• International Journal of Safety
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• v.1 no.1
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• pp.58-61
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• 2002

A preparation method of cobalt supported alumina catalyst for a emergency escape mask cartridge has been studied. Catalysts were prepared by incipient wetness impregnation method using pre-shaped $\gamma$=alumina powders of 70-100 mesh. The catalyst was tested in a continuous-flow reactor system and characterized by elemental analysis, BET and TGA-DTA techniques. Cobalt shows higher activity than platinum or nickel for carbon monoxide oxidation at room temperature. Optimum loading amount of cobalt was 10 wt.% for CO oxidation and the reaction activity increases gradually with the increase of calcination temperature up to $450^{\circ}C.

• Journal of Korean Society for Atmospheric Environment
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• v.6 no.1
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• pp.57-72
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• 1990

The oxidation of carbon monoxide on a catalyst, $LaSrNiCoO_3$ was investigatigated with a plug flow system. Kinetic quantities such as reaction-rate, reaction order and Arhenius-parameters at various reactor temperature from 200$^\circ$C to 300$^\circ$C were determined. Also, the optimum condition for the oxidation of carbon monoxide with this catalyst was determined and are as follows. Partial pressure of oxigen ; 428mmHg Partial pressure of carbon monoxide ; 332mmHg Mixed moral ratio of oxigen and Carbon monoxide ; 1.3 : 1 Total gas flow ; 224ml/min Reaction temperature ; 340$^\circ$C The reaction kinetic equation at the optimum condition, temperature range from 200$^\circ$C to 340$^\circ$C, are as follow. $$ $v = Ae^{6.5Kcal/RT} [CO]^{0.93 \sim 0.98} [O_2]^{0.42 \sim 0.50}$ $$ In addition to this, numerical calculation were performed to evaluate the mass and heat transfer effect on this system.

• Journal of Environmental Science International
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• v.26 no.11
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• pp.1201-1208
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• 2017

Oxidative degradation of chlorinated ethenes was carried out using heat-activated persulfate. The activation rate of persulfate was dependent on the temperature and the activation reaction rate could be explained based on the Arrhenius equation. The activation energy of persulfate was 19.3 kcal/mol under the assumption that the reaction between the sulfate radical and tricholoroethene (TCE) is very fast. Activation could be achieved at a moderate temperature, so that the adverse effects due to high temperature in the soil environment were mitigated. The reaction rate of TCE was directly proportional to the concentration of persulfate, indicating that the remediation rate can be controlled by the concentration of the injected persulfate. The solution was acidized after the oxidation, and this was dependent on the oxidation temperature. The consumption rate of persulfate was high in the presence of the target organic, but the self-decomposition rate became very low as the target was completely removed.

• Journal of the Korean Applied Science and Technology
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• v.22 no.1
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• pp.56-61
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• 2005

Methanol was synthesized by homogeneous and catalytic reactions of partial oxidation of methane. The effect of pressure, temperature and oxygen concentration on methanol synthesis was investigated. The catalyst used was Bi-Cs-Mg-Cu-Mo mixed oxide. The partial oxidation reaction was carried out in a fixed bed reactor at 20${\sim}$46 bar and $450{\sim}480^{\circ}C$ and oxygen concentration of 5.3${\sim}$7.7mol%. The results were compared with results of homogeneous reaction performed at the same conditions. Methane conversions of the homogeneous and catalytic reactions increased with temperature. Methanol selectivity of the homogeneous reaction decreased with increasing temperature. However, the methanol selectivity of catalytic reaction increased with temperature. For both homogeneous and catalytic reactions, the methane conversions were around 5%. This may be due to the low oxygen concentration. Methanol selectivity of the catalytic reaction was higher than that of homogeneous one.

