• Journal of the Korean Applied Science and Technology
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• v.22 no.4
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• pp.355-361
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• 2005

The physical characteristics of polyurethane were examined by SEM, FT-IR tensile strength and mole % [NCO/OH]. Growing concerns in the environment-friendly architecture and public works have led to the development of solvent-free formulations that can be cured and foamed in air. Compared with general packing materials, this resin is much stronger in intensity and much longer in durability. Polyurethane foam resins were mainly composed of polyol, MDI, silicone surfactant, fillers, catalyst and blowing agent. The rigid foam of polyurethane in mechanical characteristics were due to chain extender and the increase of mole % [NCO/OH]. The change in the microstructure of polyurethane should be taken into account when considering the process of construction and durability through the polyurethane polymer resin in lots of industries.

• The Korean Journal of Rheology
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• v.9 no.1
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• pp.33-39
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• 1997

PCL, MDI, BD 및 DMPA를 이용, 폴리우레탄(PU)을 ionomer 및 nonionomergudxo 로 제조하였으며 이때 연질성분의 함량(SSC) 및 길이가 PU의 기계적, 동적기계적 특성은 물론 형상기억특성에 미치는 영향을 연구하였다. Ionomer는 nonionomer에 비하여 경도, 탄 성율 및 강도가 모두 우수하였으며 그 효과는 실온에서 경질성분의 함량(HSC)이 높은 PU 일수록 보다 뚜렷하였는데 이는 HSC가 증가할수록 ion 중심의 농도가 증가하며 ion 중심간 의 Coulob 력이 고온보다 실온에서 보다 큰데 기인하는 것으로 해석하였다. 반복인장하중실 험에서 ionomer는 nonionomer에 비해 회복변형이 크고 잔류변형이 작았는데 이는 ionomer 의 고무탄성율이 보다 큰 데 기인한 것으로 해석하였다. 나아가 재료의 형상기억거동은 기 본적으로 탄성율의 온도의존성에 크게 의존함을 알수있었다.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.14 no.6
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• pp.503-511
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• 2002

Heat flow characteristics during hot water extraction process was studied experimentally. Data were taken at various outlet port type for the fixed inlet port type, inlet-outlet temperature differences and mass flow rates. In this study, the temperature distribution in a storage tank and an outlet temperature were measured to predict a degree of stratification in the storage tank, and a useful rate of hot water was analysed with respect to the variables dominating a extraction process. Experimental results show that the degree of stratification and useful rate of hot water are all high in a low flow rate in case of using modified distributor I (MDI) as the outlet port type.

• Macromolecular Research
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• v.16 no.5
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• pp.467-472
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• 2008

Rigid polyurethane foams (RPUFs) were fabricated from crude MDI (CMDI) and polypropylene glycols (PPGs) of various isocyanate indices with a physical blowing agent (HFC 365mfc). There was a tendency for the gel time to decrease and the tack-free time to increase with increasing index value. With increasing index value the foam density and compression strength decreased and the glass transition temperature, dimension stability and thermal insulation increased, while the cell size and closed cell content were virtually unchanged. Allophanate crosslinks and condensation reactions between the isocyanate groups, which are favored with a high index value, exerted significant effects on the properties of RPUFs.

• Elastomers and Composites
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• v.53 no.2
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• pp.86-94
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• 2018

The effect of the NCO index and catalyst type on the thermal stability of poly(urethane-isocyanurate) (PUIR) foams was investigated to identify a method for enhancing the flame resistance of PUIR. PUIR foams were prepared using 4,4-diphenylmethane diisocyanate (MDI) and [(diethylene glycol)adipate]diol, which were synthesized by esterification of adipic acid and diethylene glycol. Dabco K-15, Dabco TMR-30, and Toyocat RX-5 were used as the catalysts for trimerization and gelation. The amount of urea and isocyanurate groups in PUIR was semi-quantitatively determined by normalizing their absorbance with the phenyl absorbance measured by FT-IR. The normalization data showed that Dabco TMR-30 effectively generated isocyanurate groups in PUIR. As a result, Dabco TMR-30 effectively raised the decomposition temperature and increased the 800 K and 900 K residues of the PUIR foam synthesized with an NCO index of 200.

• Elastomers and Composites
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• v.27 no.4
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• pp.267-274
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• 1992

Polydimethylsiloxane(PDMS)-containing polyurethane coating materials were synthesized because PDMS-based elastomers have unique properties including an extremely low glass transition temperature, good thermal and oxidative stability, and good dielectric properties. In this experiment a vinyl copolymer which consisted of vinyl chloride, vinyl acetate, vinyl alcohol, and maleic acid was used, and Coronate L was used as a polyisocyanate. PDMS-containing polyurethane was synthesized from polydimethylsiloxane, MDI, and 1,4-butanediol. Films were casted by reaction of viny copolymer, Coronate L, and PDMS-containing polyurethane. Thickness of tile films were $150-170{\mu}m$ and the films were characterized by IR, DSC, and Instron.

