• Title/Summary/Keyword: M-splitting

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Thermochemical hydrogen production utilization of M-ferrite (M=Co,Ni,Mn) (M-ferrite를 이용한 열화학적 수소제조(M=Co,Ni,Mn))

  • Cho, Mi-Sun;Kim, Woo-Jin;Woo, Sung-Woong;Park, Chu-Sik;Kang, Kyoung-Soo;Choi, Sang-Il
    • 한국신재생에너지학회:학술대회논문집
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    • 2006.06a
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    • pp.43-46
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    • 2006
  • 본 연구는 페라이트의 Fe 양이온 일부를 Ni, Mn, Co등으로 치환하여 M-ferrites를 제조하여 열화학적 2단계 물 분해 반응의 특성을 비교 평가하였고, XRD, SEM, GC등의 분석으로 각 금속산화물의 특성을 확인하였다. M-ferrites는 고상법으로 제조하였다. 각각의 M-ferrites에 대한 열적환원은 1573K에서 진행하였고 물 분해 반응은 1273K에서 실시하였다. 이 반응에서 생성된 가스는 전량 포집하여 GC를 통해 분석하였다. 반응 전후의 시료에 대하여 SEM, XRD를 분석하여 GC결과와 함께 금속산화물의 산화환원반응 특성을 고찰하였다. 그 결과로서 물 분해 반응 후 M-ferrite (M=Co, Ni, Mn)의 생성을 XRD를 통하여 확인할 수 있었고, 물 분해 반응과의 비교결과 격자상수의 증대가 M-ferrite내의 산소의 환원에 영향을 미치는 것을 알 수 있었다. SEM결과에서는 4cycle의 물 분해 반응 후 Mn-ferrite의 심한 sintering 현상을 확인 할 수 있었다.

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A CASE REPORT OF CORRECTION OF MANDIBULAR PROGNATHISM BY INTRAORAL OBLIQUE SPLITTING OSTEOTOMY OF MANDIBULAR RAMI (구내 경사 분열 골절단술(Intraoral oblique splitting osteotomy)에 의한 하악 전돌증의 치험례)

  • Park, Hui-Dae;Doe, Kee-Yong;Bae, Yun-Ho;Byun, Sang-Kill;Chin, Byung-Rho;Lee, Hee-Keung
    • Journal of Yeungnam Medical Science
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    • v.6 no.2
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    • pp.183-194
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    • 1989
  • This is a report of 2-cases of mandibular prognathism corrected by Intraoral oblique splitting osteotomy of mandibular ramus. The Intraoral oblique splitting osteotomy is a modification of sagittal split osteotomy of ramus and it is documented by Yoshida, on 1985. By this method. authors obtained the following results. 1. The patients' esthetic, psychological and functional problems were dissolved by setback of mandibular prognathism. 2. The postoperative infection, splitted bone segments fracture, paresthesia of the face and T.M.J. dysfunction were not appeared. 3. Postoperative intermaxillary fixation was maintained for 8 weeks. The patients could open their mouths in normal range after a week of intermaxillary fixation removal. 4. The soft tissue changes of lower lip and chin were about 1:1 to the hard tissue changes. 5. During intermaxillary fixation period and postoperative orthodontic treatment, slight relapse was observed. Now, the patients are under postoperative orthodontic treatment.

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A Flowfield Analysis Around an Airfoil by Using the Euler Equations (Euler 방정식을 사용한 익형 주위에서의 유동장 해석)

  • Kim M. S.
    • 한국전산유체공학회:학술대회논문집
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    • 1999.05a
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    • pp.186-191
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    • 1999
  • An Euler solver is developed to predict accurate aerodynamic data such as lift coefficient, drag coefficient, and moment coefficient. The conservation law form of the compressible Euler equations are used in the generalized curvilinear coordinates system. The Euler solver uses a finite volume method and the second order Roe's flux difference splitting scheme with min-mod flux limiter to calculate the fluxes accurately. An implicit scheme which includes the boundary conditions is implemented to accelerate the convergence rate. The multi-block grid is integrated into the flow solver for complex geometry. The flowfields are analyzed around NACA 0012 airfoil in the cases of $M_{\infty}=0.75,\;\alpha=2.0\;and\;M_{\infty}=0.80,\;\alpha=1.25$. The numerical results are compared with other numerical results from the literature. The final goal of this research is to prepare a robust and an efficient Navier-Stokes solver eventually.

