• Transactions of the Korean Society of Mechanical Engineers B
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• v.31 no.10
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• pp.855-859
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• 2007

Hydrogen as an energy carrier in fuel cell offers perhaps the largest potential benefits of reduced emissions of pollutants and greenhouse gases. The generation of high-purity hydrogen from hydrocarbon fuels is essential for efficient operation of fuel cell. Reduction of carbon monoxide to an acceptable level of 10ppm involves high temperature and low temperature water gas shift (WGS), followed by selective oxidation of residual carbon monoxide. The WGS reactor was designed and tested in this study to produce hydrogen-rich gas with CO to less than 5000 ppm. In the water gas shift operation, gas emerges from the reformer is taken through a high temperature shift (HTS) catalyst to reduce the CO concentration to about $2{\sim}4%$ followed to about 5000 ppm via a low temperature shift (LTS) catalyst.

• Journal of Korean Society of Environmental Engineers
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• v.29 no.5
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• pp.528-532
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• 2007

The generation of high-purity hydrogen from hydrocarbon fuels is essential for efficient operation of fuel cell. In general, most feasible strategies to generate hydrogen from hydrocarbon fuels consist of a reforming step to generate a mixture of $H_2$, CO, $CO_2$ and $H_2O$(steam) followed by water gas shift(WGS) and CO clean-up steps. The WGS reaction that shifts CO to $CO_2$ and simultaneously produces another mole of $H_2$ was carried out in a two-stage catalytic conversion process involving a high temperature shift(HTS) and a low temperature shift(LTS). In the WGS operation, gas emerges from the reformer is taken through a high temperature shift catalyst to reduce the CO concentration to about $3\sim4%$ followed to about 0.5% via a low temperature shift catalyst. The WGS reactor was designed and tested in this study to produce hydrogen-rich gas with CO to less than 0.5%.

• Resources Recycling
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• v.30 no.6
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• pp.12-18
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• 2021

The water-gas shift reaction is the subsequent step using steam for hydrogen enrichment and H₂/CO ratio-controlled syngas from gasification. In this study, a water-gas shift reaction was performed using syngas from an RPF gasification system. The water-gas shift using a catalyst was performed in a laboratory-scale tube reactor with a high temperature shift (HTS) and a low temperature shift (LTS). The effects of the reaction temperature, steam/carbon ratio, and flow rate on H₂ production and CO conversion were investigated. The operating temperature was 250-400℃ for the HTS system and 190-220℃ for the LTS system. Steam/carbon ratios were between 1.5 and 3.5, and the composition of reactant was CO : 40 vol%, H₂ : 25 vol%, and CO₂ : 25 vol%. The CO conversion and H₂ production increased as the reaction temperature and steam/carbon ratio increased. The CO conversion and H₂ production decreased as the flow rate increased due to reduced retention time in the catalyst bed.

• Transactions of the Korean hydrogen and new energy society
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• v.27 no.6
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• pp.621-627
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• 2016

Low-priced hydrogen is required in petrochemical industry for producing low-sulfur oil, and upgrading low-grade crude oil since environmental regulations have been reinforced. Steel industry can produce hydrogen from by-product gases such as Blast Furnace Gas (BFG), Coke Oven Gas (COG), and Linze Donawitz Gas (LDG) with water gas shift (WGS) reaction by catalysis. In this study, we optimized conditions for WGS reaction with commercial catalysts by BFG and LDG. In particular, the influence on activity of gas-hourly-space-velocity, and $H_2O/CO$ ratios at different temperatures were investigated. As a result, 99.9%, and 97% CO conversion were showed with BFG, and LDG respectively under $350^{\circ}C$ High Temperature Shift (HTS), $200^{\circ}C$ Low Temperature Shift (LTS), 3.0 of $H_2O/CO$, and $1500h^{-1}$ of GHSV. Furthermore, 99.9% CO conversion lasted for 250 hours with BFG as feed gas.

• New & Renewable Energy
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• v.5 no.2
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• pp.9-14
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• 2009

Automobile Shredder Residue (ASR) is very appropriate in a gasification melting system. Gasification melting system, because of high reaction temperature over than $1,350^{\circ}C$, can reduce harmful materials. To use the gasification processes for hydrogen production, the high concentration of CO in syngas must be converted into hydrogen gas by using water gas shift reaction. In this study, the characteristics of shift reaction of the high temperature catalyst (KATALCO 71-5M) and the low temperature catalyst (KATALCO 83-3X) in the fixed - bed reactor has been determined by using simulation gas which is equal with the syngas composition of gasification melting process. The carbon monoxide composition has been decreased as the WGS reaction temperature has increased. And the occurrence quantity of the hydrogen and the carbon dioxide increased. When using the high temperature catalyst, the carbon monoxide conversion ratio ($1-CO_{out}/CO_{in}$) rose up to 95.8 from 55.6. Compared with average conversion ratio from the identical synthesis gas composition, the low temperature catalyst was better than the high temperature catalyst.

