• Title/Summary/Keyword: Lower heat value

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Microstructure and Mechanical Properties of (Ti,Al)N Films Deposited by Ion Beam Sputtering (이온빔 스퍼터링에 의해 제조된 (Ti,Al)N 박막의 미세구조 및 기계적 특성)

  • Oh, Y.G.;Baeg, C.H.;Hong, J.W.;Wey, M.Y.;Kang, H.J.
    • Journal of the Korean Society for Heat Treatment
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    • v.16 no.6
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    • pp.329-334
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    • 2003
  • Microstructure and mechanical properties of $(Ti_{1-x}Alx)N$ films, Produced by the the Ion Beam Sputtering(IBS) method, were studied by changing the Ti, Al contents. The compositions of films determined by RBS were $(Ti_{0.75}Al_{0.25})N$, $(Ti_{0.61}Al_{0.39})N$ and $(Ti_{0.5}Al_{0.5})N$, and XPS binding energies of Ti2P, A12p and N1s shifted to higher energies than those of pure Ti, Al and N, which indicated that nitrides were formed. XRD results indicated that the NaCl structure for $$x{\leq_-}0.39$$ changed into amorphous structure at x=0.5. For films with $$x{\leq_-}0.39$$, the lattice parameter decreased in proportion to the Al content. Nanoindentation hardness value were above HV=3300 at Al content up to x=0.39. However, the hardness of films with x=0.5 abruptly decreased to HV=1800, and this lower hardness values were attributed to different crystal structure. Critical load(Lc) in scratch test showed 23N at x=0.25, 22N at x=0.39 and 22N at x=0.5, which indicated that films with different Al contents showed similar adhesion behavior.

Fabrication Characteristics of Slag Fiber by 4 Wheel System (4휠 시스템을 이용한 슬래그 섬유의 제조)

  • Song, Yeong-Hwan;Seong, Hwan-Goo;Park, Soo-Han;Wang, Xiaosong;Hur, Bo-Young
    • Journal of Korea Foundry Society
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    • v.26 no.5
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    • pp.222-226
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    • 2006
  • Steel making slag has gained a considerable attraction as one candidate of eco-materials in research fields for recycling resources. Thus, many researches have been performed but were limited to development of substitute for cement being used in the construction field. A little research work also has been done on development of higher value-added materials, including heat resistant and sound absorbing materials. For this reason, the present study were focused on macrostructure characterization of fabricated slag fibers which are applicable to heat resistant materials. The slag fibers were fabricated through a modified melt extraction method. The processing variables employed were the wheel speed and molten slag temperature. The synthesized fibers were characterized by optical microscope and scanning electron microscopy. It was found that the wheel speed of 1400 rpm generated better quality of mineral fibers in terms of the relative amount of shot, diameter and length. This was attributed to the relative extent of contact width between the flowing melt and the rotating wheel. The thickness of the slag fibers also were decreased with increasing the slag melt temperature due mainly to significant decrease in the viscosity of the slag melt. In addition, the lower melt temperature caused an increase in number of shots plus the mineral fibers.

Characteristics of Welds of Pure Titanium Plate Using Ultrasonic Attenuation (초음파 감쇠를 이용한 순 티타늄 판재의 용접부 특성)

  • Seon, Sang-Won;Yi, Won;Park, Hee-Dong;Hwang, Yeong-Tak
    • Journal of the Korean Society for Nondestructive Testing
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    • v.33 no.2
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    • pp.205-211
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    • 2013
  • This paper studies on mechanical properties, fractures, and ultrasonic characteristics of Pure Titanium welds using ultrasonic attenuation. Ti specimen was made by using AR purge gas. When the titanium weld specimen is fractured, Tensile tests were conducted in order to observe the ultrasonic signal changes. A scanning electron microscope(SEM) was used to observe changes in failure surface and an ultrasonic normal probe with the central frequency of 4 MHz was used to obtain ultrasonic signals. As a result, the value of the mechanical properties in the weld zone was lower than that in the base zone and heat affected zone(HAZ) from Ti. Also the grain size in the weld zone was bigger than that in the weld zone and HAZ from Ti. Ultrasonic signals using a RMS method presents correlation between envelope area and the tensile strength. Consequently, the ultrasonic method could be potential tool for integrity evaluation of the Ti weld zone.

