• Title/Summary/Keyword: M2 polarization

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Experimental Validation of a Direct Methanol Fuel Cells(DMFCs) model with a Operating Temperatures and Methanol Feed Concentrations (직접메탄올 연료전지의 농도 및 온도변화에 따른 실험적 검증)

  • Kang, Kyungmun;Ko, Johan;Lee, Giyong;Ju, Hyunchul
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.06a
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    • pp.125.2-125.2
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    • 2010
  • In this paper, both theoretical and experimental investigations have been performed to examine the effects of key operating parameters on the cell performance of a DMFCs (i.e., methanol feed concentration and operating temperature). For experiment, the membrane electrode assemblies (MEAs) were prepared using a conventional MEA fabrication method based on a catalyst coated electrode (CCE) and tested under various cell temperatures and methanol feed concentrations. The polarization curve measurements were conducted using in-house-made $25cm^2$ MEAs. The voltage-current density data were collected under three different cell temperatures ($50^{\circ}C$, $60^{\circ}C$, and $70^{\circ}C$) and four different methanol feed concentrations (1 M, 2 M, 3 M, and 4 M). The experimental data indicate that the measured I-V curves are significantly altered, depending on these conditions. On the other hand, previously developed one-dimensional, two-phase DMFC model is simulated under the same operating conditions used in the experiments. The model predictions compare well with the experimental data over a wide range of these operating conditions, which demonstrates the validity and accuracy of the present DMFC model. Furthermore, both simulation and experimental results exhibit the strong influences of methanol and water crossover rates through the membrane on DMFC performance and I-V curve characteristics.

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Investigation on Electrolytic Corrosion Characteristics with the Variation of Current Density of 5083-H321 Aluminum Alloy in Seawater (5083-H321 알루미늄 합금의 해수 내 전류밀도의 변화에 따른 전식 특성 연구)

  • Kim, Young-Bok;Kim, Seong-Jong
    • Journal of the Korean institute of surface engineering
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    • v.52 no.1
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    • pp.23-29
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    • 2019
  • Electrolytic corrosion of the ship's hull can be occurred due to stray current during welding work using shore power and electrical leakage using shore power supply. The electrolytic corrosion characteristics were investigated for Al5083-H321 through potentiodynamic polarization and galvanostatic corrosion test in natural seawater. Experiments of electrolytic corrosion were tested at various current densities ranging from $0.01mA/cm^2$ to $10mA/cm^2$ for 30 minutes, and at various applied time ranging from 60 to 240 minutes. Evaluation of electrolytic corrosion was carried out by Tafel extrapolation, weight loss, surface analysis after the experiment. In the electrolytic corrosion characteristics of Al5083-H321 as the current density increased, the surface damage tended to proportionally increase. In the current density of $0.01mA/cm^2$ for a applied long time, the damage tended to grow on the surface. In the case of $10mA/cm^2$ current density for a applied long time, the damage progressed to the depth direction of the surface, and the amount of weight loss per hour increased to 4 mg/hr.

Detection of Artificial Displacement of a Reflector by using GB-SAR Interferometry and Atmospheric Humidity Correction (GB-SAR 간섭기법을 이용한 반사체의 인위적 변위탐지 및 대기습도보정)

  • Lee, Jae-Hee;Lee, Hoon-Yol;Cho, Seong-Jun;Sung, Nak-Hun;Kim, Jung-Ho
    • Korean Journal of Remote Sensing
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    • v.26 no.2
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    • pp.123-131
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    • 2010
  • In this paper we applied Ground-Based Synthetic Aperture Radar(GB-SAR) interferometry to detect artificial displacement of a reflector and performed an atmospheric humidity correction to improve the accuracy. A series of GB-SAR images were obtained using a center frequency of 5.3 GHz with a range resolution of 25 cm and a azimuth resolution of $0.324^{\circ}$, all in full-polarization (HH, VV, VH, HV) modes. A triangular trihedral corner reflector was located 160 m away from the system, and the artificial displacements of 0-40 mm was implemented during the GB-SAR image acquisition. The result showed that the RMS error between the actual and measured displacements, averaged in all polarization data, was 1.22 mm, while the maximum error in case of the 40 mm displacement was 2.72 mm at HH-polarization. After the atmospheric correction with respect to the humidity, the RMS error was reduced to 0.52 mm. We conclude that a GB-SAR system can be used to monitor the possible displacement of artificial/natural scatterers and the stability assessment with sub-millimeter accuracy.

