• Title/Summary/Keyword: Low-temperature corrosion

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A study on the Properties of Composite Systems Using Polymer-Modified Mortar and Epoxy Resins for Waterproofing and Anti-Corrosion of Concrete Structures (시멘트 혼입 폴리머와 에폭시수지를 복합한 수처리 콘크리트구조물용 방수방식재료의 성능평가에 관한 연구)

  • Bae Kee-Sun;Jang Sung-Joo;Oh Sang-Keun
    • Journal of the Korea Concrete Institute
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    • v.17 no.1 s.85
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    • pp.3-10
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    • 2005
  • The purpose of this study is to investigate the properties of composite systems using polymer cement and epoxy resins for waterproofing and anti-corrosion to concrete structures such as water supply facilities and sewage-works. For the waterproofing and anti-corrosion of concrete structures, there can be required various properties such as absorption capacity and water permeability, adhesion and tensile strength, hair crack-resistance, impact-resistance, repeated low and high temperature test and chemical resistance, soundness for drinking water, soundness for drinking water and etc. In this study these engineering properties of composite systems using polymer-modified mortar and epoxy resins were examined and could be confirmed to satisfy the guidelines of KS. Especially, it was turn out that the adhesion properties was excellent and high crack-resistance up to 1.49 mm will be perform.

A Study on Waste Heat Recycling of Plasma Melting System (플라즈마 용융 공정시의 폐열 재활용 연구)

  • Kim, Seong-Jung
    • Journal of the Korea Organic Resources Recycling Association
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    • v.14 no.3
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    • pp.85-90
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    • 2006
  • The purpose of this research is to design an imitation boiler similar to the waste heat boiler installed on a plasma melting furnace in order to acquire a capability of a thermal design as to the circulation of heat and the discharge of noxious gas inside a boiler and to improve the efficiency of a waste heat boiler using the CFD (Computation Fluid Dynamics) program. The position of corrosion and the generation of a clinker inside a boiler due to temperature changes, combustion gas flows, and corrosive gases inside a boiler are examined to design the structure of an efficient boiler and recycle energy. As a result of this research, the boiler installed on a plasma melting furnace met the conditions of design by cooling the combustion gases discharged after the second combustion from an exhaust port, originally at 1,200 degrees Celsius, down to around 450 degrees Celsius. On the other hand, the circulation of corrosive gases (SOx and HCL) may lead to the generation of corrosion or a clinker in the upper and lower parts of an exhaust port more easily than any other parts of a boiler. Accordingly, the corrosion on the inside and outside walls of a boiler may result in a shortened lifespan of a boiler and an inability to recycle waste heat in an efficient manner. A prevention against corrosion at high and low temperatures needs to be considered in detail.

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Fatigue Life Analysis and Prediction of 316L Stainless Steel Under Low Cycle Fatigue Loading (저사이클 피로하중을 받는 316L 스테인리스강의 피로수명 분석 및 예측)

  • Oh, Hyeong;Myung, NohJun;Choi, Nak-Sam
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.40 no.12
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    • pp.1027-1035
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    • 2016
  • In this study, a strain-controlled fatigue test of widely-used 316L stainless steel with excellent corrosion resistance and mechanical properties was conducted, in order to assess its fatigue life. Low cycle fatigue behaviors were analyzed at room temperature, as a function of the strain amplitude and strain ratio. The material was hardened during the initial few cycles, and then was softened during the long post period, until failure occurred. The fatigue life decreased with increasing strain amplitude. Masing behavior in the hysteresis loop was shown under the low strain amplitude, whereas the high strain amplitude caused non-Masing behavior and reduced the mean stress. Low cycle fatigue life prediction based on the cyclic plastic energy dissipation theory, considering Masing and non-Masing effects, showed a good correlation with the experimental results.

