• 제목/요약/키워드: M/N ratio

검색결과 2,086건 처리시간 0.028초

Dye removal from water using emulsion liquid membrane: Effect of alkane solvents on efficiency

  • Ghaemi, Negin;Darabi, Farzaneh;Falsafi, Monireh
    • Membrane and Water Treatment
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    • 제10권5호
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    • pp.361-372
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    • 2019
  • Effect of different alkane based solvents on the stability of emulsion liquid membrane was investigated using normal alkanes (n-hexane, n-heptane, n-octane and n-decane) under various operating parameters of surfactant concentration, emulsification time, internal phase concentration, volume ratio of internal phase to organic phase, volume ratio of emulsion phase to external phase and stirring speed. Results of stability revealed that emulsion liquid membrane containing n-octane as solvent and span-80 (5 % (w/w)) as emulsifying agent presented the highest amount of emulsion stability (the lowest breakage) compared with other solvents; however, operating parameters (surfactant concentration (5% (w/w)), emulsification time (6 min), internal phase concentration (0.05 M), volume ratio of internal phase to organic phase (1/1), volume ratio of emulsion phase to external phase (1/5) and stirring speed (300 rpm)) were also influential on improving the stability (about 0.2% breakage) and on achieving the most stable emulsion. The membrane with the highest stability was employed to extract acridine orange with various concentrations (10, 20 and 40 ppm) from water. The emulsion liquid membrane prepared with n-octane as the best solvent almost removed 99.5% of acridine orange from water. Also, the prepared liquid membrane eliminated completely (100%) other cationic dyes (methylene blue, methyl violet and crystal violet) from water demonstrating the efficacy of prepared emulsion liquid membrane in treatment of dye polluted waters.

탈질 여과조에서 외부 탄소원 제거를 위한 적정 체류 시간과 외부 탄소원 종류 및 질산염 농도에 대한 외부 탄소원의 적정 비율 (Optimum Conditions for the Removal of External Organic Carbon Sources in a Submerged Denitrification Biofilter)

  • 오승용;조재윤;윤길하
    • 한국양식학회지
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    • 제12권1호
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    • pp.47-56
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    • 1999
  • 순환여과식 어류 양식 시설에서 호기성 미생물의 질산화 작용에 의하여 암모니아는 질산염으로 산화되어 축적되며 이를 제거하기 위하여 협기성 미생물을 이용한 탈질산화 과정을 많이 이용하고 있다. 이 과정에서 혐기성 미생물에 의한 탈질산화 효율은 외부 탄소원의 종류, 수리학적 체류시간(hydraulic retention time, HRT) 및 외부 탄소원 농도에 대한 수중 질산염의 농도비율 ($COD/NO_3^-N$, C;N)에 따라 달라진다. 따라서 우리 나라 순환여과식 양식장에서 일반적으로 이용되고 있는 선라이트 골판을 여과 재료로 한 침지식 여과조를 탈질 여과조로 이용하여 적정 유기 탄소원 제거 조건을 구명하기 위해 질산염의 농도를 순환여과식 양어장의 일반적인 농도인 $20.0mg/\ell$로 고정하고 외부 탄소원으로 메탄올과 글루코스를 사용하여 HRT와 C:N 비율 변화에 따른 적정 제거 조건을 알아보았다. 외부 탄소원의 종류에 따른 질산성질소의 제거 효율은 어떤 실험 조건에서도 메탄올이 글루코스보다 높게 나왔으며 HRT의 경우 글루코스와 메탄올 어느 쪽도 HRT 4시간 보다 8시간에서 효율이 좋았다. (P<0.05). HRT 8시간에서 C:N의 비율 3,4,5,6 중에서 5까지는 효율이 증가하여 글루코스의 경우 최대 제거 효율은 76.5%였고 일간 제거속도는 $223.5 g/m^2/day$였다. 그러나 외부 탄소원으로 메탄올을 사용할 경우 C:N 비율이 6으로 증가하면 효율이 감소되었다. HRT가 4시간일 경우 일간제거속도는 C:N 비율 5의 조건에서 메탄올이 $355.6g/m^2/day$로 가장 높았으나 배출수에 포함된 유기물 농도가 $40.9 mg/\ell$로 양어 용수에는 부적당하였다. 적정 제거 조건으로 생각되어지는 HRT 8시간, C:N 비율 5, 유기탄소원으로 메탄올을 사용하여 유입수의 질산성질소 농도를 $40.9 mg/\ell$ 로 높일 때 일간 제거속도는 질산성질소 농도가 20.6 mg/\ell$일 때 보다 2.2배가 증가하였다. 또한 배출수의 질산성질소 농도도 $5.6 mg/\ell$로 나타나 질산성질소의 일간제거속도는 높아졌으나 C:N 비율 5를 맞추기 위한 메탄올의 농도 증가로 인하여 배출수의 메탄올 농도가 $71.3 mg/\ell$로 증가하여 양식 dydt로는 부적당하였다. 따라서 선라이트 골판을 이용한 침지식 탈질조의 최적 운전 조건은 HRT 8시간, C:N 비율 5및 외부 탄소원으로 메탄올을 이용하는 것이 가장 좋은 결과를 나타내었다. 유입수의 질선성질소 농도가 증가하면서 질산성질소의 일간제거속도도 함께 증가하였고 이에 따라 수중 pH도 8.0에서 8.8까지 점차적으로 증가하는 결과를 나타내었다.