• Elastomers and Composites
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• v.34 no.4
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• pp.285-291
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• 1999

Effects of catalysts on network structure, hard segment length and distribution of polyurethane foams in the absence of catalysts were investigated. CFC free all MDI-based poly urethane foams were prepared from poly(ethylene adipate)glycol, 4,4'-diphenylmethane diisocyanate, and water. Amino catalysts used were 1,4-diazabicyclo[2,2,2]octane(DABCO), N, N,N',N'-tetramethyl--hexane-1,6-diamine(MR), bis(2-methylamino ethyl)ether(ET), 1,8-diazabicyclo-[5,4,0]-undecene-7(DBU). Dibutyltindilaurate(DBTL) as control was also used. Hard segment components of polyurethane foams were obtained by a selective degradation of polyester chains with 0.01N KOH-methanol solution. The PUFs with DBU catalyst contained more amount of isocyanurate components than other PUFs. On the other hand, the PUFs with ET, MR, DBTL catalysts contained more amount of allophanate and biuret component than the other PUFs.

• Elastomers and Composites
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• v.55 no.1
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• pp.20-25
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• 2020

The effect of the isocyanate index (NCO index) on the particle size and particle size distribution of a waterborne polyurethane dispersion (WPUD) with polycarbonate-diol was determined. The WPUDs were prepared using a conventional acetone process with polycarbonate-polyol (M_n = 2028), 4,4'-methylenebis(cyclohexyl isocyanate) (H₁₂MDI), 2,2-bis(hydroxymethyl) propionic acid (DMPA), and dibutyltin dilaurate catalyst. At NCO index values below 1.5, the number average particle diameter of the WPUDs significantly increased with the NCO index, whereas the particle diameter slightly varied at higher NCO indexes. The dependency of the WPUD viscosity on the NCO index exhibited similar behavior to that of the particle size. The relative values of the full width at half maximum of the WPUD particle distribution curves at various NCO indexes were not influenced by the NCO index.

• The Bulletin of The Korean Astronomical Society
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• v.37 no.2
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• pp.114.2-114.2
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• 2012

태양 광구표면에서 시선방향 자기장 자료를 살펴보면 그 극성이 변하는 지점들이 선의 형태로 보이는데 이것을 Magnetic Polarity Inversion Line(MPIL) 혹은 Neutral Line이라 부른다. 기존의 연구에 의하면 태양활동영역에서 MPIL의 길이가 길수록 플레어 및 코로나물질방출(CME)과 같은 큰 규모의 분출현상들이 일어나는 빈도가 높다는 사실이 보고된 바 있다. 이런 점에서 볼 때 MPIL이 우주환경 예보의 측면에서 중요한 도구가 될 수 있을 것으로 기대된다. 하지만 여전히 MPIL의 기하학적, 물리적 특성 및 그 형성과 진화과정에 대한 이해가 부족한 상황이다. 우리는 본 연구에서 SOHO/MDI 시선방향 자기장 자료를 사용하여 태양활동 23주기에 나타난 308개의 태양활동영역에 대하여 MPIL의 길이, 곡률과 같은 기하학적인 특성을 연구하였고, 또한 MPIL주변의 자기장(평균 자기선속, 총 자기선속 등) 및 magnetic fragment들의 속도장(평균속력, 수렴 및 발산정도, vorticity 등)과 같은 물리적인 특성에 대한 통계적 조사를 수행하였다.

• The Bulletin of The Korean Astronomical Society
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• v.37 no.2
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• pp.130.2-130.2
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• 2012

태양의 활동영역에서 관측할 수 있는 흑점은 주로 흑점군으로 관측되며, 태양폭발현상의 발생을 예보하기 위한 중요한 관측 대상 중 하나이다. 현재 태양 폭발을 예보하는 모델들은 McIntosh 흑점군 분류법을 사용하며 통계적 모델과 기계학습 모델로 나누어진다. 컴퓨터는 흑점군의 형태학적 특성을 연속적인 값으로 계산하지만 흑점군의 형태적 다양성으로 인해 McIntosh 분류를 잘못 분류할 수도 있다. 이러한 이유로 컴퓨터가 계산한 흑점군의 형태학적인 특성을 예보에 직접 적용하는 것이 필요하다. 우리는 흑점군의 형태학적인 특성(개수, 면적, 면적비 등)과 함께 모든 흑점을 정점(Vertex)으로 하고 그 사이를 연결하는 간선(Edge)으로 하는 간선의 거리 합이 최소인 최소신장트리(Minimum spanning tree : MST)를 작성하였다. 이 최소신장트리를 사용하여 흑점군을 검출하고 가장 면적이 큰 정점을 중심으로 트리의 깊이(Depth)와 차수(Degree)를 계산하였다. 이 방법을 2003년 SOHO/MDI의 태양 가시광 영상에 적용하여 구한 흑점군의 내부 흑점수와 면적은 NOAA에서 산출한 값들과 90%, 99%의 좋은 상관관계를 가졌다. 우리는 이 연구를 통해 흑점군의 형태학적인 특성과 더불어 예보에 직접적으로 활용할 수 있는 방법을 논의하고자 한다.