• Journal of Powder Materials
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• v.27 no.6
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• pp.477-483
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• 2020

Metal-organic frameworks (MOFs) are of significant interest because of their high porosity, which facilitates their utilization in gas storage and catalysis. To enhance their current properties in these applications, it is necessary to elucidate the interactions between molecules in a confined environment that differ from those in bulk conditions. Herein, we study the confined molecular interaction by investigating the solvent-dependent photophysical properties of two different-sized molecules inside MOF-5. Ruthenium tris-bipyridine (Rubpy) and coumarin 153 (C153) are encapsulated in MOF-5. Rubpy with MOF-5 (Rubpy@MOF) is prepared by building MOF-5 around it, resulting in limited space for solvent molecules in the pores. The smaller C153 is encapsulated in the preformed MOF-5 (C153@MOF) by simply soaking the MOF in a concentrated C153 solution. C153@MOF permits more space for solvent molecules in the pore. Their characteristic absorption and emission spectra are examined to elucidate the confined molecular interactions. Rubpy@MOF and C153@MOF exhibit different spectral shifts compared to the guest molecules under bulk conditions. This discrepancy is attributed to the different micro-environments inside the pores, derived from confined host-guest interactions in the interplay of solvent molecules.

• Proceedings of the Korean Information Science Society Conference
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• 2003.10b
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• pp.307-309
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• 2003

모델을 중심으로 하는 MDA 개발 환경에서는 많은 모델링이 필요하다. 기본적으로 MDA의 기본 단계인 CIM, PIM, PSM 단계의 모델링이 필요하며, 각 단계에서 추상화 수준, 뷰포인트 등에 따라 다양한 다이어그램이 필요하다. 현재 MDA 의 PIM과 PSM 을 상대적인 개념으로 인식하기 때문에 MDA의 단계는 더욱 확대될 것이다. 본 논문에서는 분산 환경에서 컴포넌트 기반 엔터프라이즈 시스템을 개발하기 위한 EDOC 프로파일을 중심으로 MOF 기반 모델링을 수행하는 방법과 프로토타입을 기술한다. OMG 의 제안한 메타모델 표준인 MOF를 이용하므로 JMI, MOF XMI, MOF IDL 매핑을 이용할 수 있는 장점을 갖게 된다.

• Carbon letters
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• v.10 no.1
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• pp.19-22
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• 2009

In this work, the hydrogen storage behaviors of carbon nanotubes (CNTs)/metal-organic frameworks-5 (MOF-5) hybrid composites (CNTs/MOF-5) were studied. Hydrothermal synthesis of MOF-5 was conducted by conventional convection heating using 1-methyl-2-pyrrolidone (NMP) as a solvent. Morphological characteristics and average size of the CNTs/MOF-5 were also obtained using a scanning electron microscopy (SEM). The pore structure and specific surface area of the CNTs/MOF-5 were analyzed by N2/77 K adsorption isotherms. The capacity of hydrogen storage of the CNTs/MOF-5 was investigated at 298 K/100 bar. As a result, the CNTs/MOF-5 had crystalline structures which were formed by hybrid synthesis process. It was noted that the CNTs/MOF-5 can be potentially encouraging materials for hydrogen adsorption and storage applications at room temperature.

• Proceedings of the KIEE Conference
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• 2011.07a
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• pp.2089-2090
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• 2011

본 논문에서는 MOF 소손시 비오차 발생으로 인한 전력사용량에 미치는 영향을 분석하기 위해 비오차를 측정하였다. 현재 MOF 고장건수는 전체파급고장의 약 10%이상 발생되고 있으며, 현장 순회시험을 통해 2009년 68건, 2010년 156건을 적출하였다. 이러한 MOF의 고장은 대부분 내부 CT 권선소손에 의해 발생되며, CT의 1차코일 또는 2차코일 단락시 유형별로 실험을 통해 비오차를 분석하였다. 특히 3상 수전고객은 ${\Delta}$-Y결선방식으로 MOF 정상시 불평형 전류는 중성선의 전류가 발생되지 않으나, MOF 이상시 중성선에 이상전류가 발생된다. 따라서 중성선의 이상전류를 측정하여 MOF 이상유무 판정 및 과부족 계량 오차 판정을 하기 위한 자료로 활용하였다.

• Proceedings of the KIEE Conference
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• 2003.07c
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• pp.1753-1755
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• 2003

MOF insulating cover used in 22.9 kV substation hasn't shown good performance in terms of electrical safety because of its defect by short clearance MOF cover and each input and output wire junction part. The MOF cover is easily moved by outside environment as wind or rain weather because of different size MOF cover and insulating busing, also can be leaded to breakdown by tracking. Therefore, we propose MOF cover which effectively prevents from electrical accidents in this paper. To decrease the electric field concentrated on specific part, we roundly design the shape of MOF cover and clearance between cover and live part was adjusted to be longer than before. The proposed MOF cover is evaluated by using the electric field solution program.