• Journal of Information Display
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• v.12 no.1
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• pp.61-67
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• 2011

A single-clock-driven shift register and a two-stage buffer are proposed, using p-type, low-temperature polycrystalline silicon thin-film transistors. To eliminate the clock skew problems and to reduce the burden of the interface, only one clock signal was adopted to the shift register circuit, without additional reference voltages. A two-stage, p-type buffer was proposed to drive the gate line load and shows a full-swing output without threshold voltage loss. The shift register and buffer were designed for the 3.31" WVGA ($800{\times}480$) LCD panel, and the fabricated circuits were verified via simulations and measurements.

• Proceedings of the KSME Conference
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• 2007.05b
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• pp.2228-2231
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• 2007

Water gas shift reactor in fuel processing is an important part that converts carbon monoxide into hydrogen. Fuel processing system for PEMFC usually has two stages of WGS reactors, which are high temperature and low temperature shifter. In this study we prepared noble metal catalysts and compared their performances with that of a commercial iron chromium oxide catalyst. Noble metal catalysts and the commercial catalyst showed quite different temperature dependence of carbon monoxide conversion. The conversion of carbon monoxide at the commercial catalyst was very low at medium temperature(${\sim}300^{\circ}C$) and increased rapidly as temperature increased while the conversion at noble metal catalysts was high in the medium temperature range and decreased as temperature increased, which is thermodynamically expected. Their characteristics agreed well with the literature published, and we are accomplishing further study for improvement of the noble metal catalysts.

• 한국정보디스플레이학회:학술대회논문집
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• 2009.10a
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• pp.1402-1404
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• 2009

The silicon nitride films for gate dielectric were deposited by catalytic chemical vapor deposition at low temperature (${\leq}200^{\circ}C$). The mixture of $SiH_4$, $NH_3$ and $H_2$ was used as source gases. The current-voltage (I-V) and the capacitance-voltage (C-V) characteristics of the films were measured. The breakdown voltage and the flat band voltage shift of samples were improved by increase of the $NH_3$ contents and $H_2$ dilution ratio. The defect states were analyzed by photoluminescence (PL) spectra. As the defect states decreased, the breakdown voltage and the flat band voltage shift increased.

• Transactions of the Korean hydrogen and new energy society
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• v.30 no.2
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• pp.103-110
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• 2019

Cu-Zn-Al catalysts were prepared via co-precipitation method for low-temperature water-gas shift (LT-WGS) reaction under practical reaction condition. Aging time was systematically changed to find optimum point for LT-WGS under practical condition. The Cu-Zn-Al catalyst aged for 72 hours showed the highest CO conversion within low-temperature range as well as very stable catalytic activity for 200 hours despite the practical reaction condition.

• International Journal of Highway Engineering
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• v.14 no.5
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• pp.75-83
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• 2012

PURPOSES: Suggestion of asphalt binder constitutive model based on time-temperature superposition principle and overstress concept in order to describe behavior of asphalt binders. METHODS: A series of temperature sweep tests and multiple stress creep and recovery(MSCR) tests are performed to verify the applicability of time-temperature superposition principle(t-Ts) and to develop viscoelastoplastic constitutive equation based on overstress concept. For the tests, temperature sweep tests at various high temperature and various frequency and MSCR test at $58^{\circ}C$, $64^{\circ}C$ $70^{\circ}C$, $76^{\circ}C$, and $82^{\circ}C$ are performed. From the temperature sweep tests, dynamic shear modulus mastercurve and time-temperature shift function are built and the shift function and MSCR at $58^{\circ}C$ are utilized to determine model coefficients of VBO model. RESULTS: It is observed that the time-temperature shift function built at low strain level of 0.1% is applicable not only to 1.0% strain level temperature sweep test but also maximum 500,00% strain level of MSCR test. As well, the modified VBO model shows perfect prediction on MSCR measured strain at the other temperatures. CONCLUSIONS: The Time-temperature superposition principle stands hold from very low strain level to very high strain level and that the modified VBO model can be applicable for various range of strain and temperature region to predict elastic, viscoelastic, and viscoplastic strain of asphalt binders.