• 전기화학회지
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• 제6권2호
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• pp.113-118
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• 2003

폴리아닐린 분말과 고분자 계면활성제, cyclohexanone용매를 micro-milling장치내에서 분산시켜 (m입자 크기를 갖는 가공용이한 분산액을 제조하였다. 분산액을 백금 전극 위에 코팅하여 얻은 분산박막의 전기화학적 특성들은 순환전압전류법(CV)을 이용하여 조사하였다. CV의 결과에 의하면 폴리아닐린 분산박막이 순수한 폴리아닐린 박막과 유사한 전기화학적 특성을 갖는 것으로 나타났다. $3wt.\%$ NaCl용액에서 수행한 분극실험과 열린회로전위 측정 실험에서는 PANI분산액을 철표면에 코팅하면 부식전위가 증가하였다. 분산박막/철 전극의 열린회로전위값(OCP, Voc)이 분산액의 제조 조건에 따라 변화가 있음을 관찰하였다. 이러한 결과들은 본 연구에서 사용한 전도성 고분자 분산액이 철의 부식방지코팅물질로서 유용성을 갖고 있다는 것을 보여주고 있다.

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2007년도 추계학술대회 논문집
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• pp.17-18
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• 2007

Solid oxide fuel cells are clean, pollution-free technology for the electrochemical generation of electricity at high efficiency. Specially, the polarization resistance between electrolyte and electrode of SOFC unit cell is of importance, because it is desirable to develop SOFC operating at intermediate temperature below $800^{\circ}C$. The LSCF cathode prepared using modified oxalate method was investigated with different electrolyte. A precursor was prepared with oxalic acid, ethanol and $NH_4OH$ solution. The LSCF precursor was prepared at $80^{\circ}C$, and pH control was 2, 6, 8, 9 and 10. The precursor powder was calcined at $800^{\circ}C$, $1000^{\circ}C$ and $1200^{\circ}C$ for 4hrs. The crystal of LSCF powders show single phase at pH 2, 6, 8 and 9, and the average particle size was about $3{\mu}m$. The LSCF cathode with heat treatment at $1200^{\circ}C$ showed a plot of electric conductivity versus temperature. Unit cell prepared from the LSCF cathode, buffer layer between cathode and electrolyte and the LSGM, YSZ, ScSZ and CeSZ electrolyte. Also interface reaction between LSCF, buffer layer and electrolyte were measured by EPMA and the polarization resistance for unit cell with cycle measure using a Solatron 1260 analyzer.

• Journal of Advanced Marine Engineering and Technology
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• 제24권6호
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• pp.70-77
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• 2000

In this paper, the effect of solution and age heat treatment to the corrosion behavior for the Ti-6Al-4V alloy were studied by cyclic polarization methods. Ti-6Al-4V was solution heat treated at $1,066^{\circ}C$ and $966^{\circ}C$ for 5 hours, and followed by age heat treated at $650^{\circ}C$, $600^{\circ}C$ and $550^{\circ}C$ with 1, 2, 4, 8 and 16 hours under vacuum environment. Test solution was 3.5% NaCl with temperature $25^{\circ}C$. The obtained results were as follows: 1. Base metal was exhibited higher electrical charge than that of solution and aged material. With decrease of solution-treatment temperature from 1066 to $966^{\circ}C$, the electrical charge was increased due to softening of micro structure. 2. The corrosion resistance of specimen that solution treated at $966^{\circ}C$ for 5 hours and age heat treated at 650, 660 and $550^{\circ}C$ were increased with increase of aging time to 4, 8 and 16 hours respectively, and then decreased. 3. In case of 316L stainless steel, measured charge and corrosion potential was 0.0627 coulomb and -614 mV respectively. Corrosion resistance of Ti-6Al-4V was higher than that of 316L.

• Transactions on Electrical and Electronic Materials
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• 제3권1호
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• pp.14-17
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• 2002

The effects of substrate temperatures and annealing temperatures on the microstructures and ferroelectric properties of PbZ $r_{0.52}$ $Ti_{0.48}$ $O_3$(PZT) thin fims prepared by pulsed laser deposition (PLD) were investigated. For this purpose, the PZT films were deposited at various substrate temperatures (400~$600^{\circ}C$) with post annealing process in oxygen atmosphere. The single perovskite phase was formed at the deposition temperature of 500 to 55$0^{\circ}C$ without post annealing and the PZT films deposited below 50$0^{\circ}C$ formed the single phase with post annealing at $650^{\circ}C$. The grain size of the films increased and the grain boundary of the films was clearly defined as the substrate temperature increased from 400 to 55$0^{\circ}C$. The remnant polarization (Pr) and the coercive field (Ec) of the films deposited at 55$0^{\circ}C$ and annealed at $650^{\circ}C$ were 34.3 $\mu$C/c $m^2$and 60.2 kV/cm, respectively.y.y.