• Applied Chemistry for Engineering
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• v.30 no.5
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• pp.615-619
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• 2019

Statistical design of experiments was performed to optimize MOF-235 synthesis process. Concentrations of terephthalic acid (TPA), iron (III) chloride hexahydrate, N,N-dimethylformamide (DMF) and ethanol were important factors to develop the crystal structure of MOF-235. MOF-235 was synthesized with various concentrations of the listed chemicals above and the crystallinity was measured by XRD. The effect of the composition on the synthesis of MOF-235 was evaluated using a statistical analysis. For the variance analysis using F-test, the concentration of ethanol showed the greatest effect on the crystallinity and TPA the least influential. A regression model for predicting the crystallinity of MOF-235 was derived and the prediction results for two synthetic variables were presented using contour plots. Finally, the crystallinity was predicted by a mixture method with $FeCl_3$, ethanol and DMF.

• Korean Journal of Adult Nursing
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• v.17 no.5
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• pp.762-771
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• 2005

Purpose: The purpose of this study was to identify characteristics of patients who were recipients of decision-making DNR, to describe the situations of DNR, and to analyze the APACHE III and MOF scores. Method: Data collection was conducted through reviews of medical records of 51 patients and through interviews with families of patients who were decision-makers for DNR at C university K Hospital located in Seoul from April to September 2002. Results: The men's APACHE III and MOF scores were higher than the women's and the non cancer patients were higher than cancer patients. Some 80.4% of DNR orders was by communication, while 11.8% of consents were written. Each of APACHE III and MOF scores of patients in the intensive care unit was higher than the patients in general ward at both points of admission and decision-making of DNR. APACHE III and MOF scores positively correlated statistically with each other. Conclusions: The findings of this study suggest that APACHE III and MOF scores be useful for decision-making of DNR as a tool measuring severity.

• Applied Chemistry for Engineering
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• v.31 no.4
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• pp.377-382
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• 2020

A sequential design of experiments was employed to optimize MOF-235 synthesis for acetylene adsorption process. Two experimental designs were applied: a two-level factorial design for screening and a central composite design, one of response surface methodologies (RSM). In this study, 2³ factorial design of experiment was used to evaluate the effect of parameters of synthesis temperature and time, and also mixing speed on crystallinity of MOF-235. Experiments were conducted 16 times follwing MINITAB 19 design software for MOF-235 synthesis. Half-normal, pareto, residual, main and interaction effects were drawn based on the XRD results. The analysis of variance (ANOVA) of test results depicts that the synthesis temperature and time have significant effects on the crystallinity of MOF-235 (response variable). After screening, a central composite design was performed to optimize the acetylene adsorption capacity of MOF-235 based on synthesis conditions. From nine runs designed by MINITAB 19, the result was calculated using the second order model equation. It was estimated that the maximum adsorption capacity (18.7 mmol/g) was observed for MOF-235 synthesized at optimum conditions of 86.3 ℃ and 28.7 h.

• 한국전산유체공학회:학술대회논문집
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• 2009.11a
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• pp.228-230
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• 2009

The moment-of-fluid (MOF) method is a new volume-tracking method that accurately treats evolving material interfaces. Based on the moment data (volume and centroid) for each material, the material interfaces are reconstructed with second-order spatial accuracy in a strictly conservative manner. The MOF method is coupled with a stabilized finite element incompressible Navier-Stokes solver for two fluids, namely water and air. The effectiveness of the MOF method is demonstrated with a free-surface dam-break problem.

• Journal of the Korea Organic Resources Recycling Association
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• v.29 no.1
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• pp.47-57
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• 2021

This study was conducted to evaluate the properties of mixtures of mixed organic fertilizer (MOF) and various organic sources such as livestock manure compost (LMC), dried compost of poultry manure (CPM), dried food waste powder (FWP) and amino acid by-product fertilizer (ABF) and their influences on growth of lettuce and Chinese cabbage. The content of N, P2O5 and K2O of mixture of MOF, LMC and FWP (MLF) was 3.6~3.9%, 2.1~2.2% and 1.3~1.4%, respectively. Lettuce dry weight of MLF3 treatment blending with MOF (60%), LMC (10%) and FWP (30%) was increased by about 29% than that of MOF. The content of N, P2O5 and K2O of mixture of MOF, CPM, FWP and ABF (MCFA) was 4.5~4.7%, 1.7~1.9% and 1.3~1.4%, respectively. Compared to MOF, growth factors of lettuce and Chinese cabbage in the MCFA treatments were not significantly deferent. These results indicated that MLFs and MCFAs, the mixtures of respectively organic sources and MOF, could be applied as orgnic fertilizer in the cultivation of lettuce and Chinese cabbage, and were expected that LMC and ABF might be used as another sources of organic fertilizer.