• Applied Chemistry for Engineering
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• v.22 no.1
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• pp.37-44
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• 2011

The critical micelle concentration (CMC) of sorbitan laurate SP 20 surfactant in this paper was near $7.216{\times}10^{-4}mol/L$ and the surface tension at CMC was about 26.0 mN/m, which showed higher CMC and lower surface tension than those of octylphenol ethoxylate octylphenol ethoxylate (OPE) 10 surfactant. Dynamic surface tension measurement using a maximum bubble pressure tensiometer showed that the adsorption rate at the interface between air and surfactant solution was found to be slower with SP 20 surfactant, presumably due to a low mobility of SP 20 surfactant monomer. The contact angle of SP 20 surfactant solution was observed to decrease with an increase in surfactant concentration and showed a larger value than that of OPE 10 surfactant solution. Half-life time for foams generated with 1 wt% surfactant solution was also larger with SP 20 surfactant, which indicated higher foam stability with SP 20 surfactant. Dynamic behavior study reveals that the solubilization of n-decane oil was much lower with SP 20, which is in good agreement with experimental results of foam stability, contact angle and CMC. Dynamic interfacial tension measurement by a spinning drop tensiometer shows that interfacial tensions at equilibrium condition in both systems were almost the same but the time required to reach equilibrium was longer with SP 20.

• Applied Chemistry for Engineering
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• v.22 no.4
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• pp.376-383
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• 2011

The CMCs of LA and LA3 nonionic surfactants obtained from the reaction between glycidol and lauryl alcohol were found to be $0.97{\times}10^{-3}mol/L$ and $1.02{\times}10^{-3}mol/L$ respectively and the surface tensions for 1 wt% surfactant were 26.99 and 27.48 mN/m respectively. Dynamic surface tension measurements using a maximum bubble pressure tensiometer showed that the adsorption rate of surfactant molecules at the interface between the air and the surfactant solution was found to be relatively fast in both surfactant systems, presumably due to the high mobility of surfactant molecules. The contact angles of LA and LA3 nonionic surfactants were 27.8 and $20.9^{\circ}$ respectively and the dynamic interfacial tension measurement by a spinning drop tensiometer showed that interfacial tensions at equilibrium condition in both systems were almost the same. Also both surfactant systems reached equilibrium in 2~3 min. Both surfactant solutions showed high stability when evaluated by conductometric method and the LA nonionic surfactant system provided the higher foam stability than the LA3 nonionic surfactant system. The phase behavior experiments showed a lower phase or oil in water (O/W) microemulsion in equilibrium with an excess oil phase at all temperatures studied. No three-phase region was observed including a middle-phase microemulsion or a lamellar liquid crystalline phase.

• Journal of the Korean Geosynthetics Society
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• v.20 no.1
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• pp.1-8
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• 2021

In urban areas, structures are installed deep underground in the lower part of the structure to utilize space. Therefore, a retaining wall is used to prevent earth pressure from the ground when constructing a structure. Due to the development of construction technology, retaining wall applied to excavation work are used to prevent danger such as falling rocks and landslides in temporary facilities when construction or retaining walls are installed. In general, the application of a retaining wall to a temporary facility during the embankment construction is the case of expanding an existing roads or railways. Therefore, it is necessary to study the retaining wall applied to the embankment construction such as the double-track site of the high-speed railway. In this study, two types of common one row H-pile retaining wall and two types of IER retaining wall were analyzed, and the stability of the retaining wall applied to the construction of double-track of the high-speed railway was analyzed. The earth retaining wall is a construction method that combines forced pile applied to the stabilization of the slope with the wall of the earth retaining wall. As a result of the analysis, the IER retaining wall had maximum lateral displacement of 19.0% compared to the type with H-plie installed only in the front while dynamic load was applied. In addition, the slower the speed of high-speed railway, the more displacement occurred, and the results show that more caution is needed when designing the ground in low-speed sections.