• 한국표면공학회지
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• 제44권3호
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• pp.82-88
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• 2011

A uniform chromium-free conversion coating treated with an alkaline phosphate- permanganate solution was formed on the AZ 31 magnesium alloy. The effect of acid pickling on the morphology and on the corrosion resistance of the alkaline phosphate-permanganate conversion coating was investigated. The chemical composition and phase structure of conversion coating layer were determined via optical microscopy, SEM, EDS, XPS and XRD. Results show that the conversion coatings are relatively uniform and continuous, with thickness 1.8 to $2.4\;{\mu}m$. The alkaline phosphate-permanganate conversion coating was mainly composed of elements Mg, O, P, Al and Mn. The conversion-coated layers were stable compounds of magnesium oxide and spinel ($MgAl_2O_4$). These compounds were excellent inhibitors to corrosion. The electrochemical corrosion behaviors of coatings in 3.5 wt.% NaCl solutions were evaluated by electrochemical impedance spectroscopy, potentiodynamic polarization technique. EIS results showed a polarization resistance of $0.1\;k{\Omega}$ for the untreated Mg and $16\;k{\Omega}$ for the alkaline phosphate-permanganate conversion treatment sample, giving an improvement of about 160 times. The results of the electrochemical measurements demonstrated that the corrosion resistance of the AZ 31 magnesium alloy was improved by the alkaline phosphate-permanganate conversion treatment.

• 한국표면공학회지
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• 제54권5호
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• pp.238-247
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• 2021

PEO (plasma electrolytic oxidation) was applied to modify the surface of AZ31 magnesium alloy in this study. The mixed solution of sodium hydroxide (NaOH) and sodium silicate (Na₂SiO₃) was used as the electrolyte, and 0 - 0.05 g/L of Ca-GP (Glycerol Phosphate Calcium salt) was added in the electrolyte as an additive. PEO treatment was conducted at a current density of 30mA/cm² for 5 minutes using a DC power supply. The surface properties were identified by SEM, XRD and surface roughness analyses, and the corrosion resistance was evaluated by potentiodynamic polarization and immersion tests. In addition, the biocompatibility was evaluated by immersion test in SBF solution. As the concentration of Ca-GP was increased, the surface morphology was denser and more uniform, and the amount of Ca and the thickness of oxide layer increased. Only Mg peak was observed in XRD analysis due to very thin oxide layer. The corrosion resistance of PEO-treated samples increased with the concentration of Ca-GP in comparision with the untreated sample. In particular, the highest corrosion resistance was identified at the group of 0.04g Ca-GP through potentiodynamic polarization and immersion tests in saline solution (0.9 wt.%NaCl). During the immersion in saline solution, pH rapidly increased at the beginning of immersion period due to rapid corrosion, and then increase rate of pH decreased. However, the pH value in the SBF temporarily increased from 7.4 to 8.5 during the day, then decreased due to the inhibition of corrosion with HA(hydroxyapatite) formation.

• 천문학회보
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• 제40권1호
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• pp.66.1-66.1
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• 2015

We present the first observational detection of radial and azimuthal oscillations in full halo coronal mass ejections (HCMEs). We analyze nine HCMEs well-observed by LASCO from Feb 2011 to Jun 2011. Using the LASCO C3 running difference images, we estimated the instantaneous apparent speeds of the HCMEs in different radial directions from the solar disk center. We find that the development of all these HCMEs is accompanied with quasi-periodic variations of the instantaneous radial velocity with the periods ranging from 24 to 48 mins. The amplitudes of the instant speed variations reach about a half of the projected speeds. The amplitudes are found to anti-correlate with the periods and correlate with the HCME speed, indicating the nonlinear nature of the process. The oscillations have a clear azimuthal structure in the heliocentric polar coordinate system. The oscillations in seven events are found to be associated with distinct azimuthal wave modes with the azimuthal wave number m=1 for six events and m=2 for one event. The polarization of the oscillations in these seven HCMEs is broadly consistent with those of their position angles with the mean difference of $42.5^{\circ}$. The oscillations may be connected with natural oscillations of the plasmoids around a dynamical equilibrium, or self-oscillatory processes, e.g. the periodic shedding of Alfvenic vortices. Our results indicate the need for advanced theory of oscillatory processes in CMEs.