Electrochemical Evaluation of Corrosion Property of Welding Zone of 304 Stainless Steel (304 스테인리스강의 용접부위의 부식특성에 관한 전기화학적 평가)

  • Moon, Kyung-Man;Kim, Yun-Hae;Kim, Jong-Do;Lee, Myung-Hoon;Kim, Jin-Gyeong
    • Journal of Ocean Engineering and Technology
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    • v.23 no.4
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    • pp.58-63
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    • 2009
  • Two kinds of welding methods are used for austenitic 304 stainless steel: laser welding and TIG welding. The difference in the corrosion characteristics of the welded zone between these two welding methods was investigated using electrochemical methods, such as corrosion potential measurements, polarization curves, cyclic voltammograms, etc. The Vickers hardnesses of all the welded zones (WM: Weld Metal, HAZ: Heat Affected Zone, BM: Base Metal) showed relatively higher values in the case of laser welding than for TIG welding. Furthermore, the corrosion current densities of all the welding zones showed lower values compared to TIG welding. In particular, the corrosion current density of the HAZ with TIG welding had the highest value of all the welding zones, which suggests that chromium depletion due to the formation of chromium carbide appears in the HAZ, which is in the range of the sensitization temperature. Thus, it can easily be corroded with a more active anode. Consequently, we found that the corrosion resistance of all of the welding zones for austenitic 304 stainless steel could apparently be improved by using Laser welding.

Air Temperature Differences in Areas with High-rise Buildings (초고층빌딩지역의 기온차)

  • Jin, Wen-Cheng;Lee, Kyoo-Seock
    • Journal of the Korean Institute of Landscape Architecture
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    • v.40 no.1
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    • pp.12-22
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    • 2012
  • In Seoul, skyscrapers are built in commercial zones known as residential-commercial complexes, which cause such environmental problems as urban heat islands(UHI) and air pollution. To investigate air temperature differences in areas near skyscrapers at Gangnam-gu, Seoul, South Korea, fixed air temperature observation and traverse observations were performed from March 16, 2008 to March 15, 2009. The annual mean air temperature at Tower Palace(TPL) was higher than that at Sookmyung Girls' High School(SMG) by $0.7^{\circ}C$, although the distance between the two observation positions is only 200m. The number of tropical nights at TPL was 13, while that at SMG was 5. The higher air temperature at TPL was due to a significantly lower sky view factor(SVF), which prevented long-wave radiation from emitting into the sky. The highest air temperature increases near TPL occurred on summer nights because of the high-electricity consumption value of $70.22Wh/m^2$ for the TPL block in August due to air conditioning for cooling. It is concluded that the warm air pocket centered on TPL.

Thermal properties of glass-ceramics made with zircon and diopside powders

  • Lee, Dayoung;Kang, Seunggu
    • Journal of Ceramic Processing Research
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    • v.19 no.6
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    • pp.504-508
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    • 2018
  • Diopside is a ceramic material with excellent physical and chemical properties. However, when it is applied as an LED packaging material, heat dissipation of the LED element is not sufficient due to its relatively lower thermal conductivity, which may cause degradation of the LED function. In this study, glass-ceramics based on a $ZrO_2-CaO-MgO-SiO_2$ system, in which diopside is the main crystal phase, were prepared by heat-treating the glass, which was composed of zircon ($ZrO_2-SiO_2$) powders and diopside ($CaO-MgO-2SiO_2$) powders. The possibility of using the glass-ceramics as a packaging material for LEDs was then investigated by analyzing the density, shrinkage, thermal conductivity, and phases generated according to the amount of zircon powder added. The density and shrinkage of specimens decreased slightly and then increased again with the amount of $ZrO_2-SiO_2$ added within a range of 0~0.38 mol. Even though the crystal phase of zircon does not appear in the $ZrO_2-CaO-MgO-SiO_2$ system, the glass containing 0.38 mol zircon powder showed the highest thermal conductivity, 1.85 W/mK, among the specimens fabricated in this study: this value was about 23% higher than that of pure diopside. It was found that the thermal conductivity of the glass-ceramics based on a $ZrO_2-CaO-MgO-SiO_2$ system was closely related to the density, but not to the phase type. Zirconia ($ZrO_2$), a component oxide of zircon, plays an important role in increasing the density of the specimen. Furthermore the thermal conductivity of glass-ceramics based on a $ZrO_2-CaO-MgO-SiO_2$ system showed a nearly linear relationship with thermal diffusivity.

