• 상하수도학회지
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• 제23권5호
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• pp.527-537
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• 2009

Three sets of parallel MBRs (reactor No.1, reactor No.2, reactor No.3) maintaining an MLSS of 4,000 mg/L, 6,000 mg/L and 8,000 mg/L, respectively, were operated to investigate the effect of various HRTs and DO concentration of MBRs on the removal efficiency of organic matters and nitrogen. The HRTs were operated on 4 hr, 6 hr, 8 hr. DO concentrations were ranged 1.5~2.0 mg/L and 0.5~1.0 mg/L respectively on each HRT conditions. MBR was divided into an aerated part and non-aerated part by baffle placed under the water. DO concentrations were controlled by altering the position of baffle. In terms of TSS and CODCr, all systems had a similar level of the removal under varied HRTs and MLSS. TSS removal efficiency was more than 99% and CODCr removal was ranged 94~97% under all conditions. Under the same condition on the HRT and MLSS concentrations, DO concentrations did not affect the organic removal efficiency. On the nitrification efficiency, with high DO concentration, as HRT or MLSS increased, the slight increment of nitrification efficiency was observed. However, under the low DO concentration, increase of MLSS and HRT resulted in larger increase of the nitrification efficiency. At the same HRT and MLSS, the nitrification efficiency increased greatly with up to 16% as DO increased. When the HRT increased from 4hr to 8hr, the denitrification efficiency slightly increased under most of conditions. However, the increase of MLSS resulted in about 19~39% denitrification efficiency increment. MLSS concentrations showed great effect on the denitrification. The increase of the DO concentration at the same HRT and MLSS resulted in decrease of denitrification efficiency with up to 27%. In all systems, the denitrification efficiency had more influence on the TN removal efficiency than nitrification efficiency. So, MLSS concentration has greater effect on the TN removal than HRT and DO. The TN removal efficiency increased as MLSS increased with up to 37%. As a result, the highest TN removal efficiency was observed 79.0% at the condition showed the highest denitrification efficiency that DO of 0.5~1.0 mg/L, an HRT of 8 hr, and 8,000 mg/L of MLSS concentration were maintained.

• 한국환경과학회지
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• 제25권6호
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• pp.817-827
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• 2016

The resistance in series model has been frequently used for determination of various filtration resistance to correctly understand the membrane fouling behaviour in MBR (membrane bio-reactor) for wastewater treatment. The cake layer resistance ($R_c$) which is commonly determined by calculation of flux dataset that are obtained empirically before and after removing the cake layer on membrane surface. However, the calculated Rc values are very dependent on the cleaning methods adapted for removal of cake layer. This study investigated how the various cleaning options affect $R_c$. Seven different cleaning methods were employed: i) ultrasonication (100 W, 10 min), ii) ultrasonication (200 W, 60 min), iii) ultrasonication (400 W, 120 min), iv) water rinsing in a shaker (100 rpm, 10 min), v) water rinsing in a shaker (300 rpm, 60 min), vi) water rinsing, vii) sponge scrubbing. For the hydrophilic PES membrane, the cake layer removal efficiencies ranged from 64% to 10%, indicating that the removal of cake layer was highly dependent on the cleaning options. For the hydrophobic PVDF membrane, the cake layer removal efficiencies ranged from 79% to 97%. Consequently, a standardized method for cake layer removal to determine cake resistance ($R_c$) is needed for correct interpretation of the fouling phenomena.

• 공업화학
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• 제25권4호
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• pp.401-408
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• 2014

분리막 생물반응기에서 산기량 제어는 반응기 내 유체흐름과 특히 막표면 근방에서의 전단응력을 변화시켜 막오염 감소 및 에너지 절약을 구현하는 중요 독립변수 중 하나이다. 본 연구에서는 원통형 생물 반응기 중심에 침지형 평막을 장착하고 하부에서 공기가 공급되는 3차원적 시스템에 대하여 "COMSOL"프로그램을 사용하여 수치해석하였다. 용액의 점도, 온도는 일정하다고 가정했으며 투과액 부피와 산기량의 비인 $SAD_p$를 변수로 사용하였다. 유속센서, 동영상 이미지분석으로 측정한 유속과 수치해석 결과는 11% 이내에서 일치함을 확인하였다. 반응기 내 유체의 흐름은 산기관과 막모듈 구간에서 급격하게 증가하였으나 막모듈을 지나면서 감소하였으며 반응조 벽에서 중심축 방향으로 갈수록 유속이 증가하는 경향을 보였다. 막 표면에서 계산된 전단응력은 하단 중앙부가 가장 크게 나타났으며 산기량이 증가할수록 전단응력이 증가하였다. 특히 산기량을 0.15에서 0.25 L/min로 증가할 경우 크게 증가함을 확인할 수 있었다.