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2-Methoxy-5-Nitrophenol 금속착염의 화학적 성질에 관한 연구 (Studies on the Properties of 2-Methoxy-5-Nitrophenol Complex Salts)

  • 김선덕;우세홍;김명운
    • 한국환경보건학회지
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    • 제1권1호
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    • pp.21-27
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    • 1974
  • This work was carried out to investigate the chemical properties of the chelate compounds which were produced with 2-methoxy-5-nitrophenol(MNG) and metal salt such as copper nitrate and manganese nitrate. And obtained results were as in the followings. 1) The binding ratio of the chelate compounds formation were determined by using the molar ratio concentration method and their chemical structures were identified by IR-spectrum. 2) In the absorbance measuring, 2-methoxy-5-nitrophenol coordinated with manganese and copper showed the maximum absorbance at $430 m\mu$ and $410 m\mu$ respectively. 3) The binding ratio of chelated compounds were measured by molar ratio method and continuous variation method with spectrophotometer, which was identified as 1:2. 4) The conditional formation constant(log Kn value) of manganese and copper chelate compounds were 6.70, 6.75, respectively according to the equation of $log\frac{A-AM\circ n MNG}{AMm MNG-A}=n log (M\circ)+log Kn$ 5) The dissociations degree of manganese and copper chelate compound were $2, 300{\times} 10^{-7}$, $2, 346{\times} 10^{-7}$ respectively according to the molar calculation method.

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Assessment of In Vitro Oocyte Maturation in Two Gobiid Fish Species, Chasmichthys dolichognathus and Tridentiger trigonocephalus after Exposure to Benzo[a]pyrene

  • Hwang, In-Joon;Baek, Hea-Ja
    • 한국발생생물학회지:발생과생식
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    • 제15권3호
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    • pp.223-230
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    • 2011
  • Polycyclic aromatic hydrocarbons (PAHs) are ubiquitous environmental contaminants derived from incomplete combustion of carbons and crude oil. In this study, we investigated the effects of benzo[a]pyrene (B[a]P), a representative PAHs on in vitro sex steroid hormone production and germinal vesicle breakdown (GVBD) using isolated oocytes of longchin goby (Chasmichthys dolichognathus) and chameleon goby (Tridentiger trigonocephalus). Oocytes in diameters of 0.8-0.9 (end vitellogenic stage) and 0.9-1.0 mm (germinal vesicle migratory stage) from longchin goby and 0.5 mm (fully vitellogenic stage) from chameleon goby were used. In GVBD assay, B[a]P at 10 nM stimulated GVBD in the oocytes of 0.8-0.9 mm from longchin goby. B[a]P at 1 nM stimulated GVBD in the oocytes with diameter 0.5 mm from chameleon goby. In steroid production from oocytes of longchin goby, B[a]P at 100 nM decreased testosterone (T) production, B[a]P at 1,000 nM increased estraiol-17 (J (E2) production and 10 and 100 nM increased $17,20{\beta}$-dihydroxy-4-pregnen-3-one ($17{\alpha}20{\beta}P$) production in the oocytes with diameter 0.8-0.9 mm. B[a]P at 1,000 nM increased E2 production, 100 and 1,000 nM increased $17{\alpha}20{\beta}P$ production in the oocytes with diameter 0.9-1.0 mm. In steroid production of oocytes from chameleon goby, B[a]P at 1,000 nM increased $E_2$ production. B[a]P at 10 nM increased $17{\alpha}20{\beta}P$ production. In the ratio of $E_2$ to T ($E_2$/T), B[a]P at 100 and 1,000 nM increased $E_2$/T in the oocytes of longchin goby. B[a]P at 100 nM also increased $E_2$/T in the oocytes of chameleon goby. Taken together, these results suggest that B[a]P have not only weak estrogenic effects but progestogenic effects on oocyte maturation.