Thermoelectric Performance Enhancement of Sintered Bi-Te Pellets by Rotary-type Atomic Layer Deposition (로터리형 원자층 증착법을 이용한 Bi-Te계 소결체의 열전 성능 개선)

  • Myeong Jun Jung;Ji Young Park;Su Min Eun;Byung Joon Choi
    • Journal of Powder Materials
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    • v.30 no.2
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    • pp.130-139
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    • 2023
  • Thermoelectric materials and devices are energy-harvesting devices that can effectively recycle waste heat into electricity. Thermoelectric power generation is widely used in factories, engines, and even in human bodies as they continuously generate heat. However, thermoelectric elements exhibit poor performance and low energy efficiency; research is being conducted to find new materials or improve the thermoelectric performance of existing materials, that is, by ensuring a high figure-of-merit (zT) value. For increasing zT, higher σ (electrical conductivity) and S (Seebeck coefficient) and a lower κ (thermal conductivity) are required. Here, interface engineering by atomic layer deposition (ALD) is used to increase zT of n-type BiTeSe (BTS) thermoelectric powders. ALD of the BTS powders is performed in a rotary-type ALD reactor, and 40 to 100 ALD cycles of ZnO thin films are conducted at 100℃. The physical and chemical properties and thermoelectric performance of the ALD-coated BTS powders and pellets are characterized. It is revealed that electrical conductivity and thermal conductivity are decoupled, and thus, zT of ALD-coated BTS pellets is increased by more than 60% compared to that of the uncoated BTS pellets. This result can be utilized in a novel method for improving the thermoelectric efficiency in materials processing.

Enhanced Electrical and Optical Properties of IWO Thin Films by Post-deposition Electron Beam Irradiation (증착 후 전자빔 조사에 따른 IWO 박막의 전기적, 광학적 특성 개선 효과)

  • Jae-Wook Choi;Sung-Bo Heo;Yeon-Hak Lee;Daeil Kim
    • Journal of the Korean Society for Heat Treatment
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    • v.36 no.5
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    • pp.298-302
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    • 2023
  • Transparent and conducting tungsten (W) doped indium oxide (IWO) thin films were deposited on the glass substrate by using RF magnetron sputtering and then electron irradiation was conducted to investigate the effect of electron irradiation on the optical and electrical properties of the films. The electron irradiated films showed three x-ray diffraction peaks of the In2O3 (222), (431) and (046) planes and the full width at half maximum values are decreased as increased electron irradiation energy. In the atomic force microscope analysis, the surface roughness of as deposited films was 1.70 nm, while the films electron irradiated at 700 eV, show a lower roughness of 1.28 nm. In this study, the figure of merit (FOM) of as deposited films is 2.07 × 10-3-1, while the films electron irradiated at 700 eV show the higher FOM value of 5.53 × 10-3-1. Thus, it is concluded that the post-deposition electron beam irradiation is the one of effective methods to enhance optical and electrical performance of IWO thin films.