• 한국광학회지
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• 제6권2호
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• pp.142-147
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• 1995

광섬유 loop mirror를 사용하여 수동형 모우드 록킹된 '8'자 고리형 erbium 첨가 광섬유 레이저로부터 솔리톤 광펄스 출력을 얻었다. 광섬유 loop mirror는 loop내의 한쪽 끝에 erbium 첨가 광섬유를 포함하는 증폭형 loop mirror 형태로 구성되었으며 비선형 매질로서 길이 504m의 분산천이 광섬유가 사용되었다. 파장 $1.48{\mu}m$의 반도체레이저로 펌핑하고 공진기내 편광조절기를 조절함으로써 공진기 일주시간에 해당하는 기본주기로 반복되는 솔리톤 펄스군을 얻을 수 있었다. 솔리톤 펄스군은 중심파장 1574nm, 파장폭 1.2nm로 나타났으며 기본주기내에서 임의 시간간격의 펄스패턴을 가지고 있었다. 자기상관계를 이용하여 2.4ps의 펄스 폭을 측정하였는데 이는 이론에 의한 예측치와 거의 일치하는 값이다. 또한 펄스폭과 주파수 대역폭의 곱이 0.348로서 transform limit에 가까운 펄스임을 알 수 있었다.

• 한국재료학회지
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• 제22권7호
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• pp.342-345
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• 2012

The dielectric properties and phase transformation of poled <001>-oriented $Pb(Mg_{1/3}Nb_{2/3})O_3-x%PbTiO_3$(PMN-x%PT) single crystals with compositions of x = 20, 30, and 35 mole% are investigated for orientations both parallel and perpendicular to the [001] poling direction. An electric-field-induced monoclinic phase was observed for the initial poled PMN-30PT and PMN-35PT samples by means of high-resolution synchrotron x-ray diffraction. The monoclinic phase appears from $-25^{\circ}C$ to $100^{\circ}C$ and from $-25^{\circ}C$ to $80^{\circ}C$ for the PMN-30PT and PMN-35PT samples, respectively. The dielectric constant (${\varepsilon}$)-temperature (T) characteristics above the Curie temperature were found to be described by the equation$(1/{\varepsilon}-1/{\varepsilon}_m)^{1/n}=(T-T_m)/C$, where ${\varepsilon}_m$ is the maximum dielectric constant and $T_m$ is the temperature giving ${\varepsilon}_m$, and n and C are constants that change with the composition. The value of n was found to be 1.82 and 1.38 for 20PT and 35PT, respectively. The results of mesh scans and the temperature-dependence of the dielectric constant demonstrate that the initial monoclinic phase changes to a single domain tetragonal phase and a to paraelectric cubic phase. In the ferroelectric tetragonal phase with a single domain state, the dielectric constant measured perpendicular to the poling direction was dramatically higher than that measured in the parallel direction. A large dielectric constant implies easier polarization rotation away from the polar axis. This enhancement is believed to be related to dielectric softening close to the morphotropic phase boundary.

• The Korean Journal of Ceramics
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• 제6권3호
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• pp.291-295
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• 2000

The pyroelectric property of $Pb_{0.9}La$_{0.1}TiO_3$ceramics in a range of 1.3-4.1$\mu\textrm{m}$, fabricated by conventional solid sintering, was investigated as a function of poling field. The pyroelectric of the 4.1$\mu\textrm{m}$ of $Pb_{0.9}La$_{0.1}TiO_3$ceramics is higher than that of the 1.3$\mu\textrm{m}$ and 1.7$\mu\textrm{m}$ of $Pb_{0.9}La$_{0.1}TiO_3$ceramics at a low poling field and the pyroelectric coefficient is 25nC/$\textrm{cm}^2$K at a 4kV/mm poling field in every grain size. In order to explain this phenomenon, the intrinsic and extrinsic effects in view of the definition of the pyroelectric coefficient are introduced. The intrinsic and extrinsic effects on the pyroelectric property were investigated by measuring the tetragonal ratio and the $I_{002}$ with temperature with high temperature X-ray diffractometer. The change of spontaneous polarization and the $90^{\circ}$domain wall motion with temperature in the 1.3$\mu\textrm{m}$ and 4.2$\mu\textrm{m}$ of $Pb_{0.9}La$_{0.1}TiO_3$ceramics have no effects on the pyroelectric coefficient. In our study, it can be seen that the pyroelectric coefficient is related to the quantity of $180^{\circ}$domain switching after poling treatment.