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Erysiphe magnoliicola Comprises the Powdery Mildew Found on Magnolia kobus in Korea

  • In-Young Choi;Lamiya Abasova;Joon-Ho Choi;Byoung-Ki Choi;Hyeon-Dong Shin
    • The Korean Journal of Mycology
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    • v.50 no.2
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    • pp.125-130
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    • 2022
  • The powdery mildew found on Magnolia kobus was recorded as Microsphaera alni for the first time in Korea in 1975. After splitting M. alni into several distinct species, this mildew was regarded as Microsphaera magnifica, now Erysiphe magnifica. Since E. magnifica is known to be a North American species, the powdery mildew found on M. kobus in Korea was studied to clarify its identity. Based on morphological characteristics and sequencing results of the internal transcribed spacer and large subunit rDNA gene, the powdery mildew found on M. kobus in Korea was identified as Erysiphe magnoliicola.

Investigation of the mechanical and electrical properties of graphene nanoribbons-reinforced cementitious composites (그래핀 나노리본 보강 시멘트 복합체의 기계적 전기적 특성 분석)

  • Li, Pei-Qi;Liu, Jun-Xing;Bae, Sung-Chul
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2022.04a
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    • pp.184-185
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    • 2022
  • This study researched the effect of graphene nanoribbons (0.05 wt%) on cement-based materials' mechanical and electrical properties. The results were compared with the ordinary Portland cement (OPC) paste and OPC paste with the same content of carbon nanotubes. The experiment results showed that after curing for 28 days, the compressive and splitting tensile strength of the sample with graphene nanoribbons were increased by 17.8% and 6.6% compared to OPC paste, and its reinforced effect for cement-based materials was superior to carbon nanotubes. Besides, due to the excellent electrical properties of graphene nanoribbons, the sample reinforced by graphene nanoribbons had a lower electrical resistivity (135.5 Ω·m) than OPC paste (418.5 Ω·m) and paste with carbon nanotubes (175.5 Ω·m). This proved the promising application of graphene nanoribbons on cement-based materials.

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Effect of Hydrogen Treatment on Anatase TiO2 Nanotube Arrays for Photoelectrochemical Water Splitting

  • Kim, Hyun Sik;Kang, Soon Hyung
    • Bulletin of the Korean Chemical Society
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    • v.34 no.7
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    • pp.2067-2072
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    • 2013
  • Hydrogen ($H_2$) treatment using a two-step $TiO_2$ nanotube (TONT) film was performed under various annealing temperatures from $350^{\circ}C$ to $550^{\circ}C$ and significantly influenced the extent of hydrogen treatment in the film. Compared with pure TONT films, the hydrogen-treated TONT (H:TONT) film showed substantial improvement of material features from structural, optical and electronic aspects. In particular, the extent of enhancement was remarkable with increasing annealing temperature. Light absorption by the H:TONT film extended toward the visible region, which was attributable to the formation of sub-band-gap states between the conduction and valence bands, resulting from oxygen vacancies due to the $H_2$ treatment. This increased donor concentration about 1.5 times higher and improved electrical conductivity of the TONT films. Based on these analyses and results, photoelectrochemical (PEC) performance was evaluated and showed that the H:TONT film prepared at $550^{\circ}C$ exhibited optimal PEC performance. Approximately twice higher photocurrent density of 0.967 $mA/cm^2$ at 0.32 V vs. NHE was achieved for the H:TONT film ($550^{\circ}C$) versus 0.43 $mA/cm^2$ for the pure TONT film. Moreover, the solar-to-hydrogen efficiency (STH, ${\eta}$) of the H:TONT film was 0.95%, whereas a 0.52% STH efficiency was acquired for the TONT film. These results demonstrate that hydrogen treatment of TONT film is a simple and effective tool to enhance PEC performance with modifying the properties of the original material.

Reaction Characteristics of Thermochemical Methane Reforming on Ferrite-Based Metal Oxide Mediums (페라이트계 금속 산화물 매체 상에서 열화학 메탄 개질 반응 특성)

  • Cha, Kwang-Seo;Lee, Dong-Hee;Jo, Won-Jun;Lee, Young-Seak;Kim, Young-Ho
    • Transactions of the Korean hydrogen and new energy society
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    • v.18 no.2
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    • pp.140-150
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    • 2007
  • Thermochemical 2-step methane reforming, involving the reduction of metal oxide with methane to produce syngas and the oxidation of the reduced metal oxide with water to produce pure hydrogen, was investigated on ferrite-based metal oxide mediums. The mediums, CoFZ, CuFZ, or MnFZ, were composed of the mixture of M(M=Co, Cu or Mn)-substituted ferrite as an active component and $ZrO_2$ as a binder, respectively. The WZ medium, composed of the mixture of $WO_3$ and $ZrO_2$, was also prepared to compare. With an addition of $ZrO_2$, the surface area of the mediums was slightly increased and the sintering of active components was greatly suppressed during the reduction. The higher reactivity of the reduced mediums for water splitting was confirmed by the temperature programmed reaction. From the results of the thermochemical 2-step methane reforming, the reactivity of $CH_4$ reduction and water splitting with ferrite-based metal oxide mediums was relatively higher than that with WZ, and the order of reactivity of the mediums was MnFZ>CoFZ>CuFZ>WZ.