Purchasing Behaviors and Needs for HMR according to the Food-Related Lifestyles of Baby Boomer Women (베이비부머 여성들의 식생활 라이프 스타일에 따른 HMR 구매행동 및 요구도)

  • Myung, Choonok;Nam, Haewon;Park, Youngsim
    • The Korean Journal of Food And Nutrition
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    • v.29 no.1
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    • pp.87-103
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    • 2016
  • The purpose of this study was to analyze the food-related lifestyle choices of female baby boomers and to investigate variables regarding home meal replacement (HMR) buying behaviors and future needs. This study was conducted on 358 female baby boomers 53 years of age living in Gyeonggi and near Seoul. Out of 420 distributed questionnaires, 358 were returned and used for analysis (response rate: 85.2%). As a result of cluster analysis, three groups were identified based on the food-related lifestyles : a value-seeking group, a convenience-seeking group, and a health-seeking group. Among the three groups, there were significant differences in two socio-demographic characteristics, education level (p<0.05) and regular exercise (p<0.01), and in several health- and food-related habits, type of breakfast (p<0.01), type of dinner (p<0.05), dinner details (p<0.05), frequency of eating out (p<0.05), and eating habits score (p<0.01). The health-seeking group was significantly more likely to purchase ready to cook (RTC) items (59.1%) than were the other groups (p<0.001). However, the ratio of HMR purchasing for the purpose of meal replacement (p<0.05) and an HMR purchasing frequency of more than twice a week (p<0.001) were significantly lower in the health-seeking group. Reasons for selecting HMR showed a similar tendency among groups in taste (26.2%), convenience (18.7%), price (16.9%), safety (15.3%) and type of food (14.3%). However, the satisfaction scores for hygiene and safety reported by the health-seeking group were significantly lower than those reported by the other groups. More than two-thirds of all respondents were willing to purchase HMR in the future, though there were significant differences according to group: convenience-seeking group, 73.1%, health-seeking group, 70.1%, and value-seeking group, 65.7% (p<0.05). Our results suggest that the number of baby boomers purchasing HMR products will continue to grow and baby boomers will want HMR products to be more healthy (52.0%), safe (28.5%) and delicious (13.4%). An emphasis on taste was high in the convenience-seeking group, whereas an emphasis on health was high in the health-seeking and value-seeking groups. In conclusion, this study shows various food-related lifestyles amongst female baby boomers and illustrates the need to develop HMR marketing strategies targeted to these different lifestyles.

Study on Crude Oil Productions and its practice with Rice hull As Treated in Various Supercritical Solvents on Application of Liquefaction Technology (Liquefaction technology 적용 시 왕겨를 이용한 Crude oil 생산 및 적용 연구)

  • Shin, JoungDu;Baek, Yi;Hong, Seung-Gil;Kwon, Soon-Ik;Park, Woo-Kyun;Park, SangWon
    • Journal of the Korea Organic Resources Recycling Association
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    • v.18 no.1
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    • pp.110-118
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    • 2010
  • Supercritical treatment of liquefaction technology for rice hull was investigated the biomass conversion rate and evaluated its crude oil in respect to feasibility of burner in order to heat the green house. The reaction was carried out in a 5,000 mL liquefaction system with dispenser and external electrical furnace. Raw materials (160 g) of rice hull and 3,000 mL of different solvents were fed into the reactor. It was observed that the maximum crude oil yield was about 84.4 % with 1-butanol. The calorific value of crude oil from ethanol solvent were 7,752 kcal/kg. Furthermore, in case study of co-solvent with ethanol and bulk-glycerol, it observed that more than 80 % of rice hull was decomposed and liquefied in its solvent at $315{\sim}326^{\circ}C$ for 30 min. For the development of applicable bio-fuel from rice hull, it was considered that its feasibility is necessary to be carried out for co-solvent soluble portions. Regarding to utilize the crude oil into burner as fuel, it was observed that its calorific value was lower at approximately 24 % than the diesel. Also, flame length from crude oil at lower temperature was decreasing due to incomplete incineration. The temperature of warm wind on the burner was maintained between 63 and $65^{\circ}C$, and the temperature of emission line was appeared at $350{\sim}380^{\circ}C$.