목을 선정하고 이를 관계 전문가의 요구사항과 함께 종합적으로 검토하여 3개 분야의 연계대상을 선정하였다. 연계대상 데이터는 크게 항만과 항만시설물 데이터, 유지관리 데이터, 사용자 데이터로 분류할 수 있다. 각 세부 연계 데이터별로 API 인터페이스 설계서를 작성하였고, POMS의 연계 데이터와 통합플랫폼의 데이터 연계 프레임워크를 정의하였다. POMS와 통합 플랫폼의 데이터 연계는 플랫폼 개발 이후, 운영단계에서 실효성 있는 데이터를 실시간으로 수시 제공받아 통합 플랫폼 운영의 효율성을 향상시킬 것으로 기대된다.