Browse > Article
http://dx.doi.org/10.33961/jecst.2021.00682

The Synergistic Effect of 2-Chloromethylbenzimidazole and Potassium Iodide on the Corrosion behavior of Mild Steel in Hydrochloric Acid Solution  

Zhou, Liben (School of Materials Science and Engineering, Jiangsu University of Science and Technology)
Cheng, Weizhong (School of Materials Science and Engineering, Jiangsu University of Science and Technology)
Wang, Deng (School of Materials Science and Engineering, Jiangsu University of Science and Technology)
Li, Zhaolei (School of Materials Science and Engineering, Jiangsu University of Science and Technology)
Zhou, Haijun (School of Materials Science and Engineering, Jiangsu University of Science and Technology)
Guo, Weijie (School of Materials Science and Engineering, Jiangsu University of Science and Technology)
Publication Information
Journal of Electrochemical Science and Technology / v.13, no.1, 2022 , pp. 138-147 More about this Journal
Abstract
The synergistic effect of 2-chloromethylbenzimidazole (2-CBI) and potassium iodide (KI) for mild steel in 1 M hydrochloric acid solution was investigated by potentiodynamic polarization curves and electrochemical impedance spectroscopy (EIS). The results showed that, with the addition of 100 ppm potassium iodide, the inhibition efficiecy (IE) of 100 ppm 2-CBI in 1 M hydrochloric acid had been improved from 91.14% to 96.15%. And synergistic parameter of 100 ppm 2-CBI with different amounts of potassium iodide is always greater than 1. The adsorption of potassium iodide combining with 100 ppm 2-CBI obeys to the Langmuir adsorption isotherm. Thermodynamic adsorption parameters, including ∆G0ads, ∆Ha and ∆Sa of the adsorption of the combinned inhibitor, as well as the Ea of the mild steel corrosion in 1 M HCl with the combinned inhibitor, were calculated.
Keywords
Mild Steel; 2-Chloromethylbenzimidazole; Potassium Iodide; Synergism; Adsorption;
Citations & Related Records
연도 인용수 순위
  • Reference
1 A. Popova, M. Christov, Corros. Sci., 2006, 8(10), 3208-3221.
2 L. Feng, S. Zhang, Y. Lu, B. Tan, S. Chen, L. Guo, Appl.Surf.Sci., 2019, 483, 901-911.   DOI
3 A. Yurt, A. Balaban, S.U. Kandemir, G. Bereket, B. Erk, Mater.Chem.Phys., 2004, 85(2-3), 420-426.   DOI
4 M.A. Hegazy, A.S. El-Tabei, A.H. Bedair, M.A. Sadeq, Corros. Sci., 2012, 54, 219-230.   DOI
5 D.K. Yadav, M.A. Quraishi, B. Maiti, Corros. Sci., 2012, 55, 254-266.   DOI
6 S. Hari Kumar, S. Karthikeyan, Ind.Eng.Chem.Res., 2013, 52(22), 7457-7469.   DOI
7 Sudheer, M.A. Quraishi, Ind.Eng.Chem.Res., 2014, 53(8), 2851-2859.   DOI
8 H.K. Sappani, S. Karthikeyan, Ind.Eng.Chem.Res., 2014, 53(9), 3415-3425.   DOI
9 A. Popova, E. Sokolova, S. Raicheva, M. Christov, Corros. Sci., 2003, 45(1), 33-58.   DOI
10 R. Solmaz, G. Kardas, M. Culha, B. Yazici, M. Erbil, Electrochim. Acta, 2008, 53(20), 5941-5952.   DOI
11 A. Popova, M. Christov, S. Raicheva, E. Sokolova, Corros. Sci., 2004, 46(6), 1333-1350.   DOI
12 N. Hackerman, A.C. Makrides, Ind.eng.chem, 1954, 6(3), 523-527.   DOI
13 K.F. Khaled, Electrochim. Acta, 2003, 48(17), 2493-2503.   DOI
14 J. Cruz, R. Martinez, J. Genesca, E. Garcia-Ochoa, J.Electroanal.Chem., 2004, 566(1), 111-121.   DOI
15 K.F. Khaled, J.Appl.Electrochem., 2010, 41(3), 277-287.   DOI
