• Journal of Welding and Joining
• /
• v.33 no.5
• /
• pp.31-34
• /
• 2015

Microstructure and tensile property in the weld heat-affected zone (HAZ) of austenitic Fe-Mn-Al-C low density steels were investigated through transmission electron microscopy analysis and tensile tests. The HAZ samples were prepared using Gleeble simulation with high heat input welding condition of 300 kJ/cm, and the HAZ peak temperature of $1200^{\circ}C$ was determined from differential scanning calorimetry (DSC) test. The strain- stress responses of base steels showed that the addition of V improved the tensile and yield strength by grain refinement and precipitation strengthening. Tensile strength and elongation decreased in the weld HAZ as compared to the base steel, due to grain growth, while V-added steel had a higher HAZ strength as compared than V-free steel.

• Korean Journal of Metals and Materials
• /
• v.47 no.9
• /
• pp.533-541
• /
• 2009

Materials used for a reactor pressure vessel(RPV) are required high strength and toughness, which determine the safety margin and life of a reactor. Ni-Mo-Cr low alloy steel shows better mechanical properties than existing RPV steels due to higher Ni and Cr contents compared to the existing RPV steels. The present study focuses on effects of Ni, Cr contents on the cleavage fracture toughness of Ni-Mo-Cr low alloy steels in the transition temperature region. The fracture toughness was characterized by a 3-point bend test of precracked Charpy V-notch(PCVN) specimens based on ASTM E1921-08. The test results indicated that the fracture toughness was considerably improved with an increase of Ni and Cr contents. Especially, control of Cr content was more effective in improving fracture toughness than manipulating Ni content, though Charpy impact toughness was changed more extensively by adjusting Ni content. These differences between changes in the fracture toughness and that in the impact toughness were derived from microstructural features, such as martensite lath size and carbide precipitation behavior.

• Corrosion Science and Technology
• /
• v.4 no.6
• /
• pp.236-241
• /
• 2005

Hydrogen induced cracking (HIC) is one of the hydrogen degradation phenomena of linepipe steels caused by $H_2S$ gas in the crude oil or natural gas. However, NACE TM0284-96 standard HIC test method is hard to satisfy the steel requirements for sour service application since it uses more severe environmental conditions than actual conditions. Therefore, in order to use steels effectively, it is required to evaluate HIC resistance of steels in the practical range of environmental severity. In this study, HIC resistance of two high strength low alloy (HSLA) steels being used as line pipe steels was evaluated in various test solutions with different $H_2S$ pressures and pH values. The results showed that the key parameter affecting crack area ratio (CAR) is $H_2S$ partial pressure of test solution when the pH value of test solution is not over 4. Hydrogen diffusivity was not a constant value, but it was rather affected by the hydrogen ion concentration (pH value) in the solution.

• Proceedings of the KSME Conference
• /
• 2000.11b
• /
• pp.67-76
• /
• 2000

Cr-Mo low alloy steels have been used for a long time for pressure vessel due to its excellent corrosion resistance, high temperature strength and toughness. The paper reviewed the latest trends on material development and some problems on Cr-Mo low alloy steel for pressure vessel, such as elevated temperature strength, hardenability, synergetic effect between temper and hydrogen embrittlement, hydrogen attack and hydrogen induced disbonding of overlay weld-cladding.

• Transactions of Materials Processing
• /
• v.14 no.3 s.75
• /
• pp.215-223
• /
• 2005

A numerical analysis program is developed by FDM scheme for the prediction of microstructural transformation during heat treatment of steels. In this study, multi-phase model was used fur description of diffusional austenite transformations in low-alloy hypoeutectoid steels during cooling after austenitization. A fundamental property of the model consisting of coupled differential equations is that by taking into account the rate of austenite grain growth, it permits the prediction of the progress of ferrite, pearlite, and bainite transformations simultaneously during quenching and estimate the amount of martensite also by using K-M eq. In order to simulate the microstructural evolution during tempering process, another Avrami-type eq. was adopted and method for vickers hardness prediction was also proposed. To verify the developed program, the calculated results are compared with experimental ones of casting product. Based on these results, newly designed heat treatment process is proposed and it was proved to be effective for industry.

