• 한국연소학회:학술대회논문집
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• 2012.11a
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• pp.111-114
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• 2012

The ignition behavior of single coal particles of five kindes of coal with different ranks (low volatile bituminous, low volatile sub-bituminous, high volatile bituminous, lignite) with particle size of $150-200{\mu}m$ was investigated at high heating rate condition. Particles were injected into a laminar flow reactor and the ignition behavior was observed with high speed cinematography. Sub-bituminous were observed to ignite homogeneously; however, low volatile bituminous coal and lignite undergo fragmentation prior to igntion. The observation was analyzed with previous work.

• Korean Chemical Engineering Research
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• v.49 no.5
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• pp.639-643
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• 2011

Fry-drying of coal slurry is one of the upgrading low rank coal processes. It consists of slurry mixing, slurry dewatering, solvent recovery and briquetting. Cost estimation and economic feasibility are examined for the upgrading low rank coal process based on capacity of 1 million ton/yr. In case that investment costs are $100,000,000, discount rate is 12%, and service life is 20 years, the results of economic analysis are enough to satisfy the evaluation criteria of investment such as IRR, B/C ratio, NPV and discounted payback period. According to sensitivity analysis, investment value are very sensitive to raw material cost and product price. Since the bituminous coal price is currently soaring, it is expected that the investment value will increase more and more.

• Clean Technology
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• v.20 no.3
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• pp.321-329
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• 2014

In this study, Indonesia low rank coal, which has moisture content of around 26%, is dried less than 5% by using a laboratory-scale (batch type) steam fluidized-bed dryer in order to produce the low-moisture, high rank coal. Normally, CCS (carbon capture and storage) process discharges $CO_2$ and steam mixture gas around $100-150^{\circ}C$ of temperature after regeneration reactor. The final purpose of this research is to dry low rank coal by using the outlet gas of CCS process. At this stage, steam is used as heat source for drying through the heat exchanger and $CO_2$ is used as fluidizing gas to the dryer. The experimental variables were the steam flow rate ranging from 0.3 to 1.1 kg/hr, steam temperature ranging from 100 to $130^{\circ}C$, and bed height ranging from 9 to 25 cm. The characteristics of the coal, before and after drying, were analyzed by a proximate analysis, the heating value analysis and particle size analysis. In summary, the drying rate of low rank coal was increased as steam flow rate and steam temperature increased and increased as bed height decreased.

• Transactions of the Korean hydrogen and new energy society
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• v.27 no.6
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• pp.693-701
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• 2016

Steam gasification of low rank coals is possible at relatively low temperature and low pressure, and thus shows higher efficiency compared to high rank coals. In this study, the gasification reactivity of four different Indonesian low rank coals (Samhwa, Eco, Roto, Kideco-L) was evaluated in $T=700-800^{\circ}C$. The low rank coals containing $53.8{\pm}3.4$ wt% volatile matter in proximate analysis and $71.6{\pm}1.2$ wt% carbon in ultimate analysis showed comparable gasification reactivity. In addition, $K_2CO_3$ catalyst rapidly accelerated the reaction rate at $700^{\circ}C$, and all of the coals were converted over 90% within 1 hour. The XRD analysis showed no significant difference in carbonization between the coals, and the FT-IR spectrum showed similar functional groups except for differences due to moisture and minerals. TGA results in pyrolysis ($N_2$) and $CO_2$ gasification atmosphere showed very similar behavior up to $800^{\circ}C$ regardless of the coal species, which is consistent with the steam gasification results. This confirms that the indirect evaluation of the reactivity can be made by the above instrumental analyses.

• Economic and Environmental Geology
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• v.32 no.1
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• pp.83-91
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• 1999

Coal properties are controlled by the following two factors : One is the maceral components and the other is the degree of coalification. In other words, even if coals in question indicate the same degree of coalification, their chemical and physical properties considerably vary one another when their maceral components are different. It is well known that virtrinite reflectance is the best single criterion for the degree of coalification covering the whole range of coal rank. Some authors have recently insisted that sporinite fluorescence is more leliable coal rank parameter than vitrinite reflectance in case of low rank coals. In this paper, to examine the relince of sporinite fluorescence as coal rank parameter, fluidity analysis of coals is newly performed and the data are analyzed in comparision with those of virinite reflectance, sporinite fluorescence and maceral components. The results of this study are as follows; 1) Vitrinite reflectance becomes low when degradinite content is high within one columnar samples, and vice versa. 2) variation of vitrinite reflectance depend on degradinite content and on difference of roiginal plant. 3) In dealing with the Japanese paleogene coals, sporinite fluorescence is more reliable parameter indicating the degree of coalification than vitrinite reflectance. 4) Maximum fluidity increases exponetially in proportion to the increases of degradinite content.