The Effect of Air Impurities on the PEMFC Performances (공기에 포함된 불순물에 의한 PEMFC 운전 성능 변화)

  • Jang, Jong-Hyun;Kim, Yi-Young;Han, Jong-Hee;Lee, Sang-Yeop;Cho, Eun-Ae;Kim, Hyoung-Juhn;Lim, Tae-Hoon
    • 한국신재생에너지학회:학술대회논문집
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    • 2008.05a
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    • pp.526-529
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    • 2008
  • The effect of air impurities on PEMFC performances were studied using electrochemical analysis, such as OCV monitoring, polarization, constant current operation, and electrochemical impedance spectroscopy. The nitrogen dioxide in air lowered the operation voltage at 1 A/$cm^2$ by 160 mV (10 ppm) and 227 mV (100 ppm), while the carbon monoxide effect was relatively not significant (30 mV at 100 ppm). For both nitrogen dioxide and carbon monoxide, the performances were largely recovered when pure air was provided again. Further study for additional air impurities and simulated air are under progress to provide fundamental data for the design of fuel cell vehicles.

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Study on Angular Rate Sensor using Sol-Gel PZT thin film (Sol-gel 압전체 박막을 이용한 각속도 센서에 대한 연구)

  • Lee, S. H.;R. Meada;M. Esashi
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2003.03a
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    • pp.34-34
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    • 2003
  • Piezoelectric or magnetostrictive materials, known as smart materials, have been researched widely for sensors or actuators in micro system technology. In our research, thick sol-gel lead zirconate titanate(Pb(Zr$\sub$1-x/Ti$\sub$x/)O$_3$) films were fabricated and their characteristics were investigated f3r angular rate sensor applications. The thickness of the PZT films is 1.5${\mu}$m, which is required by a vibration angular rate sensor for a good actuation and sensing. The remnant polarization of the PZT flms is 12.0 ${\mu}$C/$\textrm{cm}^2$. The electromechanical constants of PZT thin film showed the value of susceptance(B) of 4800${\mu}$ s at capacitance of 790pF. The PZT films were applied to the vibration angular rate sensor structure and the vibration of 1.78 ${\mu}$m in amplitude at the resonant frequency of 35.8㎑ was obtained by driving voltage of 5V$\sub$p-p/ of bulk piezoelectric materials with out of phase signal through voltage and inverting amplifier.

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The Synergistic Effect of 2-Chloromethylbenzimidazole and Potassium Iodide on the Corrosion behavior of Mild Steel in Hydrochloric Acid Solution

  • Zhou, Liben;Cheng, Weizhong;Wang, Deng;Li, Zhaolei;Zhou, Haijun;Guo, Weijie
    • Journal of Electrochemical Science and Technology
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    • v.13 no.1
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    • pp.138-147
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    • 2022
  • The synergistic effect of 2-chloromethylbenzimidazole (2-CBI) and potassium iodide (KI) for mild steel in 1 M hydrochloric acid solution was investigated by potentiodynamic polarization curves and electrochemical impedance spectroscopy (EIS). The results showed that, with the addition of 100 ppm potassium iodide, the inhibition efficiecy (IE) of 100 ppm 2-CBI in 1 M hydrochloric acid had been improved from 91.14% to 96.15%. And synergistic parameter of 100 ppm 2-CBI with different amounts of potassium iodide is always greater than 1. The adsorption of potassium iodide combining with 100 ppm 2-CBI obeys to the Langmuir adsorption isotherm. Thermodynamic adsorption parameters, including ∆G0ads, ∆Ha and ∆Sa of the adsorption of the combinned inhibitor, as well as the Ea of the mild steel corrosion in 1 M HCl with the combinned inhibitor, were calculated.

Choline chloride-Glycerol (1:2 mol) as draw solution in forward osmosis for dewatering purpose

  • Dutta, Supritam;Dave, Pragnesh;Nath, Kaushik
    • Membrane and Water Treatment
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    • v.13 no.2
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    • pp.63-72
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    • 2022
  • Choline chloride-glycerol (1:2 mol), a natural deep eutectic solvent (NADES) is examined as a draw solution in forward osmosis (FO) for dewatering application. The NADES is easy to prepare, low in toxicity and environmentally benign. A polyamide thin film composite membrane was used. Characterization of the membrane confirmed porous membrane structure with good hydrophilicity and a low structural parameter (722 ㎛) suitable for FO application. A dilute solution of 20% (v/v) NADES was enough to generate moderate water flux (14.98 L m-2h-1) with relatively low reverse solute flux (0.125 g m-2h-1) with deionized water feed. Application in dewatering industrial wastewater feed showed reasonably good water flux (11.9 L m-2h-1) which could be maintained by controlling the external concentration polarization and fouling/scaling mitigation via simple periodic deionized water wash. In another application, clarified sugarcane juice could be successfully concentrated. Recovery of the draw solute was accomplished easily by chilling utilizing thermo responsive phase transition property of NADES. This study established that low concentration NADES can be a viable alternative as a draw solute for dewatering of wastewater and other heat sensitive applications along with a simple recovery process.

