• Elastomers and Composites
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• v.35 no.4
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• pp.272-280
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• 2000

The experimental kinetics was analyzed for commercial rubbers such as NR, IR, BR, SBR 1500, and SBR 1700. Kinetic analysis for the commercial rubbers was performed using a thermogravimetric method, which the activation energies of NR obtained by Kissinger, Friedman, ana Ozawa's method were 195.0, 198.3, and 186.3 kJ/mol, respectively. whereas that of SBR 1500 were 246.4, 247.5, and 254.8 kJ/mol, respectively. It was shown that the yield of pyrolytic oil was generally increased with increasing the final temperature. Considering the effect of heating rate. it was found that the yield of pyrolytic oil was not consistent for each sample. The number average molecular weight of pyrolitic oil of SBR 1500 was in the range of 740-2486. The calorific value of SBR 1500 was 39-40 kJ/g, and it might be a considerable energy potential although it was lower than the conventional fuel such as kerosene, diesel, light fuel, and heavy fuel.

• Journal of the Korean Wood Science and Technology
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• v.42 no.4
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• pp.439-449
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• 2014

RPS (Renewable Portfolio Standard) has increased wood pellet demand dramatically in recent years in Korea where self-supply rate of wood pellet is not more than 10%. However global production capacity of wood pellet is prospected to be unable to meet the global demand after 2020. Therefore it is urgently needed to develop new sustainable biomass energy resources which can replace wood pellet at lower cost. As a result of this study EFB (empty fruit bunch) and MF (mesocarp fiber), the representative solid palm biomass, are estimated to be generated at the rate of 20 and 28 million tons per year (based on 10% moisture content) in Malaysia and Indonesia, respectively in 2012. Total annual generation rate of EFB and MF is estimated as 48 million tons per year only in Malaysia and Indonesia in 2012. With calorific value of over 90% of wood pellet EFB is expected to be a excellent biomass energy resource which can replace wood pellet. EFB can be utilized as fuel for power generation or industrial purpose. However EFB may not be a proper fuel for domestic and greenhouse heating because of its high ash content.

• Journal of the Korean Wood Science and Technology
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• v.46 no.5
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• pp.527-540
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• 2018

In this study, the characteristics of the white charcoal from charcoal kilns made for both charcoal production and thermotherapy and from the traditional charcoal kiln were compared and examined. A charcoal kiln for thermotherapy as a secondary purpose was made to minimize environmental problems such as fine dust and harmful gas generated from sealed charcoal kiln in consideration of comfort and safety. White Charcoal produced from the charcoal kiln for both charcoal production and thermotherapy had higher ash and volatile matter and lower fixed carbon than that from the traditional charcoal kiln. The density of the white charcoal produced from the charcoal kiln for both charcoal production and thermotherapy was slightly higher than that of the traditional one, but the equilibrium moisture content and pH were not significantly different. The calorific value, refinement degree, hardness and anatomical structure were not different between the two. It was concluded that the white charcoal produced from the advanced charcoal kiln for thermotherapy as a secondary purpose meets the quality certification standards of Korea Forest Research Institute.

• Fire Science and Engineering
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• v.33 no.1
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• pp.7-14
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• 2019

While wood pellets are often used as a fuel in thermoelectric power plants and firewood boilers, there is a risk of ignition temperature when strong wood pellets, which have a high calorific value, for prolonged periods of time. In this research study, the minimum auto ignition temperature and the ignition limitation temperature according to the change in flow rate depending on the size of the test vessel were calculated, and based on these temperatures, the apparent activation energy was calculated to predict the combustive properties of the material. The apparent activation energy was calculated to be 190.224 kJ/mol. The thicker the sample is storage in the vessel, the longer the ignition induction time was due to the increased difficulty in heat being transferred from the surface of the vessel to the middle section area of the vessel. For vessel of the same size, the higher the flow rate, the lower the auto ignition temperature was. It was also confirmed that increases in the size of the test vessel lowered the auto ignition temperature and increased the ignition induction time.