• Proceedings of the KSME Conference
• /
• 2000.11a
• /
• pp.67-76
• /
• 2000

Cr-Mo low alloy steels have been used for a long time for pressure vessel due to its excellent corrosion resistance, high temperature strength and toughness. The paper reviewed the latest trends on material development and some problems on Cr-Mo low alloy steel for pressure vessel, such as elevated temperature strength, hardenability, synergetic effect between temper and hydrogen embrittlement, hydrogen attack and hydrogen induced disbonding of overlay weld-cladding.

• Journal of the Korean Society for Heat Treatment
• /
• v.32 no.1
• /
• pp.17-28
• /
• 2019

Jominy hardenability curves of low alloy steel containing less than 5 wt.% of alloying elements in total were calculated by applying Scheil's rule of additivity to pre-calculated isothermal transformation curve. Isothermal transformation curve for each phase in steel was approximated as a simple mathematical equation by using Kirkaldy's approach and all coefficients in the equation were estimated from experimental temperature-time-transformation (TTT) and/or continuous cooling transformation (CCT) data in the literature. Then jominy test with simple boundary conditions was performed in computer by applying the finite difference scheme. The resultant cooling curves at each location along a longitudinal direction of Jominy bar were applied to calculate phase fractions as well as mechanical properties such as micro Vickers hardness. The simulated results were compared with experimental CCT data and Jominy curves in the literature.

• Corrosion Science and Technology
• /
• v.5 no.6
• /
• pp.189-195
• /
• 2006

Effects of tungsten (W) on the precipitation kinetics of secondary phases and the associated resistance to pitting corrosion of 25%Cr duplex stainless steels were investigated through microstructural and electrochemical noise analyses. With the partial substitution of W for Mo in duplex stainless steel, the potential and current noises of the alloy were significantly decreased in chloride solution due to retardation of the ${\sigma}$ phase precipitation. The preferential precipitation of the $\chi$ phase in the W-containing alloy during the early period of aging contributed to retarding the precipitation of the $\sigma$ phase by depleting W and Mo along grain boundaries. In addition, the retardation of the nucleation and growth of the $\sigma$ phase in the W-containing alloy appears to be attributed to the inherently low diffusivity of W compared with that of Mo.

• Proceedings of the KWS Conference
• /
• 1994.05a
• /
• pp.39-43
• /
• 1994

The effects of ageing treatment on the mechanical properties of two Cu-bearing HSLA(High Strength Low Alloy) steels, HSLA-A and HSLA-B ,were studied by means of SEM, TEM, tensile, charpy impact and hardness tests. These steels showed excellent combination in strength and toughness at an ageing of $650^{\circ}C$ by the precipitation of $\varepsilon$-Cu and low carbon alloying. The peak strength was achieved at an ageing of 50$0^{\circ}C$ in both steels, while the impact energy was very low in this peak strength. With ageing temperature above this temperature, strength was decreased whereas impact energy increased. A marked increase in hardness above 675$^{\circ}C$ was associated with the formation of “M-A constituents” which forms during cooling from austenite-ferrite two phase region. The impact transition temperature of HSLA-A and HSLA-B steels were -l$25^{\circ}C$ and -145$^{\circ}C$, respectively.

• Applied Microscopy
• /
• v.48 no.4
• /
• pp.117-121
• /
• 2018

The multiple length scale analysis of previously designed Fe-Mn-Al-C based low-density model alloys reveals the difference in ordered ${\kappa}-carbide$, $(Fe,Mn)_3AlC_x$, between Fe-25Mn-16Al-5.2C (at%) alloy and Fe-3Mn-10Al-1.2C (at%) alloy. For the former alloy composition consisting of fully austenite grains, ${\kappa}-carbide$ showed majorly cuboidal and minorly pancake morphology and its chemical composition was not changed through aging for 24 h and 168 h at $600^{\circ}C$. Meanwhile, for the isothermally annealed ferritic alloy system for 1 hr at 500 and $600^{\circ}C$, the dramatic change in the chemical composition of needle-shape ${\kappa}-carbide$, $(Fe,Mn)_3(Fe,Al)C_x$, was found. Here we address that the compositional fluctuations in the vicinity of the carbides are significantly controlled by abutting phase, either austenite or ferrite. Namely, the cooperative ordering of carbon and Al is an important factor contributing to carbide formation in the high-Mn and high-Al alloyed austenitic steel, while the carbon and Mn for the low-Mn and high Al alloyed ferritic steel.