16 R.L. Camacho-Mendoza, E. Gutierrez-Moreno, E. Guzman-Percastegui, E. Aquino-Torres, J. Cruz-Borbolla, J.A. Rodriguez-Avila, J.G. Alvarado-Rodriguez, O. Olvera-Neria, P. Thangarasu, J.L. Medina-Franco, J.Chem.Inf.Model., 2015, 55(11), 2391-2402.   DOI
17 Fishtik, J.Electroanal.Chem., 1984, 165, 1-8.   DOI
18 X. Li, S. Deng, H. Fu, G. Mu, Corros. Sci., 2008, 50(9), 2635-2645.   DOI
19 E.E. Oguzie, Y. Li, F.H. Wang, J.Colloid.Interface.Sci., 2007, 310(1), 90-98.   DOI
20 M.M. Solomon, S.A. Umoren, I.B. Obot, A.A. Sorour, H. Gerengi, ACS Appl.Mater Interfaces, 2018, 10(33), 28112-28129.   DOI
21 I.B. Onyeachu, M.M. Solomon, J.Mol.Liq., 2020, 313, 113536 .   DOI
22 G. Zerjav, I. Milosev, Mater.Corros., 2015, 66(12), 1402-1413.   DOI
23 M. Mahdavian, S. Ashhari , Electrochim. Acta, 2010, 55(5), 1720-1724.   DOI
24 I.O. Arukalam, Carbohydr.Polym., 2014, 112, 291-299.   DOI
25 Y. Feng, K.S. Siow, W.K. Teo, A.K. Hsieh, Corros. Sci., 1999, 41(5), 829-852.   DOI
26 T. Murakawa, S. Nagaura, N. Hackerman, Corros. Sci., 1967, 7(2), 79-89.   DOI
27 S.A. Umoren, M.M. Solomon, J.Ind.Eng.Chem., 2015, 21, 81-100.   DOI
28 M.A. Migahed, I.F. Nassar, Electrochim. Acta, 2008, 53(6), 2877-2882.   DOI
29 A.M. Badawi, M.A. Hegazy, A.A. El-Sawy, H.M. Ahmed, W.M. Kamel, Mater.Chem.Phys., 2010, 124(1), 458-465.   DOI
30 F. Bentiss, M. Lebrini, M. Lagrenee, Corros. Sci., 2005, 47(12), 2915-2931.   DOI
31 M.A. Amin, Q. Mohsen, O.A. Hazzazi, Mater.Chem.Phys., 2009, 114(2-3), 908-914.   DOI
32 E.A. Noor, A.H. Al-Moubaraki, Mater.Chem.Phys., 2008, 110(1), 145-154.   DOI
33 N. Yilmaz, A. Fitoz, y. Ergun, K.C. Emregul, Corros. Sci., 2016, 111, 110-120.   DOI
34 M.S. Kumar, S.L.A. Kumar, A. Sreekanth, Ind.Eng.Chem.Res., 2012, 51(15), 5408-5418.   DOI
35 M.A.M. Ibrahim, E.M.A. Omar, Surf.Coat.Technol., 2013, 226, 7-16.   DOI
36 S. Martinez, I. Stern, Appl.Surf.Sci., 2002, 199(1-4), 83-89.   DOI
37 I.B. Obot, U.M. Edouk, J.Mol.Liq., 2017, 46, 66-90.
38 J. Aljourani, K. Raeissi, M.A. Golozar, Corros. Sci., 2009, 51(8),1836-1843.   DOI
39 F.S. de Souza, A. Spinelli, Corros. Sci., 2009, 51(3), 642-649.   DOI
40 N.T. Abdel Ghani, A.M. Mansour, Spectrochim.Acta, Part A, 2012, 86, 605-613.   DOI
41 Z. Li, D. Wang, B. He, X. Ye, W. Guo, Mater.Tehnol., 2018, 52(3), 307-314.   DOI
42 J. Liu, D. Wang, L. Gao, D. Zhang, Appl.Surf.Sci., 2016, 389, 369-377.   DOI
43 A.S. Fouda, A.A. Al-Sarawy, E.E. El-Katori, Desalination, 2006, 201(1-3), 1-13.   DOI
44 A.A. Khadom, Reaction Kinetics, React. Kinet.Mech.Cat., 2015, 115(2) , 463-481.   DOI
45 D.B. Tripathy, M. Murmu, P. Banerjee, M.A. Quraishi, Desalination, 2019, 472, 114128.   DOI
46 T. Douadi, H. Hamani, D. Daoud, M. Al-Noaimi, S. Chafaa, J.Taiwan Inst.Chem.Eng., 2017, 71, 388-404.   DOI
47 P.C. Okafor, Y. Zheng, Corros. Sci., 2009, 51(4), 850-859.   DOI
48 Z. Li, J. Xu, W. Guo, K. Liang, Y. Zhang, B. He, Electrochemistry, 2017, 5(8), 456-460.
49 R.G. Sundaram, G. Vengatesh, M. Sundaravadivelu, Surf.Interfaces, 2021, 22, 100841.   DOI
50 J. Saranya, M. Sowmiya, P. Sounthari, K. Parameswari, S. Chitra, K. Senthilkumar, J.Mol.Liq., 2016, 216, 42-52.   DOI
51 M. Yadav, S. Kumar, T. Purkait, L.O. Olasunkanmi, I. Bahadur, E.E. Ebenso, J.Mol.Liq., 2016, 213, 122-138.   DOI
52 P. Kannan, T.S. Rao, N. Rajendran, J.Mol.Liq., 2016, 222, 586-595.   DOI
53 X. Li, S. Deng, H. Fu, Corros. Sci., 2011, 53(11), 3704-3711.   DOI
54 X. Li, S. Deng, H. Fu, X. Xie, Corros. Sci., 2014, 78 , 29-42.   DOI
55 M. Mobin, M. Rizvi, Carbohydr.Polym., 2016, 136, 384-393.   DOI