Endotoxins of Enteric Pathogens Are Chemotactic Factors for Human Neutrophils

  • Islam, Laila N.;Nabi, A.H.M. Nurun;Ahmed, K. Mokim;Sultana, Novera
    • BMB Reports
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    • v.35 no.5
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    • pp.482-487
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    • 2002
  • Early activation of human peripheral blood polymorphonuclear neutrophils is characterized by their morphological changes from spherical to polarized shapes. The endotoxins from enteric pathogens (S. dysenteriae type 1, V. cholerae Inaba 569B, S. typhimurium, and K. pneumoniae) were assessed by their ability to induce morphological polarization of the neutrophils as measures of early activation. Phagocytic activity, adhesion, chemokinetic locomotion, and nitroblue tetrazolium (NBT) dye-reduction ability measured the later activation of the cells. Neutrophils showed distinct morphological polarization in suspension over a wide range of concentrations of these endotoxins when were compared with those that were induced by the standard chemotactic factor, N-formyl-L-methionyl-L-leucyl-L-phenylalanine (FMLP). It was discovered that all of the endotoxins induced locomotor responses in neutrophils in suspension that were dose- and time-dependent. The optimum concentration for the endotoxins of S. dysenteriae, V. cholerae, and K. pneumoniae was 1 mg/ml in which 71, 69, and 66% of the neutrophils were polarized. However, the S. typhimurium dose was 2 mg/ml in which 50% of the cells responded. Neutrophils that were stimulated with endotoxins also showed increased random locomotion (p<0.005) through cellulose nitrate filters, but an enhanced adhesion of the cells to glass surfaces (p<0.03). These are important functions of these cells to reach and phagocytose damaged cells, as well as invading microorganisms. Interestingly, the endotoxins had a highly-significant inhibitory effect upon the proportions of neutrophils phagocytosing opsonized yeast (p<0.01) with a small number of yeast that were engulfed by the cells (p<0.02). Further, endotoxin-treated cells showed an enhanced ability to reduce NBT dye (p<0.03). Therefore, we concluded that endotoxins of enteric pathogens are neutrophil chemotactic factors.

Analysis of Land Subsidence and Microwave Penetration on Drying Mudflat by using a Polarimetric Scatterometer Experiment (다편광 산란계 실험을 통한 개펄 건조시의 지반 침하와 마이크로파 침투 분석)

  • Lee Hoon-Yol;Chae Hee-Sam;Cho Seong-Jun
    • Proceedings of the KSRS Conference
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    • 2006.03a
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    • pp.145-148
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    • 2006
  • 새로 조성된 간척지 갯벌이 건조 수축하면 지반 침하와 더불어 토양 내로의 마이크로파의 침투 깊이가 증가한다 따라서 인공위성 DInSAR를 이용하여 지반 침하량을 구하고자 할 때, 건조 시 동시에 발생하는 마이크로파의 개펄 침투 현상을 규명하여 보정해 주어야 한다. 이를 위하여 다편광 산란계(Polarimetric Scatterometer)를 구성하여 건조 개펄에 대한 실내실험을 실시하였다. PolScat의 구성은 5.0-5.6GHz 대역의 dual-polarization square horn antenna를 사용하였으며 Agilent 8753ES 벡터 네트워크 분석기를 사용하였다. 길이 2m, 폭 2m, 높이 20cm의 개펄 샘플을 약 6주 동안 실내에서 건조시켜 위상을 측정한 결과 지반 침하와 함께 약 4mm의 마이크로파 투과현상이 발견되었다. 따라서 인공위성 DInSAR 지반침하량 계산에 있어서 반드시 토양 수분에 따른 마이크로파의 토양 침투 깊이를 보정해 주어야 함이 밝혀졌다.

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Characteristics of Sequentially-Rotated Array Antenna by Varying Sequential Array Parameter (배열 정수 변화에 의한 순차 회전 배열 안테나의 특성)

  • Han, Jeong-Se;Lee, Hyun-Sung;Seo, Dong-Kug;Park, Byoung-Woo
    • The Journal of the Korea Contents Association
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    • v.7 no.11
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    • pp.76-83
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    • 2007
  • In the sequentially rotated array antennas, the characteristics of antenna gain, axial ratio and cross polarization have been analyzed with a varying of sequential array constant(number of array element, figure of rotation) respectively. Where the antenna element of array is a probe feeding, LHCP truncated microstrip antenna whose resonant frequency is in 11.85GHz. The simulation results of 23 SRA antennas((M=2, 3, 4, 6, 8), $(1\leqP\leqM)$) has shown as follows. The widest 3dB bandwidth of axial ratio appears at P=2 which is in-dependant of M, the highest antenna gain appears when a sequential array constant has a pair of (2, 1), (3, 2), (4, 1), (6, 3), (8, 1) respectively. Specially, all of the SRA antenna appear very poor characteristics in case of M=P. Therefore the SRA antenna has to be designed as selecting a optimal sequential array constant among a lot of simulation data.