• Journal of Hydrogen and New Energy
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• v.34 no.6
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• pp.631-640
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• 2023

This study selected Eco-AZ91 MgH₂, which shows high enthalpy as a material for this purpose, as the basic material, and analyzed the change in characteristics by synthesizing TiNi as a catalyst to control the thermodynamic behavior of MgH₂. In addition, the catalyst dispersion technology using graphene oxide (GO) was studied to improve the high-temperature aggregation phenomenon of Ni catalyst and to secure a source technology that can properly disperse the catalyst. XRD, SEM, and BET analysis were conducted to analyze the metallurgical properties of the material, and TGA and DSC analysis were conducted to analyze the dehydrogenation temperature and calorific value, and the correlation between MgH₂, TiNi catalyst, and GO reforming catalyst was analyzed. As a result, the MgH₂-5 wt% TiNi at GO composite could lower the dehydrogenation temperature to 478-492 K due to the reduction of the catalyst aggregation phenomenon and the increase in the reaction specific surface area, and an experimental result for the catalyst dispersion technology by GO could be ensured.

• Journal of Korean Society of Environmental Engineers
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• v.33 no.10
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• pp.767-773
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• 2011

The purpose of this study was to investigate the possibility of an alternative fuel resource by incinerating a mix of combustible MSW (municipal solid waste) and offals after separating recyclable material at the MRF (material recovery facilities) location. We analyzed the physical and chemical properties including the 3-contents, the calorific value, and chemical compositions of the separation rejects in MRF, and compared the results with combustible MSW. Moreover, we experimented the trend of combustible properties and the concentration change of air pollutants at mixed incineration in the MSW incinerator. According to the results of the experiment, the separation rejects showed higher heating value (5,865 kcal/kg), and lower moisture and ash content than combustible MSW. Since we have incinerated MSW in the MSW incinerator mixing the offals at 30% and 50% respectively, we know that the change of the concentration of dust, $SO_2$, $NO_2$, and CO did not appear significant, and not exceed the pollutants emission regulation. But, considering the enhancement of the HCl emission concentration (max. 33.7 ppm) at the co-incineration of the 50% offals, we believe that the proper mixing ratio of the separation rejects would become within 30%.

• Clean Technology
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• v.27 no.1
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• pp.79-84
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• 2021

In this study, the waste activated carbon used in the painting process was filled into a cylindrical cartridge and the characteristics of desorption by low temperature gas were investigated. Adsorption and desorption experiments of toluene with activated carbon were conducted to determine the flow rate of desorption. In an experiment where desorption was performed while changing conditions at flow rates of 1, 2 and 4 ㎥ min-1, it was determined that 2 ㎥ min-1 was appropriate due to the high THC concentration and desorption time. In the early stage of the desorption of waste activated carbon, 2-butanone and MIBK (methyl isobutyl ketone) with a low boiling point were generated at a high rate in the gas component, and after that, the concentration of THC decreased and the BTX was desorbed at a high rate. The total calorific value of the gas component generated during the desorption of waste activated carbon was 316 kcal kg-1. From repeating the regeneration of waste activated carbon with toluene five times, it was observed that the iodine value and the specific surface area were relatively lower than that of new activated carbon. In the desorption experiment where two cylindrical cartridges were connected in series, the maximum THC concentration was about 470 ppm.

