• 제목/요약/키워드: Low temperature synthesis

검색결과 605건 처리시간 0.037초

저압 초음파 분무 공정을 이용한 γ-Fe2O3 나노입자의 합성 (Synthesis of γ-Fe2O3 Nanoparticles by Low-pressure Ultrasonic Spraying)

  • 이창우;김순길;좌용호;이재성
    • 한국분말재료학회지
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    • 제14권1호
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    • pp.19-25
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    • 2007
  • This study was focused on the optimization of low-pressure ultrasonic spraying process for synthesis of pure ${\gamma}-Fe_2O_3$ nanoparticles. As process variables, pressure in the reactor, precursor concentration, and reaction temperature were changed in order to control the chemical and microstructural properties of iron oxide nanoparticles including crystal phase, mean particle size and particle size distribution. X-ray diffraction (XRD) and transmission electron microscopy (TEM) studies revealed that pure ${\gamma}-Fe_2O_3$ nanoparticles with narrow particle size distribution of 5-15 nm were successfully synthesized from iron pentacarbonyl ($Fe(CO)_{5}$) in hexane under 30 mbar with precursor concentrations of 0.1M and 0.2M, at temperatures over $800^{\circ}C$. Also magnetic properties, coercivity ($H_c$) and saturation magnetization ($M_s$) were reported in terms of the microstructure of particles based on the results from vibration sampling magnetometer (VSM).

Synthesis of $Ba(Mg_{1/3}Ta_{2/3})O_3$ Nanopowders by Glycothermal Process

  • Badrakh, Amar;Cho, Hong-Chan;Lim, Dae-Young
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2009년도 하계학술대회 논문집
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    • pp.167-168
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    • 2009
  • Phase pure barium magnesium tantalate $Ba(Mg_{1/3}Ta_{2/3})O_3$(BMT) nanopowders were synthesized at temperature as low as $220^{\circ}C$ through glycothermal reaction by using $Ba(OH)_2{\cdot}8H_2O$, $Mg(NO_3){\cdot}6H_2O$, and $TaCl_5$ as precursors and 1,4-butandiol as solvent. XRD, SEM, and TGA data support that glycothermal processing method provides a simple low temperature route for producing fine grained BMT nanopowders without alkaline mineralizers. BMT nanopowders synthesized at $220^{\circ}C$ showed more homogenous with rounded morphologies.

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저온소결 세라믹기판용 Cordierite계 결정화 유리의 합성 및 특성조사에 관한 연구;(III) Tape casting에 의한 기판 제조 (Synthesis and Characterization of Cordierite Glass-Ceramics for Low Firing Temperature Substrate; (III) Fabrication of substrates by tape casting process)

  • 김병호;문성훈;이근헌;임대순
    • 한국세라믹학회지
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    • 제30권10호
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    • pp.845-851
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    • 1993
  • Low firing temperature substrate were synthesized through tape casting and sintering of glass with cordierite composition and then their properties were investigated. Even though the dielectric properties and XRD patterns of substrates, obtained by tape casting and sintering at 900~100$0^{\circ}C$ for various periods, were similar to those of substrates obtained by dry pressing, the sinterability was enhanced. The substrates were thin and the size was 0.6$\times$50$\times$50mm. From the results of dielectric properties, the sinterability and X-ray diffraction pattern, the proper condition for cofiring process with conductor, Cu, was 90$0^{\circ}C$ for 1h. The properties of the substrate are as follows; the dielectric constant was 5.31(at 1MHz), the dissipation factor was 0.0028, the apparent porosity was 0.28% and the main crystalline phase was $\alpha$-cordierite.

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저온 photoluminescence 스펙트럼 및 형광체 합성에 관한 연구 (A Study on Phosphor Synthetic and Low Temperature Photoluminescence Spectrum)

  • 김수용
    • 조명전기설비학회논문지
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    • 제24권4호
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    • pp.10-16
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    • 2010
  • 본 논문에서는 ZnO와 $Ga_2O_3$ 분말을 1 : 1의 mole비로 혼합하고 여기에 Mn을 첨가하여 Ar 주입 상태와 진공 상태에서 조성된 $ZnGa_2O_4$ : Mn을 합성하였다. 제작된 $ZnGa_2O_4$ : Mn의 발광 스펙트럼 관찰을 하여 산소의 성분 변화가 발광 특성에 미치는 영향을 설명하였다. 또한 저온의 Photoluminescence(PL) 스펙트럼으로부터 Mn의 site symmetry가 발광 스펙트럼에 미치는 영향을 설명하였다.

GaOOH로부터 합성된 GaN 분말의 구조적, 광학적 특성 (Structural and Optical Properties of GaN Powders Synthesized from GaOOH)

  • 조성룡;이종원;박인용;김선태
    • 한국재료학회지
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    • 제12권6호
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    • pp.476-481
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    • 2002
  • In this work, we report on the synthesis of the GaN powders from gallium oxide hydroxide (GaOOH) powders and on the structural and optical properties of them. Simple heat treatment of GaOOH in the flow of $NH_3$ gas leads to the formation of submicron hexagonal GaN powders even at the low reaction temperature of $800^{\circ}C$. XRD measurements show that the powders obtained are the single phase GaN. EDS, FTIR, and PL measurements indicate the oxygen-associated characteristics. It is shown from the low temperature PL measurement on GaN powders synthesized at $1000^{\circ}C$ that the shallow donor-acceptor recombination induced emission is more intense than the near band-edge excitonic emission.