• Transactions of the Korean hydrogen and new energy society
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• v.23 no.2
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• pp.173-182
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• 2012

Effects of temperature, pressure, and gas residence time on methane combustion characteristics of mass produced oxygen carrier particle (OCN706-1100) were investigated in a pressurized fluidized bed reactor using methane and air as reactants for reduction and oxidation, respectively. The oxygen carrier showed high fuel conversion, high $CO_2$ selectivity, and low CO concentration at reduction condition and very low NO emission at oxidation condition. Moreover OCN706-1100 particle showed good regeneration ability during successive reduction-oxidation cyclic tests up to the 10th cycle. Fuel conversion and $CO_2$ selectivity decreased and CO emission increased as temperature increased. These results can be explained by trend of calculated equilibrium CO concentration. However, $CO_2$ selectivity increased as pressure increased and fuel conversion increased as gas residence time increased.

• Proceedings of the Materials Research Society of Korea Conference
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• 1998.05a
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• pp.10-10
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• 1998

• Bulletin of the Korean Chemical Society
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• v.16 no.3
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• pp.296-298
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• 1995

• Journal of Environmental Science International
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• v.18 no.10
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• pp.1071-1077
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• 2009

A novel pretreatment technique was applied to the conventional Pt/alumina catalyst to prepare for the highly efficient catalyst for the preferential oxidation of carbon monoxide in hydrogen-rich condition. Their performance was investigated by selective CO oxidation reaction. CO conversion with the oxygen-treated Pt/Alumina catalyst increased remarkably especially at the low temperature below $100^{\circ}C$. This result is promising for the normal operation of the proton exchange membrane fuel cell (PEMFC) without CO poisoning of the anode catalyst. XRD analysis results showed that metallic Pt peaks were not observed for the oxygen-treated catalyst. This implies that well dispersed small Pt particles exist on the catalyst. This result was continued by high resolution transmission electron microscopy (HRTEM) analysis. Consequently, it can be concluded that highly dispersed Pt nanoparticles could be prepared by the novel pretreatment technique and thus, CO conversion could be increased considerably especially at the low temperatures below $100^{\circ}C$.

• Journal of the Korean Applied Science and Technology
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• v.31 no.2
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• pp.313-319
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• 2014

This study was performed to obtain high conversion efficiency of $NH_3$ and minimize generation of nitrogen oxides using metal-supported catalyst with Ag : Cu ratio. Through structural analysis of the prepared catalyst with Ag : Cu ratio ((10-x)Ag-xCu ($0{\leq}x{\leq}6$)), it was confirmed that the specific surface area was decrease with increasing metal content. A prepared catalysts showed Type II adsorption isotherms regardless of the ratio Ag : Cu of metal content, and crystalline phase of $Ag_2O$, CuO and $CuAl_2O$ was observed by XRD analysis. In the low temperature($150{\sim}200^{\circ}C$), a conversion efficiency of AC_10 recorded the highest(98%), whereas AC_5 (Ag : Cu = 5 : 5) also showed good conversion efficiency(93.8%). However, in the high temperature range, the amounts of by-products(NO, $NO_2$) formed with AC_5 was lower than that of AC_10. From these results, It is concluded that AC_5 is more environmentally and economically suitable.

• Journal of the Institute of Electronics Engineers of Korea SD
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• v.40 no.8
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• pp.560-564
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• 2003

Thick oxide layer was fabricated by anodic reaction and complex oxidation performed by combining low temperature thermal oxidation (50$0^{\circ}C$, 1 hr at $H_2O$/O$_2$) and a RTO (rapid thermal oxidation) process (105$0^{\circ}C$, 1 min). Electrical characteristics of OPSL (oxidized porous silicon layer) were almost the same as those of thermal silicon dioxide prepared at high temperature. The leakage current through the OPSL of 20${\mu}{\textrm}{m}$ thickness was about 100 - 500 ㎀ in the range 0 V to 50 V. The average value of breakdown field was about 3.9 MV/cm. From the XPS analysis, surface and internal oxide films of OPSL prepared by complex process were confirmed completely oxidized and also the role of RTO process was important for the densification of PSL (porous silicon layer) oxidized at low temperature.