Investigation on Size Distribution of Tungsten-based Alloy Particles with Solvent Viscosity During Ultrasonic Ball Milling Process (초음파 볼밀링 공정에 의한 용매 점도 특성에 따른 텅스텐계 합금 분쇄 거동)

  • Ryu, KeunHyuk;So, HyeongSub;Yun, JiSeok;Kim, InHo;Lee, Kun-Jae
    • Journal of Powder Materials
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    • v.26 no.3
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    • pp.201-207
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    • 2019
  • Tungsten heavy alloys (W-Ni-Fe) play an important role in various industries because of their excellent mechanical properties, such as the excellent hardness of tungsten, low thermal expansion, corrosion resistance of nickel, and ductility of iron. In tungsten heavy alloys, tungsten nanoparticles allow the relatively low-temperature molding of high-melting-point tungsten and can improve densification. In this study, to improve the densification of tungsten heavy alloy, nanoparticles are manufactured by ultrasonic milling of metal oxide. The physical properties of the metal oxide and the solvent viscosity are selected as the main parameters. When the density is low and the Mohs hardness is high, the particle size distribution is relatively high. When the density is high and the Mohs hardness is low, the particle size distribution is relatively low. Additionally, the average particle size tends to decrease with increasing viscosity. Metal oxides prepared by ultrasonic milling in high-viscosity solvent show an average particle size of less than 300 nm based on the dynamic light scattering and scanning electron microscopy analysis. The effects of the physical properties of the metal oxide and the solvent viscosity on the pulverization are analyzed experimentally.

Fatigue Characteristics and FEM Analysis of $18\%$Ni(200) Maraging Steel (18Ni 마르에이징강의 피로특성 및 유한요소해석)

  • Choi Byung Ki;Jang Kyeung Cheun
    • Transactions of the Korean Society of Machine Tool Engineers
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    • v.14 no.2
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    • pp.75-82
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    • 2005
  • Recently the needs of high reliable substances of high strength and high ductility are gradually increased with the development of aerospace industry. The characteristics of maraging steel has high ductililty, formability, corrosion resistant and high temperature strength and is easy to fabricate, weld and treat with heat, and maintain an invariable size even after heat treatment. e steels are furnished in the solution annealed condition and they achieve full properties through martensitic precipitation aging a relatively simple, low temperature heat treatment. As is true of the heat treating procedures, aging is a time/temperature dependent reaction. Therefore, the objective of this stud)'was consideration of fatigue characteristics according as Nb(niobium) content and time/temperature of heat treatment change. Also the stress analysis, fatigue lift, and stress intensity factor were compared with experiment results and FEA(finite element analysis) result. The maximum ftresses of)( Y, and Z axis direction showed about $2.12\times$10$^{2}$MPa, $4.40\times$10$^{2}$MPa and $1.32\times$10$^{2}$MPa respectively. The fatigue lives showed about $7\%$ lower FEA result than experiment result showing almost invariable error every analyzed cycle. Stress intensity factor of the FEA result was lower about $3.5~ 10\%$ than that of the experiment result showing that the longer fatigue crack ten添 the hi인or error. It considered that the cause for the difference was the modeled crack tip having always the same shape and condition regardless of the crack growth.

A Study on Material Degradation Evaluation of 9Cr1MoVNb Steel by Micromechanics Test Method (미소역학 시험기법에 의한 9Cr1MoVNb강의 열화도 평가)

  • Baek, Seung-Se;Na, Sung-Hoon;Yoo, Hyun-Chul;Lee, Song-In;Ahn, Haeng-Gun;Yu, Hyo-Sun
    • Proceedings of the KSME Conference
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    • 2000.11a
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    • pp.105-110
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    • 2000
  • The Micromechanics test is new test method which uses comparatively smaller specimen than that required in conventional material tests. There are several methods, such as small-specimen creep test, the continuous indentation test, and small punch(SP) test. Among them, the small punch(SP) test method has been applied to many evaluation fields, such as a ductile-brittle transition temperature, stress corrosion cracking, hydrogen embrittlement, and fracture properties of advanced materials like FGM or MMC. In this study, the small punch(SP) test is performed to evaluate the mechanical properties at high/low temperature from $-196^{\circ}C$ to $650^{\circ}C$ and the material degradation for virgin and aged materials of 9Cr1MoVNb steel which has been recently developed. The ${\Delta}P/{\Delta}{\delta}$ parameter defined a slope in plastic membrane stretching region of SP load-displacement curve decreases according to the increase of specimen temperature, and that of aged materials is higher than the virgin material in all test temperatures. And the material degradation degrees of aged materials with $630^{\circ}C$ -500hrs and $630^{\circ}C$ -1000hrs are $36^{\circ}C$ and $38^{\circ}C$ respectively. These behaviors are good consistent with the results of hardness($H_v$) and maximum displacement(${\delta}_{max}$).