• 한국연소학회:학술대회논문집
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• 2012.04a
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• pp.205-208
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• 2012

In this study, the thermal behavior and combustion characteristics of different ranks of coals and their blends were investigated to obtain information necessary for the evaluation of the co-processing of blends with low-rank coals. Thermogravimetric analysis(TGA) and differential thermal analysis(DTA) were carried out at different temperature from ambient temperature to $800^{\circ}C$, and a laboratory-scale pulverized coal combustion burner was used with coal feeing rate of $1.04{\times}10^{-4}kg/s$.

• Transactions of the Korean hydrogen and new energy society
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• v.24 no.4
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• pp.340-346
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• 2013

Study on clean and efficient utilization technology for low rank coal with high moisture content is actively ongoing due to limited reserves of petroleum and of high grade coal and serious climate change caused by fossil fuel usage. In the present study, supercritical water gasification of low rank coal was performed. With increasing reaction temperature, content of combustible gases such as $H_2$ and $CH_4$ in the syngas increased while the $CO_2$ content decreased. As the reaction pressure increased from 210 to 300 bar, the $CO_2$ content in the syngas increased while the hydrocarbon gas content decreased. The $H_2$ and $CH_4$ content in the syngas increased slightly with pressure. With the addition of Pd, Pt, and Ru catalysts, it was possible to improve the production of $H_2$. Moreover, the increase of active metal content in the catalyst increased the $H_2$ productivity. The Ru catalyst shows the best performance for increasing the $H_2$ content in the syngas, while decreasing the $CO_2$ content.

• Korean Chemical Engineering Research
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• v.46 no.3
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• pp.555-560
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• 2008

Extraction was performed to prepare ash-free coal from low rank coal under the temperature of $200-430^{\circ}C$ and initial pressure of 0.1MPa. Three kinds of coal samples with different rank were used and N-methyl-2-pyrrolidinone(NMP, polar), 1-methyl naphthalene(I-MN, non-polar), Light Cycle Oil(LCO, non-polar) were used as solvents. Results showed that higher extraction yield could be obtained with NMP than with 1-MN and LCO, but the ash concentration shows minimun in the case of 1-MN. Three operation modes were compared, that is, idle, agitation and ultrasonic extraction mode. From the results, it was found that the extraction yield and ash concentration were 70.09% and 1.03% under the agitation mode, 80.7% and 0.76% under the ultrasonic operation mode respectively in the case of NMP used at the temperature of $350^{\circ}C$. Similar results were obtained with 1-MN. Effect of ultrasonic on the extraction was estimated as 15-20% increase in the yields and 26% reduction in the ash concentration.

• Journal of the Korean Society of Combustion
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• v.14 no.3
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• pp.16-23
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• 2009

It is strongly desired for coal-fired power plants to utilize not only low-rank coals with high moisture contents, but also lowering cost with diversifying fuel sources. In this study, combustion characteristics of low rank coal with high moisture, and standard pulverized coals are experimentally investigated using TGA (Thermogravimetric Analysis) and DTF (drop tube furnace). The coals tested are three kinds of coal with moisture content ranging from 8.32 to 26.82%. The results show that under the air combustion condition, the burn-out time at TGA rises as moisture content increases, and standard pulverized coal with 8.32% moisture content showed the lowest activation energy of 55.73 kJ/mol. In case of the high amount of moisture, the combustion efficiency decreases due to evaporation heat loss, and unburned carbon in ash produced at combustion process in DTF increased. Aslo, initial deformation temperature of slag attached in alumina tube of DTF decreased with lowering the crytallinity of anorthite and augite. To improve the combustion reactivity and efficiency, it is effective to upgrade through drying the high moisture coal to moisture level (less than 10%) of standard pulverized coal.

• Clean Technology
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• v.24 no.2
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• pp.119-126
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• 2018

This study introduced a treatment process that was developed to treat Indonesian low-rank coal with high-ash content, which has the same characteristics as residual coal from the biosolubilization process. The treatment process includes separation of ash, solid-liquid separation, pelletizing, and drying. To reduce the ash content, flotation was performed using 4-methyl-2-pentanol (MIBC) as frother, and kerosene, waste oil, and cashew nut shell liquid (CNSL) as collectors. The increasing amount of collector had an effect on combustible coal recovery and ash reduction. After flotation, a filter press, extruder, and an oven drier were used to make a dried coal pellet. Then another coal pellet was made using asphalt as a binder. The compressive strength and friability of the coal pellets were tested and compared.