• Journal of the Korea Institute of Building Construction
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• v.12 no.1
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• pp.54-63
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• 2012

The purpose of this study is to examine the potential for reducing the environmental load and $CO_2$ gas when cement is produced by using cement substitutes. These substitutes consisted of blast furnace slag, red mud and silica fume, which were industrial by-products. The most optimum mix was derived when alkali accelerator was added to low carbon inorganic composite mixed with industrial by-product at room temperature. It is determined that hardened properties and the results of compressive strength tests changed based on CaO content, Si/Al, the mixing ratio and the amount of alkali accelerator, curing conditions and W/B. The results of test analysis suggest that the optimum mix of low carbon inorganic composite is CaO content 30%, Si/Al 4, the mixed ratio of alkali accelerator $(NaOH:Na_2SiO_3)$ 50g:50g, the amount of alkali accelerator 100g and W/B 31%. In addition, if contraction is complemented, low carbon inorganic composite with superior performance could be developed.

• Journal of Radiation Industry
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• v.5 no.3
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• pp.249-252
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• 2011

Lignin is one of the natural macromolecules. Every year large amount of lignin arises from the cellulose production as a by-product worldwide. The use of lignin as a precursor to carbonaceous materials has gained interest due to its low cost and high availability. Therefore, we improved the properties of alkali-lignin by exposing to gamma ray in this study. The alkali-lignin is irradiated by Gamma ray irradiation with varying doses. The char yields of alkali-lignin were investigated by increasing up to 50 kGy. The cross-linking and bond scission of alkali-lignin occur simultaneously during gamma ray irradiation. The crosslinking was predominantly accelerated by gamma ray irradiation up to 50 kGy. Bond scission predominantly occurs between 50 and 500 kGy. ESCA analysis indicated that the alcoholic carbon increase up to 50 kGy. Solution viscosity was increased as absorbed dose increased up to 20 kGy. In addition, the aromatic ring was not influenced by irradiation at doses ranging from 20 to 500 kGy as shown in FT-IR results.

• Journal of Sensor Science and Technology
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• v.6 no.3
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• pp.200-206
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• 1997

Using $SiCl_{2}H_{2}$, $NH_{3}$ and $N_{2}O$, we have fabricated silicon oxynitride ($Si_{x}O_{y}N_{z}$) layers on thermally oxidized silicon wafer by low pressure chemical vapor deposition. Three different compositions were achieved by controlling gas flow ratios($NH_{3}/N_{2}O$)) to 0.2, 0.5 and 2 with fixed gas flow of $SiCl_{2}H_{2}$. Ellipsometry and high frequency capacitance-voltage(HFCV) measurements were adapted to investigate the difference of the refractive index, dielectric constant, and composition, respectively. Regardless of nitride content, silicon oxynitrides had similar stability to silicon nitrides. The relative standing of alkali ion sensitivity in silicon oxynitride layers was influenced by nitride content. The better alkali ion-sensitivity was achieved by increasing oxide content in bulk of silicon oxynitrides.

• Journal of Korean Ophthalmic Optics Society
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• v.1 no.1
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• pp.1-14
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• 1996

The mixed alkali silicate glasses doped 0.1 mol% $Fe_2O_3$ are fabricated for studying the effect of transition metal oxides, which is related to the $Li^-$ ion movement in Magic-Angle-Spinning NMR. We have investigated the spin-lattice relaxation times in the room temperature and measured the $^7Li$ MAS-NMR spectrum with temperature. When the $Fe_2O_3$ oxides are added in alkali silicate glasses, the width of spectrum is changed a little but the line shape is hardly varied. For this reason, we can think that the mixed alkali effects are shown sufficiently in the spin-spin relaxation processes. However, it is not mixed alkali effects in this case. The activation energy of $Li^-$ ions are diminished in mixed alkali glasses. From the analysis of $Li^-$ diffusion environment, spin-lattice relaxation time and the nuclear magnetization, it is confirmed that the alkali mixed effects are not shown in $^7Li$ spin-lattice relaxation processes.