• Journal of the Korean Wood Science and Technology
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• v.45 no.3
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• pp.258-267
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• 2017

In this study, pitch pine (Pinus rigida, PIR) and Mongolian oak (Quercus mongolica, QUM) pellets were fabricated with bark or/and drying waste liquor (DWL) of larch (Larix kaempferi, LAK) as an additive. Based on the results of fuel characteristics of the pellets, optimal conditions for producing the high-quality pellets were provided. In the analysis of chemical composition, bark contained holocelluose and lignin of 90% and over. DWL had 0.1% solid assumed to sugars which are generated from the oven-drying of LAK logs. QUM showed high ash content (2.2%) by containing of bark in the sawdust. Bark and DWL of LAK had high ash content of 4% and over. Calorific values of all specimens and additives were higher than that of the $1^{st}$-grade standard of wood pellets designated by NIFOS (18.0 MJ/kg). PIR and QUM pellets were fabricated with additive of 2 wt% based on the solid weight of oven-dried sawdust using a piston-type flat-die pelletizer, and thus ash content and calorific value of the pellets did not affect by the use of additive. Durability of the pellets increased with the use of additive. Durabilties of pellets, which were fabricated with bark as an additive and DWL as a controller of moisture content for sawdust, did not differ from those of pellets without additives and were lower than those of pellets either with bark or DWL. However, use of both bark and DWL for the production of wood pellets might be favorable because it can make a profit from the collection process of DWL. Based on the results of fuel characteristics of the pellets, QUM and PIR pellets were produced by a flat-die pelletizer. Moisture content (MC), bulk density and durability of the pellets improved with the use of additive. Particularly, sawdust MC of 10% and the addition of bark or DWL for PIR as well as sawdust MC of 12% and the addition of bark for QUM might be optimal conditions for the production of high-quality pellets. Except for the ash content of QUM pellets, other properties of PIR and QUM pellets exceeded the $1^{st}$-grade wood pellets standards of NIFOS.

• Journal of the Korean Applied Science and Technology
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• v.33 no.4
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• pp.836-847
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• 2016

Water soluble oil was obtained by pyrolysis of biomass. The characteristics of emulsified fuel by mixing water soluble oil and MDO(marine diesel oil) and engine emissions were studied with engine dynamometer. Saw dust was used as biomass. Water soluble oil was obtained by condensing of water and carbon content with pyrolysis of saw dust at $500^{\circ}C$. Emulsion fuel was obtained by emulsifying MDO and water soluble oil by the water soluble oil mixing ratio of 10 to 20% of MDO. Exhaust gas detection was performed with engine dynamometer. While combustion, micro-explosion took place in the combustion chamber by water in the emulsion fuel, emulsion fuel scattered to micro particles and it caused to smoke reduction. The heat produced from water vapour reduce the temperature of internal combustion chamber and it caused to inhibition of NOx production. It can be verified by the lower exhaust temperature of each ND-13 mode using emulsion fuel than that of MDO fuel. The NOx and smoke concentration were reduced by increasing water soluble oil content in the emulsion fuel. The power also decreased according to the increment of water soluble oil content of emulsion fuel because emulsion fuel has low calorific value due to high water content than MDO. As a result of ND-13 mode test with 20% bio oil content, it was achieved 25% reduction in NOx production, 60% reduction in smoke density, and 15% reduction in power loss.

• Applied Chemistry for Engineering
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• v.23 no.6
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• pp.529-533
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• 2012

In this study, we compare various physicochemical properties of solvent extracted coals obtained at both mild and high temperature conditions. In order to characterize the extraction behavior, experiments were performed using a sub-bituminous coal (Kideco) and a polar solvent (N-methyl-2-pyrrolidinone, NMP), where the extraction temperature and the effect of solvent recycling were evaluated. As the extraction temperature increased up to $350^{\circ}C$, an extraction yield and a calorific value of the extracted coal increased, while an ash content of the extracted coal decreased. FT-IR results revealed that the surface of the coal extracted at $350^{\circ}C$ was found to contain more amide, aromatic ester, and aliphatic ether groups than that at the lower temperatures. The result of MALDI-TOF/MS analysis confirmed that the smaller molecules with 300~500 m/z were extracted at a mild condition, while the bigger molecules in the range of 500~1500 m/z were extracted at the high temperature.