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A Study on the high Temperature Properties of the Graded Thermal Barrier Coatings by APS and PAS (APS법으로 제조된 열장벽 피막과 PAS법으로 제조된 열장벽 성형체의 고온 물성에 관한 연구)

  • 강현욱;권현옥;한주철;송요승;홍상희;허성강;김선화
    • Journal of the Korean institute of surface engineering
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    • v.32 no.2
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    • pp.144-156
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    • 1999
  • Thermal Barrier Coating with Functional Gradient Materials (FGM-TBC) can play an important role to protect the parts from harmful environments in high temperatures such as oxidation, corrosion, and wear and to improve the efficiency of aircraft engine by lowering the surface temperature on turbine blade. FGM-TBC can increase the life spans of product and improve the operating properties. Therfore, in this study the evaluations of mechanical and thermal properties of FGM-TBC such as fatigue, oxidation and wear-resistance at high temperatures have been conducted. The samples of both the TBC with 2, 3, 5 layers (YSZ/NiCrAlY) to be produced by Air Plasma Spray method (APS) and the bulk TBC with 6 layers to be produced by Plasma Assisted Sintering method (PAS) were used. Furthermore, residual stress, bond strength, and thermal conductivity were evaluated. The average thickness of the APS was 500$\mu\textrm{m}$ to 600$\mu\textrm{m}$ and the average thickness of the PAS was 3mm. The hardness number of the top layer of APS was 750 Hv to 810Hv and that of PAS was 950 Hv to 1440Hv. The $ZrO_2$ coating layer of APS was composed of tetragonal structure after spraying as the result of XRD analysis. As shown in the results of the high temperature wear test, the 3 layer coating of APS had the best wear resistance at $800^{\circ}C$ and the 5 layer coating of APS had the best wear resistance at $600^{\circ}C$. But, these coatings had the tendency of the low-temperature softening at $300^{\circ}C$. The main mechanism of wear was the adhesive wear and the friction coefficient of coatings was increased as increasing the test temperatures. A s results of thermal conductivity test, the ${\Delta}T$ of the APS coating was increased as number of layer and the range of thermal conductivity of the PAS was $800^{\circ}C$ to $1000^{\circ}C$.

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Growth of calcite$(CaCO_3)$ single crystal by hydrothermal method (수열법에 의한 calcite$(CaCO_3)$ 단결정 성장)

  • Lee, Yeong-Guk;Yu, Yeong-Mun;Park, Ro-Hak
    • Korean Journal of Crystallography
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    • v.7 no.1
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    • pp.30-35
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    • 1996
  • Calcite(CaCO3) single crystals were grown hydrothermally and transmittance of as grown crystals was measured. Instead of platinium, teflon was lined onto the wall of autoclave to prevent the corrosion of autoclave wall by acidic NH4Cl solution. Spontaneous nucleation and growth of calcite crystal on teflon was reduced considerably by addition of NaCl and /or CH3COOH and applying low temperature gradient. When the temperature gradient exceeded to a few degrees from the critical temperature gradient(6-7℃), spontaneous nucleation and growth was rapidly increased in any hydrothermal solutions. Precise temperature control is thought to be the most important factor for the growth of calcite single crystal by hydrothermal technique. As grown calcite single crytal showed high transmittance compared to natural one by UV-visible analysis.

