• Journal of the Korean Ceramic Society
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• v.44 no.4 s.299
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• pp.214-218
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• 2007

The decrease of polarization resistance in cathode is the key point for operating at intermediate temperature SOFC (solid oxide fuel cell). In this study, the influence of Co substitution in B-site at complex perovskite on the electronic conductivity of PSCM ($Pr_{0.3}Sr_{0.7}Co_xMn_{(1-x)}$) was investigated. The PSCM series exhibits excellent MIEC (mixed ionic electronic conductor) properties. The ASR (area specific resistance) of PSCM3773 was $0.174{\Omega}{\cdot}cm^2\;at\;700^{\circ}C$. The activation energy of PSCM3773 was also lower than other compositions of PSCM. The TEC(thermal expansion coefficient) was decreased by addition of Mn. The ASR values were increased gradually during the thermal cycling test of PSCM37773 due to the delamination between electrolyte and cathode materials. The delamination was caused by the difference of TEC.

• Journal of Korea Foundry Society
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• v.24 no.3
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• pp.138-144
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• 2004

Effects of alloying elements such as Si, Mn, Zn on the fluidity and mechanical properties of high ductility Al-Mg based alloys were investigated. The fluidity of alloys was evaluated using a vacuum suction fluidity test, and Si addition was observed to increase the fluidity of AI-Mg binary alloys substantially while Zn somewhat decreased the fluidity. However, both the strength and ductility were significantly deteriorated by the Si additions. It was observed that a small amount of Mn addition to Al-Mg alloy increased the tensile strength effectively without losing much ductility but the effect of Zn addition on the strength was relatively small.

• Journal of the Korean Society for Heat Treatment
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• v.14 no.5
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• pp.267-274
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• 2001

Microalloyed steels, which substituted by conventional quenched and tempered steels, have been used in a wide variety of structural and engineering application. The main driving force for preference of MA steels is a cost reduction which can be achieved by an omission of heat treatment. In this study, low carbon martensitic MA steels in 0.18C-0.30(0.60)Si-2.00(1.80)Mn-0.05S-1.5Cr-0.05(0.10)V-0.015Ti(wt%) were investigated to know the effects of cooling method on the mechanical properties and microstructures of Si, Mn, V added microalloyed steel at different reheating temperature. Microstructure of oil quenched steels which were comprised lath martensite, auto-tempered martensite and retained austenite, had more various structure than that of air cooled steel made of mainly bainite. Therefore, oil quenched steels, which had more various microstructure, had better strength-toughness balance compare to air cooled steels. In the impact test, fracture mode of oil quenched steels, which showed good mechanical properties, were dimple, but that of air cooled steels were cleavage.

• Journal of Pharmaceutical Investigation
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• v.4 no.4
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• pp.17-25
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• 1974

1. Neutron acivation analysis of arsenic contained in Korean human liver was studied in the view point of forensic chemistry, using 12 corpses. A sample of 1g was irradiated for 30 mins. in a neutron flux of $1.2{\times}10^{12}n/cm^2/sec$, followed by nitric-sulfuric acid digestion and then by Gutzeit separation. Radio activity was detected by it's scintillation counter. The arsenic content in the liver was found to be $0.01{\mu}g/g$ to $0.15{\mu}g/g$. 2. A rapid and convenient method for the radiochemical determination of minerals by neutron activation analysis was established. After neutron irradiation to the standard soln. of Cu and Mn in pneumatic tube (neutron flux : $1.2{\times}10^{12}n/cm^2/sec$), Cu and Mn were determined by estimating the ratio of the widths under energy peak area in ${\gamma}-ray-spectrogram$. When the standard soln. of Mn and Cu is irradiated for 15 mins. to 18 hrs., recovery test shows that the relative errors are 5.1% and 4.5% for copper and manganese, respectively.

• Korean Journal of Materials Research
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• v.29 no.3
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• pp.189-195
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• 2019

The effect of C, Mn, and Al additions on the tensile and Charpy impact properties of austenitic high-manganese steels for cryogenic applications is investigated in terms of the deformation mechanism dependent on stacking fault energy and austenite stability. The addition of the alloying elements usually increases the stacking fault energy, which is calculated using a modified thermodynamic model. Although the yield strength of austenitic high-manganese steels is increased by the addition of the alloying elements, the tensile strength is significantly affected by the deformation mechanism associated with stacking fault energy because of grain size refinement caused by deformation twinning and mobile dislocations generated during deformation-induced martensite transformation. None of the austenitic high-manganese steels exhibit clear ductile-brittle transition behavior, but their absorbed energy gradually decreases with lowering test temperature, regardless of the alloying elements. However, the combined addition of Mn and Al to the austenitic high-manganese steels suppresses the decrease in absorbed energy with a decreasing temperature by enhancing austenite stability.

• Journal of Electrochemical Science and Technology
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• v.10 no.2
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• pp.159-169
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• 2019

The activated carbon materials were prepared from waste biomass by ultrasonic assisted chemical activation method (UCA), ultrasonic assisted physical activation method (UPA) and Manganese nitrogen doped carbon (Mn/N-C). The XRD result shows the turbostatic (fully disordered) structure. The cyclic voltammetry test was done at 50 mV/s using 1M sodium sulfate and the values of specific capacitance were found to be 93, 100 and 115 F/g for UCA, UPA and Mn/N-C respectively. The power density values for the samples UCA, UPA and Mn/N-C were found to be 46.04, 87.97 and 131.42 W/kg respectively. The electrochemical impedance spectroscopy was done at low frequency between 1 to 10 kHz. The Nyquist plot gives the resistant characteristics of the materials due to diffusional resistance at the electrode-electrolyte interface. The Energy Dispersive X-Ray Spectroscopyanalysis (EDAX) analysis showed that the percentage doping of nitrogen and manganese were 3.53 wt% and 9.44 wt% respectively. It is observed from the experiment Mn/N-C doped carbon show good physical and electrochemical properties.