• 한국환경과학회지
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• 제24권11호
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• pp.1485-1491
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• 2015

There are two treatment processes that are currently applied to ships are the biological treatment process using the activated sludge and the electrochemical treatment. However, neither of them are able to remove both nitrogen and phosphorus due to their limited ability to remove organic matters, which are main causes of the red tide. This study was conducted to identify the characteristics of nitrogen removal factors from manure wastewater by replacing the final settling tank in SBR (Sequencing Batch Reactor) process and applying immersion type hollow fiber membrane. SBR process is known to have an advantage of the least land requirement in special environment such as in ship and the immersion type hollow fiber membrane is more stable in water quality change. As the result, the average in the cases of DO (Dissolved Oxygen) is 2.9(0. 6~3.9) mg/L which was determined to be the denitrifying microorganism activity in anaerobic conditions. The average in the cases of ORP (Oxidation Reduction Potential) is 98.4~237.3 mV which was determined to be the termination of nitrification since the inflection point was formed on the ORP curve due to decrease in the stirring treatment after the aeration, same as in the cases of DO. Little or no variation in the pH was determined to have positive effect on the nitrification. T-N (Total Nitrigen) removal efficiencies of the finally treated water were 71.4%, 72.3% and 66.5% in relatively average figures, thus was not a distinct prominence. In being applied in ships in the future, the operating conditions and structure improvements are deemed necessary since the MEPC (Marine Environment Protection Committee). 227(64) ship sewage nitrogen is less than the standard of 20 Qi/Qe mg/L or the removal rate of 70%.

• 한국염색가공학회지
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• 제30권1호
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• pp.51-61
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• 2018

In this study, effluent water was produced through Submerged Membrane Bio-Reactor(SMBR) process, which is a simple system and decomposes organic matter contained in wastewater with biological treatment process and performs solid-liquid separation, Especially, ozone oxidation treatment process is applied to effluent water containing fluorescent whitening agent, which is a trace pollutant which is not removed by biological treatment, and influences the quality of reused water. The concentration of $COD_{Cr}$ in the SMBR was $449.3mg/{\ell}-COD_{Cr}$, and the concentration of permeate water was $100.3mg/{\ell}-COD_{Cr}$. The removal efficiency was about 70.1%. The amount of ozone required for the removal of the fluorescent whitening agent in the permeated water in SMBR was $6.67g-O_3/min$, and the amount of ozone required to remove $COD_{Mn}$ relative to the permeate water was calculated to remove $0.997mg-COD_{Mn}$ for 1mg of $O_3$.

• 한국물환경학회지
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• 제22권2호
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• pp.358-363
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• 2006

KSMBR process is dynamic state advanced wastewater treatment applied with Trisectional Aeration (TSA) mode combined with membrane. TSA was remodeled conventional intermittent aeration which was operated nonaeration-aeration. TSA operates nonaeration ($N_1$) - aeration (A) - nonaeration ($N_2$) in Trisectional Aeration Reactor (TAR). Organics of influent could be nearly consumed to denitrification without influence by remained DO in TAR and it could be operated about sludge return ratio of 1Q (influent base). The purpose of this study was to apply KSMBR to the full-scale plant and to evaluate efficiency of nitrogen and phosphorus removal and TSA operation. The result of this study, average CODcr/T-N and CODcr/T-P ratio were 7.8 and 59.6, respectively. BOD, TCODcr, SS, T-N, T-P, E-coli removal efficiency were 98.4, 95.2, 73.0, 69.6, 99.95 %, respectively. KSMBR obtained high removal efficiencies of C, N and P when it applied full-scale plant.

• 한국염색가공학회지
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• 제29권1호
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• pp.11-17
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• 2017

In this study, ozone oxidation experiment was carried out for the removal of fluorescent whitening agent which is widely used in textile dyeing and paper industry. The stilbene fluorescent whitening agent has been industrialized since the earliest, and the amount of current production is the highest. Due to the characteristics of the fluorescent whitening agent that can not be removed by conventional wastewater treatment methods, the fluorescent whitening agent in wastewater treatment has difficulty in using as recycled water in the process. Pre-treatment ozone oxidation experiment was conducted prior to the introduction of Membrane Bio Reactor(MBR) treatment process by converting biodegradable materials into biodegradable materials. The removal efficiencies of fluorescent whitening agents, a diaminostilbenedisulfonic acid derivative by ozone oxidation were evaluated by $UV_{254}$ Scan, $COD_{Mn}$, T-N and color using a synthetic wastewater sample ($COD_{Mn}=433.0mg/{\ell}$) and paper and paper mill wastewater ($COD_{Mn}=157.2mg/{\ell}$).