temperature synthesis and ferroelectric properties of (117)-oriented $Bi_{3.25}La_{0.75}Ti_3O_{12}$ thin films on $LaNiO_3$ electrodes

  • Kim, Kyoung-Tae;Kim, Chang-Il
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2004년도 추계학술대회 논문집 Vol.17
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    • pp.264-267
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    • 2004
  • [ $Bi_{3.25}La_{0.75}Ti_3O_{12}$ ] (BLT) thin films were prepared by using metal organic decomposition method onto the $LaNiO_3$ (LNO) bottom electrode. Both the structure and morphology of the films were analyzed by x-ray diffraction (XRD) and atomic force microscope (AFM). Even at low temperatures ranging from 450 to $650^{\circ}C$, the BLT thinfilms were successfully deposited on LNO bottom electrode and exhibited (117) orientation. The BLT thin films annealed as low as $600^{\circ}C$ showed excellent ferroelectricity, higher remanent polarization and no significant degradation of switching charge at least up to $5{\times}10^9$ switching cycles at a frequency of 100 kHz and 5 V. For the annealing temperature of $600^{\circ}C$, the remanent polarization Pr and coercive field were $23.5\;C/cm^2$ and 120 kV/cm, respectively.

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High performance organic gate dielectrics for solution processible organic and inorganic thin-film transitors

  • 가재원;장광석;이미혜
    • 한국재료학회:학술대회논문집
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    • 한국재료학회 2012년도 춘계학술발표대회
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    • pp.64.1-64.1
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    • 2012
  • Next generation displays such as high performance LCD, AMOLED, flexible display and transparent display require specific TFT back-planes. For high performance TFT back-planes, low temperature poly silicon (LTPS), and metal-oxide semiconductors are studied. Flexible TFT backplanes require low temperature processible organic semiconductors. Not only development of active semiconducting materials but also design and synthesis of semiconductor corresponding gate dielectric materials are important issues in those display back-planes. In this study, we investigate the high heat resistant polymeric gate dielectric materials for organic TFT and inorganic TFT with good insulating properties and processing chemical resistance. We also controlled and optimized surface energy and morphology of gate dielectric layers for direct printing process with solution processible organic and inorganic semiconductors.

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Cloning and Expression of a cDNA AAPT3 Encoding Aminoalcoholphosphotransferase Isoform from Chinese Cabbage

  • Kim, Kwang-Soo;Park, Jong-Ho;Cho, Sung-Ho
    • Animal cells and systems
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    • 제8권2호
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    • pp.105-109
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    • 2004
  • Aminoalcoholphosphotransferase catalyzes the synthesis of phosphatidylcholine and phosphatidylethanolamine from diacylglycerol plus a CDP-aminoalcohol such as CDP-choline or CDP-ethanolamine. Previously we suggested the presence of possible isoforms of this enzyme from Chinese cabbage roots and now report the cDNA cloning and expression analysis of AAPT3 encoding a third isoform of aminoalcoholphosphotransferase (AAPT3). AAPT3 contains an open reading frame of 1,176 bp coding for a protein of 392 amino acids. It shares 96 and 95% identity with Chinese cabbage AAPT1 and AAPT2, respectively, at the deduced amino acid level. The results from reverse transcriptase-polymerase chain reaction analysis indicate that expression of AAPT3 is up-regulated by low temperature as well as AAPT1 and AAPT2.

Phase Transformation Behavior of Bi2O3-ZnO-Nb2O5 Ceramics sintered at low Temperature

  • Shiao, Fu-Thang;Ke, Han-Chou;Lee, Ying-Chieh
    • 한국분말야금학회:학술대회논문집
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    • 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part2
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    • pp.1232-1233
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    • 2006
  • To co-fire with commercial LTCC (Low Temperature Co-fired Ceramic) materials at $850^{\circ}C{\sim}880^{\circ}C$, different contents of $B_2O_3$ were added to the $Bi_2O_3-ZnO-Nb_2O_5$ (BZN) ceramics. According to the test results, the cubic phase of BZN was transformed into orthorhombic in all the test materials. $BiNbO_4$ phase was formed in test materials with $2{\sim}5wt%$ of $B_2O_3$ addition. The phase transformation of cubic BZN was controlled during the synthesis process with excess ZnO content. The Cubic and orthorhombic phases of BZN could coexist and be sintered densely at $850^{\circ}C/2hr$.

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Synthesis of Carbon Nanotubes by Using Inductively Coupled Plasma Chemical Vapor Deposition at Low Temperature

  • Kim, Young-Rae;Jang, In-Goo;Cho, Hyun-Jin;Jeon, Hong-Jun;Cho, Jung-Keun;Hwang, Ho-Soo;Kong, Byung-Yun;Lee, Nae-Sung
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2007년도 7th International Meeting on Information Display 제7권1호
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    • pp.768-771
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    • 2007
  • Carbon nanotubes (CNTs) were synthesized by inductively coupled plasma CVD at $450^{\circ}C$. CNTs were grown on the 1-nm-thick Fe-Ni-Co with $C_2H_2$ and $H_2$ at different pressures and plasma powers. CNTs were grown longer in height as the $H_{\alpha}/CH$ ratios became lower by decreasing plasma powers and increasing growth pressures.

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