Hydrogen Production from Photocatalytic Splitting of Methanol/water Solution over Ti Impregnated WO3 (티타늄 함유 텅스텐 산화물 광촉매를 이용한 메탄올/물 분해로부터 수소제조)

  • Lee, Gayoung;Park, Yujin;Park, No-Kuk;Lee, Tae Jin;Kang, Misook
    • Clean Technology
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    • v.18 no.4
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    • pp.355-359
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    • 2012
  • For effectively photochemical hydrogen production, Ti ions (0.01, 0.10, 0.50 mol%) impregnated $WO_3$ ($Ti/WO_3$) nanometer sized particles were prepared using a impregnation method as a photocatalyst. The characteristics of the synthesized $Ti/WO_3$ photocatalysts were analyzed by X-ray diffraction (XRD), scanning electron microscopy (SEM), photoluminescence spectra (PL), atomic force microscope (AFM), and electrostatic force microscope (EFM). The evolution of $H_2$ from methanol/water (1/1) photo-splitting over $Ti/WO_3$ photocatalysts was enhanced compared to those over pure $TiO_2$ and $WO_3$ photocatalysts; 3.02 mL of $H_2$ gas was evolved after 8 h when 0.5 g of a 0.10 mol% $Ti/WO_3$ catalyst was used.

Isolation and Characterization of Bacillus sp. P16 Producing Extracellular Chitosanase (키토산분해효소를 생산 분비하는 Bacillus sp. P16의 선발 및 특성)

  • Jung, Mi-Ra;Jo, Yoo-Young;Chi, Yeon-Tae;Park, Ro-Dong
    • Applied Biological Chemistry
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    • v.40 no.5
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    • pp.369-374
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    • 1997
  • An endochitosanase-producing bacterium was isolated from soil and identified as a strain of Bacillus sp. The isolate was gram positive, rod shape $(0.4-0.6{\times}1.6-2.2{\mu}m)$, endospore-forming, catalase positive, and mobility positive, and grown at pH 4.5-11.0 and upto $42^{\circ}C$ in the medium containing 2% NaCl. RAPD analysis of the DNA purified from the strain was also performed, and the chitosanase-producing strain was named as Bacillus sp. P16. The culture supernatant of the strain showed strong liquefaction activity and rapidly decreased viscosity of chitosan solution. By TLC and HPLC, chitooligosaccharides of DP 2-7 were separated and identified from the enzyme hydrolyzates of chitosan. The chitosanase from Bacillus sp. P16 was thus regarded as an endo-splitting type.

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Meauring Method of Magnetic Particles' Coercivity Distribution and Its Applications (자성분말의 보자력 분포도 측정방법과 그 응용)

  • 홍양기;박상준;정홍식
    • Journal of the Korean Magnetics Society
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    • v.5 no.3
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    • pp.216-221
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    • 1995
  • Both manufacturing parameters and particles' chemical composition controll coercivity and its distribution of magnetic particles. The coercivity and its distribution are important properties for high density magnetic recording, so these are used as tool for evaluation of reproducibility of magnetic particles. We report in this paper the applications of dM/dH versus H curve, which is derived from magnetic hysteresis loop, to the evaluation of coercivity distribution of magnetic particles and oxidation studies of recording metal particles. The coercivity distri-bution can be estimated from the full width half rnaximun (FWHM) and the peak shape of the dM/dH versus H curve. The peak shape of the curve depends upon distribution of particles' coercivity. The peak of dM/dH versus H curve becomes broad and lor is splitted into two or rmre peaks. It depends on uniformity of particles' coercivity. When the coercivity difference between Ba-Ferrite and ${\gamma}-Fe_{2}O_{3}$ is larger than 600 Oe, the peak becomes broad and is consequently splitted into two peaks. Ununiformly substituted Ba-Ferrite particles show broad peak. It is apparent that the analysis of the curve is one of sensitive measuring techniques for determination of coercivity distri-bution and studies on magnetic properties of substituted Ba-Ferrite and oxidation of magnetic recording metal particles.

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