• Korean Journal of Materials Research
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• v.12 no.8
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• pp.624-633
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• 2002

In order to improve the hydrogen storage capacity and the activation properties of the hydrogen storage alloys, the rare-earth metal alloy series, MmN $i_{4.5}$M $n_{0.5}$Z $r_{x}$(x=0, 0.025, 0.05, 0.1), are prepared by adding excess Zr in MmN $i_{4.5}$M $n_{0.5}$ alloy. The various parts in hydrogen storage vessel consisted of copper pipes reached the setting temperature within 4~5 minutes after heat addition, which indicated that storage vessel had a good heat conductivity required in application. The performance test on storage vessel filled with rare-earth metal alloys of 1000 gr was also conducted after hydrogen charging for 10 min at $18^{\circ}C$ under 10 atm. It showed that the average capacity of discharged hydrogen volume was found to be for $MmNi_{4.5}$ $Mn_{0.5}$ and $MmNi_{4.5}$ $Mn_{x}$ 0.5/$Zr_{samples}$ indicated that the released amount of hydrogen for this $AB_{5}$ type alloys was more than 92 % of theoretic value, and also it was found that the optimum discharging temperature for obtaining an appropriate pressure of 3 atm was determined to be $V^{\circ}C$ for $MmNi_{4.5}$ $Mn_{0.5}$$Zr_{x}$(x=0, 0.025, 0.05, 0.1) hydrogen storage alloys. The released amount of these hydrogen storage samples was 125 $\ell$ , 122.4 $\ell$ and 108.15 $\ell$/kg for $MmNi_{4.5}$ $Mn_{0.5}$ $Zr_{0.025}$ $MmNi_{4.5}$M $n_{0.5}$Z $r_{0.05}$, and MmN $i_{4.5}$ Mn_0.5$Zr_{0}$, at $70^{\circ}C$ respectively. Amount of the 2nd phases increase with increase on Zr contents in $MmNi_{4.5}$$Mn_{0.5}$ $Zr_{ 0.1}$/ alloy. This phenomenon indicates that$ ZrNi_3$ in $MmNi_{4.5}$ $Mn_{0.5}$ $Zr_{x}$ / phase, which shows the maximum storage capacity and the strong resistance to intrinsic degradation, is considered as a proper alloy for hydrogen storage. As the Zr contents increase, the activation time and the plateau pressure decreases and sloping of the plateau pressure increases.creases.eases.s.

• Journal of the Korean Magnetics Society
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• v.8 no.6
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• pp.362-368
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• 1998

The magnetic properties, thermal stability and anti-corrosion properties of $Cr_86Al_14$ spin valves multilayers were studied. It was found that the magnetic properties of $Cr_86Al_14$ spin valves depend on the thickness of antiferromagnetic, ferromagnetic and non-ferromagnetic layers. Exchange coupled field ($H_{ex}$) and magnetoresistance ratio (%) showed the largest value of 20 Oe, 2 % in $glass/Cr_{86}Al_{14}(600 $\AA$)/Ni_{81}Fe_{19}(50$\AA$)/Cu(40 $\AA$)/Ni_{81}Fe_{19}(40 $\AA$)$ spin valves. The $H_{ex}$ MR ratios (%) of CrAl and FeMn spin valves were decreased with increasing annealing temperatures and were lost at 150 $^{\circ}C$, 250 $^{\circ}C$ respectively. Based on these result, it was elucidated that CrAl is more thermally stable than FeMn. It was also shown that there was no change of $H_{ex}$ MR ratios in CrAl, while FeMn was changed and lost 15 days later in corrosion resistance test under 35 $^{\circ}C$, 90 % humidity condition. FeMn was found to be pitted and peeled off 15 days later by SEM micrographic analysis.

• Membrane Journal
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• v.12 no.2
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• pp.67-74
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• 2002

Submerged membrane bioreactor(SMBR) and reverse osmosis(R/O) systems treated dye wastewater for reusing of industrial water. The permeate fluxes of SMBR at 20-25 cmHg of lab. test and field test were 10 LMH($1/m^2$.hr) all test. Removal efficiencies of CODcr, $COD_{Mn}$ and T-N were 93%, 90% and 60% in the SMBR, respectively The advanced treatment of combined process(SMBR+R/0) was accomplished for increasing the removal efficiency of non-biodegradable materials and T-N. Therefore, the removal efficiency of T-N obtained in 80% above, then nitrogen concentration was under 15 mg/L. The combined process(SMBR+R/0) was suitable to reuse of the dye wastewater.

• Journal of Welding and Joining
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• v.7 no.4
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• pp.30-37
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• 1989

Effect of heat treatment on mechanical properties of an overlay weldment was investigated. Over welding was carried out on the structural C-Mn mild steel substrate to take required test specimens. Shielded metal arc welding process with 13Cr-0.2Ni stick electrode was applied. The heat treatment temperatures and holding times were $450{\circ}C., 550{\circ}C., 650{\circ}C., 750{\circ}C., 850{\circ}C.$ and 0.5hr, 2hr, 10hr, respectively. Mechanical tests and microscopic inspection were also carried out to investigate welds soundness. Test results indicated that carbon migration was dominant near bonded zone. At temperature of around 650.deg. C, carburized layer and decarburized layer were formed remarkably along overlay welds region and C-Mn mild steel region, respectively. The wideth of these layers became wider with increasing heat treatment temperature and/or holding time at the elevated temperature, and this relationship agreed with Larson-Miller parameter. Side bending test results demonstrated that the crack free region of overlay welds could be deduced from the relationship between temperature and holding time.