• Journal of Korean Society of Environmental Engineers
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• v.29 no.7
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• pp.810-819
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• 2007

Investigation of alkali activation of fly ash and blast furnace slag was carried out using waterglass and sodium hydroxide. XRD, FTIR, $^{29}Si$ and $^{27}Al$ NMR, TGA and SEM were used to observed the reaction products and microstructure of the fly ash/slag cement (FSC) pastes. The reaction products were amorphous or low-ordered calcium silicate hydrate and aluminosilicate gel produced from alkali activation of blast furnace slag and fly ash, respectively. On the basis of this investigation, waterglass solution with a modulus(Ms) of 1.0 and 1.2 is recommended for alkali activation of fly ash and blast furnace slag. Morphology of FSC pastes alkali-activated with Ms of 1.0 and 1.2 shows a more solid and continuous matrix due to restructuring of gel-like reaction products from alkali-activated fly ash and blast furnace slag together with another hydrolysis product(i.e., silica gel) from water glass.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.33 no.3
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• pp.75-83
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• 2001

The potential of oxygen delignification is a powerful tool to reduce detrimental environmental effects. This study was performed to investigate the effect of steam explosion treatment of chemically treated oak wood on oxygen-alkali pulping. Pulp yield during steam explosion treatment by ${Na_2}{O_3}$-NaOH impregnation was higher than the other impregnation chemicals. Also, NaOH extraction at room temperature after steam explosion treatment improved the kappa number from 140~116 to 90~64. Oxygen-alkali pulping of chemical steam explosion treated woods affected to pulp yields. ${Na_2}{O_3}$-NaOH impregnation was very effective to higher carbohydrate yields at same delignification level. Its carbohydrate yield seemed to be highly related to the effluent pH. Oxygen-alkali pulping after steam explosion treatment of ${Na_2}{O_3}$-NaOH impregnated wood was shown that carbohydrate yield was very high because its effluent pH was increase from natural to mild alkali. Even if oxygen bleaching limit the delignification to 50% in order to avoid unacceptable yield and viscosity losses, oxygen-alkali pulping after steam explosion by ${Na_2}{O_3}$-NaOH impregnation was possible to extend the delignification more than 80%. Considering high pulp yield with lower lignin content from steam explosion treated wood, it might be profitable to end the cook at a high kappa number instead of a low kappa number, and continuously apply the oxygen delignification, in order to better quality pulp.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2011.05a
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• pp.59-60
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• 2011

The purpose of this study is to produce the low-carbon eco-friendly inorganic composite at room temperature by an alkali accelerator without firing process at high temperature, and complement the problem of previous studies, the deterioration in strength caused by cracking, with incorporation of PVA fibers. Results of reviewing the changes in the strength properties of PVA showed that test body mixed with PVA fibers had the superiority in strength expression.

• Journal of the Korea institute for structural maintenance and inspection
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• v.26 no.1
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• pp.67-72
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• 2022

Concrete prevents corrosion of reinforcing bars due to its strong alkalinity. However, in the sea, strong alkali components with a pH of 12 to 13 are eluted, which adversely affects the ecological environment and growth of marine organisms. In this study, the mechanical properties and durability of the low alkali mortar were evaluated for the development of a low alkali mortar for the 3D printed artificial reefs. As a result of evaluation of strength characteristics, the α-35 mixture, which were produced with fly ash, silica fume and α-hemihydrate gypsum, satisfied the strength requirement 27 MPa in terms of compressive strength. As a result of pH measurement, it was found that mixing with alpha-type hemihydrate gypsum resulted in minimizing pH due to the the formation of calcium sulfate instead of calcium hydroxide production. As a result of the chloride ion penetration resistance test, the α-35 mixture exhibited the best performance, 3844C. As a result of measuring the length change over time, the α-35 mixture showed the shrinkage 33.5% less compared to the Plain mix.

• 한국정보디스플레이학회:학술대회논문집
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• 2006.08a
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• pp.1763-1768
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• 2006

Low work function alkali metals and alkaline earths successfully lower the electron injection barrier and increase electron injection into the organic layer in OLED displays, but their implementation is not easy. AlkaMax technology can ensure the required metal evaporation rate in a fast, homogeneous and easily controllable way.

• Current Photovoltaic Research
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• v.6 no.2
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• pp.56-61
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• 2018

In this study, CIGS absorber layers were deposited on low-alkali glass and sodalime glass substrates and potasium floride (KF) of various thicknesses was supplied at an elevated temperature after the CIGS growth. The effect of KF post-deposition treatment on the two types of substrates was extremely different. On the low-alkali substrate, the open-circuit voltage (Voc) was improved but the fill-factor (FF) degradation was severe, whereas the sodalime substrate showed Voc deterioration and FF improvement. In the case of supplying 20 nm of KF on both substrates, the efficiency gain of 0.3~1.1%p was obtained. With increasing the KF thickness, a small protrusion-like microstructure developed on the surface of the absorber layer, and the microstructures that were not removed in the subsequent process were found to be the main cause of the FF loss.