• 제목/요약/키워드: M-type ferrite

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구상흑연주철(球狀黑鉛鑄鐵)의 3상혼합조직(相混合組織)의 변태거동(變態擧動)에 관(關)한 연구(硏究) (A Study on the Transformation Behaviors of a Multi-phase (Ferrite-Bainite-Martensite) in Ductile Cast Iron)

  • 김석원;김동건;유선경
    • 한국주조공학회지
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    • 제11권5호
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    • pp.406-413
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    • 1991
  • Ductile cast iron(DCI) with a multi-phase(ferrite-bainite-martensite) structures was produced by various special heat treatment. Intercritical heat treatment(I. C.), intermediate heat treatment(I. M.) and step quenching(S. Q.) were used to strengthen and toughen the fracture initiation sites such as graphite-marix interfaces and eutectic cell boundaries in DCI. The purpose of this study was to investigate of DCI by the special heat treatment. (I. C., I. M., and S. Q.) At a result, bainite nucleation rate at higher temperature was higher than that of at lower temperature, and shapes of bainite and martensite became bar /spheroidal type with increase of isothermal transformation time.

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Mill Scale을 이용한 M형 Ferrite의 합성 (Preparation of M Type Hexa-Ferrite Using the Mill Scale)

  • 오영우
    • 한국자기학회지
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    • 제6권4호
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    • pp.204-210
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    • 1996
  • 제철소의 부산물인 mill scale과 $Fe_{2}O_{3}$, 그리고 이들의 혼합물을 사용하여 M형 ferrite를 제조하였다. $Fe_{2}O_{3}$$BaCO_{3}$의 몰비를 5.2~6.0으로 변화시킨 혼합물의 하소 및 소결은 각각 $1150^{\circ}C,\;1250^{\circ}C$에서 2시간 행하였으며, 하소시에 mill scale 중의 불순물 성분인 $SiO_{2},\;Al_{2}O_{3},\;MgO,\;CaO\;및\;Na_{2}O$를 적당량 첨가한 시편으로 자기적 특성과 형상을 조사하였다. $Na_{2}O$를 첨가한 시편은 미반응의 $Fe_{2}O_{3}$와 중간 화합물인 $BaFe_{2}O_{4}$의 영향으로 자기적 특성이 감소하였으나, $BaO.5.6Fe_{2}O_{3}$ 조성에 $SiO_{2}$$Al_{2}O_{3}$의 첨가는 특성의 증진을 보였으며, 특히 $Al_{2}O_{3}$$M_{s}$ 값은 감소시켰으나 $_{B}H_{c}$ 값을 증가시켰다. BM($BaCo_{3}$와 mill scale의 혼합물)과 BFM($BaCO_{3},\;Fe_{2}O_{3}$, mill scale의 혼합물) 소결 시편의 ${(BH)}_{max}$는 각각 0.86, 1.04 MGOe였으며, $440^{\circ}C$ 부근에서 자기 특성의 변화를 보였다.

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구상흑연주철의 강인화에 미치는 3상 혼합조직의 영향 (The Effect of the Multi-phase (ferrite-bainite-martensite) on the Strengthening and Toughening in the Ductile Cast Iron)

  • 김석원;이방식
    • 한국주조공학회지
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    • 제8권3호
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    • pp.310-321
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    • 1988
  • This study is aimed to investigate the effects of the multi-phase(ferrite-bainite-martensite) on the strengthening and toughening in ductile cast iron. All the specimen were austenitized at eutectoid transformation temperature range(${\alpha}+{\gamma}$) for 1hr and austempered at $300^{\circ}C$ and $400^{\circ}C$ for various holding time, and then quenched in iced water for multi - phase (${\alpha}-B-M$). When the volume fraction of martensite is below 15%, excellent maximum fracture load can be obtained due to strengthening by the fine martensite, but, with increasing of volume fraction over 15%, it was decreased drastically. The martensite size became finer and the shape of it changed from bar to spherical type with increasing of austempering holding time. The higher the austenitizing temperature is, the more preferential is the formation of austenite phase around the graphite nodules improving strength and toughness of austempered ductile cast iron.

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페라이트상을 갖는 12Cr 내열강의 기계적성질에 미치는 템퍼링 처리의 영향 (Effect of tempering treatment on the mechanical properties in 12Cr heat resistant steel with ferrite phase)

  • 강창룡;이상명;조영관;변삼섭;정병호
    • 동력기계공학회지
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    • 제15권2호
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    • pp.49-54
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    • 2011
  • Effect of tempering treatment on the mechanical properties of 12Cr heat resistant steel with ferrite phase was investigate in this study. As time and temperature of tempering treatment were increase, C and Cr contents in matrix structure were decreased. Due to increase of the amount of Cr26C6 type carbides. It was confirmed in mechanical properties experimental that tensile strength and hardness were decreased, while elongation and impact value were, increased with increasing the time and temperature.

