• 한국재료학회지
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• 제26권11호
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• pp.604-610
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• 2016

We report on the fabrication and characterization of a novel $Cu_2O/CuO$ heterojunction structure with CuO nanorods embedded in $Cu_2O$ thin film as an efficient photocathode for photoelectrochemical (PEC) solar water splitting. A CuO nanorod array was first prepared on an indium-tin-oxide-coated glass substrate via a seed-mediated hydrothermal synthesis method; then, a $Cu_2O$ thin film was electrodeposited onto the CuO nanorod array to form an oxide semiconductor heterostructure. The crystalline phases and morphologies of the heterojunction materials were examined using X-ray diffraction and scanning electron microscopy, as well as Raman scattering. The PEC properties of the fabricated $Cu_2O/CuO$ heterojunction photocathode were evaluated by photocurrent conversion efficiency measurements under white light illumination. From the observed PEC current density versus voltage (J-V) behavior, the $Cu_2O/CuO$ photocathode was found to exhibit negligible dark current and high photocurrent density, e.g. $-1.05mA/cm^2$ at -0.6 V vs. $Hg/HgCl_2$ in $1mM\;Na_2SO_4$ electrolyte, revealing the effective operation of the oxide heterostructure. The photocurrent conversion efficiency of the $Cu_2O/CuO$ photocathode was estimated to be 1.27% at -0.6 V vs. $Hg/HgCl_2$. Moreover, the PEC current density versus time (J-T) profile measured at -0.5 V vs. $Hg/HgCl_2$ on the $Cu_2O/CuO$ photocathode indicated a 3-fold increase in the photocurrent density compared to that of a simple $Cu_2O$ thin film photocathode. The improved PEC performance was attributed to a certain synergistic effect of the bilayer heterostructure on the light absorption and electron-hole recombination processes.

• 충청수학회지
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• 제21권3호
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• pp.371-376
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• 2008

Let $P(M,G,{\pi})=:P$ be a principal fibre bundle with structure Lie group G over a base manifold M. In this paper we get the following facts: 1. The tangent bundle TG of the structure Lie group G in $P(M,G,{\pi})=:P$ is a Lie group. 2. The Lie algebra ${\mathcal{g}}=T_eG$ is a normal subgroup of the Lie group TG. 3. $TP(TM,TG,{\pi}_*)=:TP$ is a principal fibre bundle with structure Lie group TG and projection ${\pi}_*$ over base manifold TM, where ${\pi}_*$ is the differential map of the projection ${\pi}$ of P onto M. 4. for a Lie group $H,\;TH=H{\circ}T_eH=T_eH{\circ}H=TH$ and $H{\cap}T_eH=\{e\}$, but H is not a normal subgroup of the group TH in general.

• 생약학회지
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• 제29권3호
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• pp.169-172
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• 1998

Hyaluronidase is one of the mucopolysaccharide-splitting enzyme and is related to the permeability of the vascular system and inflammation. An anti-hyaluronidase assay guided fractionation of the methanolic extract of Uncariae Ramulus et Uncus has furnished a pentacyclic triterpene, ursolic acid (compound I). Compound I exhibited hyaluronidase inhibitory activity with $IC_{50}$ value of 0.15 mM, and disodium cromoglycate showed the inhibitory activity with $IC_{50}$ value of 1.78 mM as a positive control.

• Advances in concrete construction
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• 제2권2호
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• pp.91-108
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• 2014

This paper presents a nonlinear finite element analysis (FEA) in order to investigate the flexural performance of one-way slabs strengthened by epoxy-bonded steel plates. Four point loading scheme is selectively chosen. A model is developed to implement the material constitutive relationships and non-linearity. Five Slabs were modeled in FEM software using ABAQUS. One slab was unstrengthened control slab and the others were strengthened with steel plates with varying the plate thickness and configuration. In order to verify the accuracy of the numerical model, a comparison was done between the experimental results available in the literature and the proposed equations by ACI 318-11 for the calculation of ultimate load capacities of strengthened slabs, the agreement has proven to be good and FEA attained accurate results compared with ACI code. A parametric study was also carried out to investigate the influence of thickness of steel plate, strength of epoxy layer and type of strengthening plate on the performance of plated slabs. Also, the practical and technical feasibility of splitting the steel plate in strengthening process has been taken into account. For practical use, the author recommended to use bonded steel plate as one unit rather than splitting it to parts, because this saves more effort and reduces the risk of execution errors as in the case of multiple bonded parts. Both techniques have nearly the same effect upon the performance of strengthened slabs.

• 대한전기학회:학술대회논문집
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• 대한전기학회 2008년도 제39회 하계학술대회
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• pp.464-465
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• 2008

Concrete poles(CP) are popular supports for distribution lines. Various types of grounding electrode, such as copper-clad rods, have been used to maintain CP's ground resistance under the required value. The buried part of CP can also have structural grounding effect because of its iron reinforcing rods inside CPs. In this paper, we measured the total ground current injected into CP ground while measuring the ground current splitting to the metal electrode as well as the total injecting current. By this, it was able to measure the ground current splitting to CP structure. Based on the measured results, interrelationship between ground resistance of metal electrodes and current split factor to CP structure was analyzed.