m-분포 페이딩과 라이시안 페이딩 환경 하에서의 다이버시티 수신된 DS-CDMA / MDPSK 신호의 성능 분석 (Performance Analysis of Diversity Received DS-CDMA/MDPSK Signals in m-distribution and Rician Fading Environments)

  • 이정도;강희조
    • 한국전자파학회논문지
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    • 제9권2호
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    • pp.191-198
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    • 1998
  • 본 논문에서는 대역확산 방식인 DS-CDMA /MDPSK 선호를 m 분포 페이딩과 라이시안 페이딩 환경 하에서 유도한 후, 페이딩으로 인한 경감된 오율성능을 개선하기 위해 MRC(Maximal Ratio Combining) 다이버시티 기법을 사용하여 두 환경에서 비교 분석하였다. 라이시안 페이딩 모델은 m-분포 페이딩 모텔에 알맞은 값을 선택하여, PN 코드 길이(N), 사용자 수(U), 다중 경로수(P), 페이딩 지수(m), 라이시안 지수(K), 다이버시티 가짓수(L), 그리고 비트에너지 대 잡음전력비($E_b/N_o$)를 함수로 하여 오율특성을 구했다. 그 결과 레일리 페이딩 상태에서는 두 결과는 완전히 일치하였으며, 페이딩이 약할수록, 사용자 수가 많을수록, 다중 경로수가 많을수록 그리고, PN 코드 길이가 작을 수록 결과는 점 점 더 일치해감을 알 수 있었다.

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경운기의 수리비계수(修理費係數) 산정(算定)에 관한 연구(硏究) (Estimation on the Coefficient of Repair & Maintenance Costs for Power Tiller)

  • 강창호;박남종;정두호
    • Journal of Biosystems Engineering
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    • 제15권2호
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    • pp.143-150
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    • 1990
  • This study was conducted to estimate the ratio of Repair & Maintenance (R&M) costs to purchasing price that is one of the important factors for calculating the management costs of farm machinery. For this purpose, hour of use and R & M costs of power tiller and its attachments utilized results that were investigated with 400 sample units, 50 units by years of use from 1 to 8 years in 1988. The results obtained are summarized as follows; 1. The ratio of R & M costs per hours and annual R & M costs, accumulated R & M costs when sercice life of power tiller is 7 years were 0.017%, 5.50% and 38.52%, respectively. And in case of rotary, these ratio when its service life is 6 years were 0.072%, 7.16% and 43.0%, respectively. 2. The relationship between accumulated hours of use(t) and accumulated R & M costs(Y) of power tiller and its attachments were $Y=19.3t^{1.3}$ in power tiller, $Y=0.03t^{2.09}$ in plow, $Y=48.84t^{1.25}$ in rotary and $Y=7.45t^{1.15}$ in trailer. 3. The ratio of accumulated R & M costs to purchasing price when service life of power tiller is 7 years was 38.5%, and in case of rotary, this ratio when its service life is 6 years was 43.0%.

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LPE 방법으로 제작된 InGaAsP/InP PBH-LD의 누설전류해석 (The analysis of leakage current of InGaAsP/InP PBH-LD fabricated by LPE)

  • 최미숙;김정호;홍창희
    • 한국정보통신학회:학술대회논문집
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    • 한국해양정보통신학회 2002년도 추계종합학술대회
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    • pp.481-485
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    • 2002
  • 본 연구에서는 수직형 LPE 장치를 이용하여 meltback 방법으로 제작된 PBH-LD에 대한 누설전류를 해석하였다. PBH-LD에서 활성층 이외의 p-n 다이오드와 p-n-p-n 전류차단층과 같은 누설경로에 따른 이들의 영향을 조사하였다. 이러한 누설전류의 영향을 알아보기 위해 누설 폭이 "0" 일 때와 누설 폭이 $W_{ι}$ 일 때를 비교하였다. 그 결과 누설 폭에 따른 임계전류는 누설 폭을 줄이거나, 고유저항 ($\rho$$_{ι}$$\rho$$_{a}$ )비를 증가시켜줌으로써 임계전류가 낮아짐을 확인하였다. 본 연구에서 제작된 LD의 경우 활성층의 폭 $W_{a}$ 가 약 1.4$\mu\textrm{m}$이고 누설 폭이 약 0.6$\mu\textrm{m}$로, 제작된 LD의 cavity length와 임계전류를 비교해 본 결과 고유저항비가 약 0.5일 때 누설 폭에 따른 계산된 임계전류값과 실제 제작된 PBH-LD의 임계전류값이 일치함을 확인하였다. 따라서, 제작된 PBH-LD의 p-InP 차단층의 도핑농도를 $10^{18}$ c $m_{-3}$ 에서 $10^{17}$ $cm^{-3}$으로 줄여 누설영역의 저항을 크게 함으로써 누설전류를 더 줄일 수 있으리라 생각된다.다.