Magnetic and Microwave Absorbing Properties of Ti-and Co-Substituted Barium Ferrite (BaFe12-2X TiXCoXO19)

  • Han-Shin Cho;Yong-Jin Kim;Sung-Soo Kim
    • Journal of Magnetics
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    • 제4권2호
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    • pp.65-68
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    • 1999
  • The M-type barium ferrite ($BaFe_{12}O_{19}$) is well known magnetic material to be used as a permanent magnet due to its strong uniaxial anisotropy. The substitution of nonmagnetic $Ti^{+4}$ and magnetically weak $Co+^2ion for Fe^{+3}$ to its strong uniaxial anisotropy. The substitution of nonmagnetic $Ti^{+4}$ and magnetically weak $Co+^2ion for Fe^{+3}$ sublattices reduces the uniaxial anisotropy and those compounds open a new application field of noise suppressor at high frequencies. In this study, the magnetic and microwave absorbing properties are investigated in Ti-and Co-substituted barium ferrites ($BaFe_{12-2X} Ti_XCo_XO_{19}$). The saturated magnetization decreases linearly with the substitution of Ti and Co. The rapid drop in coercive force is observed with Ti and Co substitution upto x=1.2. The magnetic permeability spectrum shows the natural magnetic resonance in the specimens with small coercive force and large attenuation of microwave is predicted in those specimens at high frequencies (above 4 GHz).

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NiFe2O4/m-ZrO2 device를 이용한 고온 태양열 열화학 싸이클의 수소 생산 (Hydrogen production with high temperature solar heat thermochemical cycle using NiFe2O4/m-ZrO2 device)

  • 이진규;신일융;서태범
    • 한국태양에너지학회 논문집
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    • 제31권1호
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    • pp.107-114
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    • 2011
  • Two-step thermochemical cycle using ferrite-oxide($Fe_3O_4$) device was investigated. The $H_2O$(g) was converted into $H_2$ in the first experiment which was performed using a dish type solar thermal system. However the experiment was lasted only for 2 cycles because the metal oxide device was sintered and broken down. Another problem was that the reaction was taken place mainly on a side of the metal oxide device. The $m-ZrO_2$, which was widely known as a material preventing sintering, was applied on the metal oxide device. The ferrite loading rate and the thickness of the metal oxide device were increased from 10.67wt% to 20wt% and from 10mm to 15mm, respectively. The chemical reactor having two inlets was designed in order to supply the reactants uniformly to the metal oxide device. The second-experiment was lasted for 5 cycles, which was for 6 hours. The total amount of the $H_2$ production was 861.30mL.

Synthesis of Metal and Ceramic Magnetic Nanoparticles by Levitational Gas Condensation (LGC)

  • Uhm, Y.R.;Lee, H.M.;Lee, G.J.;Rhee, C.K.
    • Journal of Magnetics
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    • 제14권2호
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    • pp.75-79
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    • 2009
  • Nickel (Ni) and ferrite ($Fe_3O_4$, $NiFe_2O_4$) nanoparticles were synthesized by LGC using both wire feeding (WF) and micron powder feeding (MPF) systems. Phase evolution and magnetic properties were then investigated. The Ni nanopowder included magnetic-ordered phases. The LGC synthesis yielded spherical particles with large coercivity while the abnormal initial magnetization curve for Ni indicated a non-collinear magnetic structure between the core and surface layer of the particles. Since the XRD pattern cannot actually distinguish between magnetite ($Fe_3O_4$) and maghemite (${\gamma}-Fe_2O_3$) as they have a spinel type structure, the phase of the iron oxide in the samples was unveiled by $M{\ddot{o}}ssbauer$ spectroscopy. The synthesized Ni-ferrite consisted of single domain particles, including an unusual ionic state. The synthesized nanopowder bore an active surface due to the defects that affected abnormal magnetic properties.

NiFe2O4/m-ZrO2와 CeO2를 이용한 고온 태양열 열화학 싸이클의 수소 생산 (Two-step thermochemical cycles for hydrogen production using NiFe2O4/m-ZrO2 and CeO2 devices)

  • 김철숙;조지현;김동연;서태범
    • 한국태양에너지학회 논문집
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    • 제33권2호
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    • pp.93-100
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    • 2013
  • Two-step thermochemical cycle using ferrite-oxide($Fe_2O_4$) device was investigated. The $H_2O$(g) was converted into $H_2$ in the first experiment which was performed using a dish type solar thermal system. However the experiment was lasted only for 2 cycles because the metal oxide device was sintered and broken down. Another problem was that the reaction was taken place mainly on a side of the metal oxide device. The m-$ZrO_2$, which was widely known as a material preventing sintering, was applied on the metal oxide device. The ferrite loading rate and the thickness of the metal oxide device were increased from 10.67wt% to 20wt% and from 10mm to 15mm, respectively. The chemical reactor having two inlets was designed in order to supply the reactants uniformly to the metal oxide device. The second-experiment was lasted for 5 cycles, which was for 6 hours. The total amount of the $H_2$ production was 861.30ml. And cerium oxide($CeO_2$) device was used for increasing $H_2$ production rate. $CeO_2$ device had low thermal resistance, however, more $H_2$ production rate than $Fe_2O_4$ device.