• Journal of the Korean earth science society
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• v.43 no.1
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• pp.23-29
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• 2022

Although tropical cyclones with wind speeds weaker than 17 ms^-1 (weak tropical cyclones: WTCs) can cause significant damage, particularly over the Seoul metropolitan area, only a few studies have focused on WTC activity over South Korea. In this study, we found that WTC activity is likely associated with the Pacific Decadal Oscillation (PDO). During the negative phases of the PDO, landfall frequency of WTCs increased significantly compared to the positive phases at 95% confidence level. When related to the negative phases of the PDO, a positive relative vorticity anomaly is found in the northern sector of the western North Pacific while a negative relative vorticity anomaly and enhanced vertical wind shear prevail in the southern sector of the WNP. These factors are favorable for the northward shift of the genesis location of tropical cyclones on average, thereby reducing the total lifetime of WTCs. Moreover, a high-pressure anomaly over the Japanese islands would shift a tropical cyclone track westward in addition to the landfall location. Consequently, the effects of the topographical friction and the Yellow Sea Bottom Cold Water on a tropical cyclone may increase. These conditions could result in a weaker lifetime maximum intensity and landfall intensity, ultimately resulting in WTCs becoming more frequent over South Korea during the negative phases of the PDO.

• Journal of the Korean GEO-environmental Society
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• v.23 no.1
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• pp.39-49
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• 2022

Expandable steel pipe piles are installed by inserting expansion equipment to increase the cross-sectional area of steel pipes, which can improve the pile performance compared to micro-piles. In this paper, a hydraulic expansion device was developed to expand steel pipe piles in practice. A series of laboratory and field tests were conducted to verify the performance of the developed expansion device to expand steel pipes. The expansion capability and expandable range was evaluated by measuring the strain and expansion time at the maximum pressure of the hydraulic expansion device. The thinner steel pipe, the larger strain but longer expansion time required in the test. For example, the 4.0-mm-thick steel pipe showed strain reduction by 30% and a decrease in the required expansion time by 40% compared to the 2.9-mm-thick steel pipe. In addition, in-situ expansion tests were performed to verify the expandability of steel pipes under the ground, and the exhumed specimen showed clear expanded sections. The structural integrity was determined by comparing the material performance the original and expanded specimens.

• Journal of Korean Tunnelling and Underground Space Association
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• v.24 no.5
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• pp.355-374
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• 2022

Soil conditioning improves the performance of EPB (earth pressure balance) shield TBMs (tunnel boring machines) by reducing shear strength, enhancing workability of the excavated soil, and supporting the tunnel face during EPB tunnelling. The mechanical and rheological behavior of the excavated muck mixed with additives should be properly evaluated to determine the optimal additive injection condition corresponding to each ground type. In this study, the laboratory pressurized vane test apparatus equipped with a vane-shaped rheometer was developed to reproduce the pressurized condition in the TBM chamber and quantitively evaluate rheological properties of the soil specimens. A series of the pressurized vane tests were performed for an artificial sand soil by changing foam injection ratio (FIR) and polymer injection ratio (PIR), which are the injection parameters of the foam and the polymer, respectively. In addition, the workability of the conditioned soil was evaluated through the slump test. The peak and yield stresses of the conditioned soil with respect to the injection parameters were evaluated through the rheogram, which was derived from the measured torque data in the pressurized vane test. As FIR increased or PIR decreased, the workability of the conditioned soil increased, and the maximum torque, peak stress, and yield stress decreased. The peak stress and yield stress of the specimen from the laboratory pressurized vane test correspond to the workability evaluated by the slump tests, which implies the applicability of the proposed test for evaluating the rheological properties of excavated soil.

• Journal of Korean Tunnelling and Underground Space Association
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• v.24 no.5
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• pp.375-393
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• 2022

This study was deal with blow-out and buoyancy stability evaluation method for slurry shield TBM. When applying a slurry shield TBM for the construction of a shallow tunnel under river or sea, the stability of slurry blow-out and segment lining buoyancy should be evaluated. However, there is a problem in that the currently applied theoretical formula is somewhat complicated, making it inconvenient to calculate in practice. In this study, some simple charts were proposed to easily evaluate the stability of slurry blow-out and segment lining buoyancy. In addition, the buoyancy safety factor of segment lining using the strength reduction method was evaluated and compared with the buoyancy safety factor based on the theoretical formula. The buoyancy safety factor by the theoretical formula was evaluated to be rather small, and it was confirmed that it was on the safe side. The simplified charts for the evaluation of slurry blow-out and buoyancy stability presented in this study are expected to be usefully utilized in the planning and design of undersea tunnels.