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The Analysis of Protection Ratio and Its Effect of Interference-to-Noise Ratio for Digital Microwave System with Diversity

  • Suh Kyoung-Whoan;Jang Won-Gyu
    • Journal of electromagnetic engineering and science
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    • 제6권3호
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    • pp.189-195
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    • 2006
  • In this paper, the derivation of the protection ratio for the digital microwave system with diversity is newly suggested for a basic guidance of initial planning for frequency coordination, and computational results are presented for an actual radio frequency band. The net filter discrimination has been also examined to see the effect of the adjacent channel protection ratio caused by adjacent channel interference. In addition, the protection ratios for the space or frequency diversity system are analyzed in terms of diversity improvement factors to find out an equivalent allowable noise-to-interference ratio (N/I) from degraded fade margin. According to results for 6.2 GHz system, with the space diversity of 25 m distance between antennas or the frequency diversity of ${\Delta}f/f=0.05$, under 64-QAM and 60 km at BER $10^{-6}$, the protection ratio can be greatly reduced in comparison to the non-diversity system. So, assuming that only the same protection ratio as the non-diversity system is kept, it is shown that the system with diversity may get more interference level of N/I allowing from 9.0 to - 5.9 dB or from 6.0 to - 4.3 dB for the space or frequency diversity. In consequence, it is concluded that the diversity system is more robust or tolerable for interferences or fades, which may play an important role in overcoming N/I to some extent.

A Clock Regenerator using Two 2nd Order Sigma-Delta Modulators for Wide Range of Dividing Ratio

  • Oh, Seung-Wuk;Kim, Sang-Ho;Im, Sang-Soon;Ahn, Yong-Sung;Kang, Jin-Ku
    • JSTS:Journal of Semiconductor Technology and Science
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    • 제12권1호
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    • pp.10-17
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    • 2012
  • This paper presents a clock regenerator using two $2^{nd}$ order ${\sum}-{\Delta}$ (sigma-delta) modulators for wide range of dividing ratio as defined in HDMI standard. The proposed circuit adopts a fractional-N frequency synthesis architecture for PLL-based clock regeneration. By converting the integer and decimal part of the N and CTS values in HDMI format and processing separately at two different ${\sum}-{\Delta}$ modulators, the proposed circuit covers a very wide range of the dividing ratio as HDMI standard. The circuit is fabricated using 0.18 ${\mu}m$ CMOS and shows 13 mW power consumption with an on-chip loop filter implementation.

Correlationship of Vertical Distribution for Ammonia Ion, Nitrate Ion and Nitrifying Bacteria in a Fixed Bed Nitrifying Biofilm

  • Choi, Gi-Chung;Byun, Im-Gyu
    • 한국환경과학회지
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    • 제21권12호
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    • pp.1455-1462
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    • 2012
  • The vertical distributions of nitrifying bacteria in aerobic fixed biofilm were investigated to evaluate the relationship between nitrification performance and microbial community at different HRT. Fluorescent in situ hybridization (FISH) and portable ion selective microelectrode system were adopted to analyze microbial communities and ions profiles according to the biofilm depth. Cilia media packed MLE (Modified Ludzack-Ettinger) like reactor composed of anoxic, aerobic I/II was operated with synthetic wastewater having COD 200 mg/L and $NH_4{^+}$-N mg/L at HRT of 6 hrs and 4 hrs. Total biofilm thickness of aerobic I, II reactor at 4 hrs condition was over two times than that of 6 hrs condition due to the sufficient substrate supply at 4 hrs condition (6 hrs; aerobic I 380 ${\mu}m$ and II 400 ${\mu}m$, 4 hrs; aerobic I 830 ${\mu}m$ and II 1040 ${\mu}m$). As deepen the biofilm detection point, the ratio of ammonia oxidizing bacteria (AOB) was decreased while the ratio of nitrite oxidizing bacteria (NOB) was maintained similar distribution at both HRT condition. The ratio of AOB was higher at 4 hrs than 6 hrs condition and $NH_4{^+}$-N removal efficiency was also higher at 4 hrs with 89.2% than 65.4% of 6 hrs. However, the ratio of NOB was decreased when HRT was reduced from 6 hrs to 4 hrs and $NO_2{^-}$-N accumulation was observed at 4 hrs condition. Therefore, it is considered that insufficient HRT condition could supply sufficient substrate and enrichment of AOB in all depth of fixed biofilm but cause decrease of NOB and nitrite accumulation.