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Formation of Fe Aluminide Multilayered Sheet by Self-Propagating High-Temperature Synthesis and Diffusion Annealing (고온자전반응합성과 확산 열처리를 이용한 FeAl계 금속간화합물 복합판재의 제조)

  • Kim, Yeon-Wook;Yun, Young-Mok
    • Korean Journal of Materials Research
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    • v.18 no.3
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    • pp.153-158
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    • 2008
  • Fe-aluminides have the potential to replace many types of stainless steels that are currently used in structural applications. Once commercialized, it is expected that they will be twice as strong as stainless steels with higher corrosion resistance at high temperatures, while their average production cost will be approximately 10% of that of stainless steels. Self-propagating, high-temperature Synthesis (SHS) has been used to produce intermetallic and ceramic compounds from reactions between elemental constituents. The driving force for the SHS is the high thermodynamic stability during the formation of the intermetallic compound. Therefore, the advantages of the SHS method include a higher purity of the products, low energy requirements and the relative simplicity of the process. In this work, a Fe-aluminide intermetallic compound was formed from high-purity elemental Fe and Al foils via a SHS reaction in a hot press. The formation of iron aluminides at the interface between the Fe and Al foil was observed to be controlled by the temperature, pressure and heating rate. Particularly, the heating rate plays the most important role in the formation of the intermetallic compound during the SHS reaction. According to a DSC analysis, a SHS reaction appeared at two different temperatures below and above the metaling point of Al. It was also observed that the SHS reaction temperatures increased as the heating rate increased. A fully dense, well-bonded intermetallic composite sheet with a thickness of $700\;{\mu}m$ was formed by a heat treatment at $665^{\circ}C$ for 15 hours after a SHS reaction of alternatively layered 10 Fe and 9 Al foils. The phases and microstructures of the intermetallic composite sheets were confirmed by EPMA and XRD analyses.

Study on the effect of long-term high temperature irradiation on TRISO fuel

  • Shaimerdenov, Asset;Gizatulin, Shamil;Dyussambayev, Daulet;Askerbekov, Saulet;Ueta, Shohei;Aihara, Jun;Shibata, Taiju;Sakaba, Nariaki
    • Nuclear Engineering and Technology
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    • v.54 no.8
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    • pp.2792-2800
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    • 2022
  • In the core of the WWR-K reactor, a long-term irradiation of tristructural isotopic (TRISO)-coated fuel particles (CFPs) with a UO2 kernel was carried out under high-temperature gas-cooled reactor (HTGR)-like operating conditions. The temperature of this TRISO fuel during irradiation varied in the range of 950-1100 ℃. A fission per initial metal atom (FIMA) of uranium burnup of 9.9% was reached. The release of gaseous fission products was measured in-pile. The release-to-birth ratio (R/B) for the fission product isotopes was calculated. Aspects of fuel safety while achieving deep fuel burnup are important and relevant, including maintaining the integrity of the fuel coatings. The main mechanisms of fuel failure are kernel migration, silicon carbide corrosion by palladium, and gas pressure increase inside the CFP. The formation of gaseous fission products and carbon monoxide leads to an increase in the internal pressure in the CFP, which is a dominant failure mechanism of the coatings under this level of burnup. Irradiated fuel compacts were subjected to electric dissociation to isolate the CFPs from the fuel compacts. In addition, nondestructive methods, such as X-ray radiography and gamma spectrometry, were used. The predicted R/B ratio was evaluated using the fission gas release model developed in the high-temperature test reactor (HTTR) project. In the model, both the through-coatings of failed CFPs and as-fabricated uranium contamination were assumed to be sources of the fission gas. The obtained R/B ratio for gaseous fission products allows the finalization and validation of the model for the release of fission products from the CFPs and fuel compacts. The success of the integrity of TRISO fuel irradiated at approximately 9.9% FIMA was demonstrated. A low fuel failure fraction and R/B ratios indicated good performance and reliability of the studied TRISO fuel.