• 산업경영시스템학회지
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• 제35권4호
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• pp.83-97
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• 2012

In this paper, we consider a single-manufacturer single-buyer supply chain problem where a single manufacturer purchases and processes raw materials into a family of items in order to deliver a family of items to a single buyer at a fixed interval of time for effective implementation of Just-In-Time Purchasing. An integrated multi-item lot-splitting model of facilitating multiple shipments in small lots between buyer and manufacturer is developed in a JIT Purchasing environment. Previous research on the integrated model assumed that the manufacturer orders raw materials m (integer) times for every production run (lot multiplier policy for the raw material). In this paper, we consider a generalized policy in the replenishment of raw materials, allowing lot multiplier policy and lot splitting policy. An iterative solution procedure is developed to find the order interval for finished goods and raw materials, and number of shipments between buyer and manufacturer. We show by numerical example that when the integrated policy is adopted by both buyer and manufacturer in a cooperative manner, both parties can benefit.

• 한국태양에너지학회:학술대회논문집
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• 한국태양에너지학회 2011년도 추계학술발표대회 논문집
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• pp.169-176
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• 2011

The two-step water splitting thermochemical cycle is composed of the T-R (Thermal Reduction)and W-D (Water Decomposition)steps. The mechanism of this cycle is oxidation-reduction, which produces hydrogen. The reaction temperature necessary for this thermochemical cycle can be achieved by a dish-type solar thermal collector (Inha University, Korea). The purpose of this study is to validate a water splitting device in the field. The device is studied and fabricated by Kodama et al (2010, 2011). The validation results show that the foam device, when loaded with $NiFe_2O_4/m-ZrO_2$powder, was successfully achieved hydrogen production with 9 (10 with a Xe-light solar simulator, 2009, Kodama et al.) repeated cycles under field conditions. Two foam device used in this study were tested for validation before an experiment was performed. The lab scale ferrite-conversion rate was in the range of 24~76%. Two foam devices were designed to for structural stability in this study. In the results of the experiments, the hydrogen percentage of the weight of each foam device was 7.194 and $9.954{\mu}mol\;g^{-1}$ onaverage, and the conversion rates 4.49~29.97 and 2.55~58.83%, respectively.

• 한국재료학회지
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• 제30권5호
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• pp.239-245
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• 2020

Synthesizing one-dimensional nanostructures of oxide semiconductors is a promising approach to fabricate highefficiency photoelectrodes for hydrogen production from photoelectrochemical (PEC) water splitting. In this work, vertically aligned zinc oxide (ZnO) nanorod arrays are successfully synthesized on fluorine-doped-tin-oxide (FTO) coated glass substrate via seed-mediated hydrothermal synthesis method with the use of a ZnO nanoparticle seed layer, which is formed by thermally oxidizing a sputtered Zn metal thin film. The structural, optical and PEC properties of the ZnO nanorod arrays synthesized at varying levels of Zn sputtering power are examined to reveal that the optimum ZnO nanorod array can be obtained at a sputtering power of 20 W. The photocurrent density and the optimal photocurrent conversion efficiency obtained for the optimum ZnO nanorod array photoanode are 0.13 mA/㎠ and 0.49 %, respectively, at a potential of 0.85 V vs. RHE. These results provide a promising avenue to fabricating earth-abundant ZnO-based photoanodes for PEC water oxidation using facile hydrothermal synthesis.

• 한국표면공학회지
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• 제56권4호
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• pp.265-272
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• 2023

Photoelectrochemical (PEC) water splitting is one of the promising methods for hydrogen production by solar energy. Iron oxide has been effectively investigated as a photoelectrode material for PEC water splitting due to its intrinsic property such as short minority carrier diffusion length. However, iron oxide has a low PEC efficiency owing to a high recombination rate between photoexcited electrons and holes. In this study, we synthesized nanoporous structured iron oxide by anodization to overcome the drawbacks and to increase surface area. The anodized iron oxide was annealed in Ar atmosphere with different purging times. In conclusion, the highest current density of 0.032 mA/cm² at 1.23 V vs. RHE was obtained with 60 s of pursing for iron oxide(Fe-60), which was 3 times higher in photocurrent density compared to iron oxide annealed with 600 s of pursing(Fe-600). The resistances and donor densities were also evaluated for all the anodized iron oxide by electrochemical impedance spectra and Mott-Schottky plot analysis.

• Advances in concrete construction
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• 제16권2호
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• pp.119-126
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• 2023

Steel fiber reinforced self-compacting concrete (SFRSCC) has good workability such as high flowability and good cohesiveness. The workability, compressive strength, splitting tensile strength, and anti-penetration characteristics of three kinds of SFRSCC were investigated in this paper. The fraction of steel fibers of the SFRSCC is 0.5%, 1.5% and 2.0% respectively. The results of the static tests show that the splitting tensile strength increases with the increase of fraction of steel fibers, while the compressive strength of 1.5% SFRSCC is lowest. It is demonstrated that the anti-penetration ability of 1.5% SFRSCC subjected to a velocity projectile (200-500 m/s) is better than 0.5% and 2.0% SFRSCC according to the experimental results. Considering the steel fiber effects, the existing formula is revised to predict penetration depth, and it is revealed that the revised predicted depth of penetration is in good agreement with the experimental results. The conclusion of this paper is helpful to the experimental investigations and engineering application.