• Journal of Dairy Science and Biotechnology
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• v.40 no.3
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• pp.93-102
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• 2022

This study was conducted using response surface methodology (RSM) to elucidate fermentation conditions that will optimize ACE inhibitory activity using Lactiplantibacillus plantarum K79. Four independent variables [skim milk (with 1% added glucose) concentration (6%-14%), incubation temperature (32℃-42℃), incubation time (8-24 h), and amount of added starter (0.02%-0.2%)] were evaluated using five-level central composite design and response surface methodology to determine the optimum fermentation condition. The dependent variables were angiotensin converting enzyme (ACE) inhibitory activity (the value obtained from 102 diluted supernatant), and pH. The respective coefficients of determinations (R²) were 0.791 and 0.905 for ACE inhibitory activity and pH. The maximum ACE inhibitory activity was 90% under the following conditions: 10% skim milk (with 1% added glucose) concentration, 37℃ incubation temperature, 17.8 h incubation time, and 0.2% added starter. Based on the RSM, using predicted best ACE conditions for fermentation of 13.49% skim milk (with 1% added glucose) with 0.0578% starter at 33.4℃ for 21.5 h, the predicted ACE inhibitory activity and pH values were 86.69% and 4.6, respectively. Actual ACE inhibitory activity and pH values were 85.5% and 4.58, respectively

• Korean Chemical Engineering Research
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• v.59 no.2
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• pp.239-246
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• 2021

Characteristics of hydrodynamics and heat absorption by gas in a directly-irradiated fluidized bed particle receiver (50 mm-ID X 150 mm high) of SiC particles have been determined. Solid holdups of SiC particles show almost constant values with increasing gas velocity. Fine SiC particles (SiC II; dp=52 ㎛, ρs=2992 kg/㎥) showed low values of relative standard deviation of pressure drop across bed but high solids holdups in the freeboard region compared to coarse SiC particles (SiC I; dp=123 ㎛, ρs=3015 kg/㎥). The SiC II exhibited higher values of temperature difference normalized by irradiance due to the effect of additional solar heat absorption and heat transfer to the gas by the particles entrained in the freeboard region in addition to the efficient thermal diffusion of the solar heat received at bed surface. Heat absorption rate and efficiency increased with increasing the gas velocity and fluidization number. The SiC II showed maximum heat absorption rate of 17.8 W and thermal efficiency of 14.8%, which are about 33% higher than those of SiC I within the experimental gas velocity range.

• Journal of Korean Tunnelling and Underground Space Association
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• v.23 no.6
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• pp.535-547
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• 2021

A policy to expand the hydrogen economy has been established in Korea and the supply of FCEV is being expanded to realize a hydrogen society. Therefore, the supply of FCEV is expected to increase rapidly, and a solution to respond to accidents of FCEV is required. In this study, an experimental study was conducted to analyze the effect of the hydrogen jet flame generated by a FCEV on the inner wall of the tunnel and the characteristics of the internal radiant heat. For the experiment, the initial pressure of hydrogen tank was set to 700 bar, and the injection nozzle diameter was set to 1.8 mm in order to make the same as the conditions generated in the FCEV. In addition, a tunnel fire resistance test specimen having the same strength as the compressive strength of concrete applied to general tunnels of 40 MPa was manufactured and used in the experiment. The results were analyzed for the separation distance (2 m and 4 m) between the hydrogen release nozzle and the tunnel fire resistance test concrete. As the result, the maximum internal temperature of the test concrete was measured to 1,349.9℃ (2 m separation distance), and the radiant heat around the jet flame was up to 39.16 kW/m².