• Title/Summary/Keyword: Low Surface Tension

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Synthesis and Properties of N-Acyl Glycine Used Triglyceride (트리글리세라이드를 이용한 N-아실 글리신의 합성 및 물성)

  • Shin, Hye-Rin;Park, Ye-Won;Jeong, Noh-Hee
    • Journal of the Korean Applied Science and Technology
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    • v.34 no.4
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    • pp.1058-1065
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    • 2017
  • Amino acid based surfactants as protein-surfactants is eco-friendly compound. So, amino acid based surfactants is expected as next generation surfactants. Amino acid based surfactants has high biodegradability, low toxicity and surface active properties. In this experiment, amino acid based surfactants, cocoyl glycine, was synthesized by glycine and triglyceride such as coconut oil and palm oil. And it was tested the surface tension, emulsifying properties, foam stability and HLB value. The synthesized surfactants was confirmed by FT-IR. Surface tension of surfactants synthesized by coconut oil on diluted aqueous solutions of surfactants was 31.2 dyne/cm at $1.0{\times}10^{-4}mol/L$. Surface tension of surfactants synthesized by palm oil on the diluted aqueous solutions of surfactants was 42.1 dyne/cm at $3.2{\times}10^{-5}mol/L$. Foam stability measured the foam height as time passed. Initial foam height of surfactants synthesized by coconut oil is 14.5 cm, and 10.7 cm after five minutes. Initial foam height of surfactants synthesized by palm oil is 3.0 cm, and 2.8 cm after five minutes. Foam height of surfactants synthesized by coconut oil was higher than surfactants synthesized by palm oil. But foam stability of surfactants synthesized by palm oil was better than surfactants synthesized by coconut oil. The emulsifying properties of synthesized surfactants are observed in benzene and soybean oil and emulsifying properties in organic solvent is better than in soybean oil.

Optimization Using 33 Full-Factorial Design for Crude Biosurfactant Activity from Bacillus pumilus IJ-1 in Submerged Fermentation

  • Kim, Byung Soo;Kim, Ji Yeon
    • Microbiology and Biotechnology Letters
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    • v.48 no.1
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    • pp.48-56
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    • 2020
  • This study aimed to optimize the culture conditions to improve the crude biosurfactant activity of Bacillus pumilus IJ-1, using a 33 full-factorial design of response surface methodology (RSM). It was found that submerged fermentation of B. pumilus improved the activity of the crude biosurfactant. The factors selected for optimization were NaCl concentration, temperature, and tryptone concentration. Response surface analysis revealed that the fitted quadratic model was statistically significant and produced an adequate R2 value (0.9898) and a low probability value (<0.0001). The optimum level for each factor was found to be 0.567% (w/v) NaCl, 21.851℃ and 0.765% (w/v) tryptone, respectively. Crude biosurfactant activity was found to be most affected by tryptone concentration; then temperature, and finally NaCl concentration. Our results may potentially facilitate large-scale biosurfactant production from B. pumilus IJ-1.

Effect of Nozzle Material on Drop Size Distribution in Electrohydrodynamic Spraying (전기수력학적 분무에서 노즐재질이 입경분포에 미치는 영향)

  • 김명찬;이상용
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.26 no.10
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    • pp.1451-1457
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    • 2002
  • When an aqueous liquid such as water having high electric conductivity and high surface tension is discharged from a nozzle under a strong DC electric field, fine drops ranging from 30 to 450 microns can be obtained only through the spindle mode. In the present study, effects of the electric conductivity and the surface wettability of nozzle materials on formation of drops with this mode were investigated. For that, three nozzles with the same size but with different materials were prepared and tested; a stainless steel needle, and a plain and a metal (gold)-coated (except for the tip portion) silica needles. Uniform drops were obtained with the gold-coated silica nozzle over the wider range of the DC voltage input. That is, formation of the liquid cone and detachment of the liquid spindle (ligament) can be more stabilized and frequent with the needles having high electric conductivity but with low surface wettability at their tips.

Isolation, Characterization, and Investigation of Surface and Hemolytic Activities of a Lipopeptide Biosurfactant Produced by Bacillus subtilis ATCC 6633

  • Dehghan-Noudeh Gholamreza;Housaindokht Mohammadreza;Bazzaz Bibi Sedigeh Fazly
    • Journal of Microbiology
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    • v.43 no.3
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    • pp.272-276
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    • 2005
  • Bacillus subtilis ATCC 6633 was grown in BHIB medium supplemented with $Mn^{2+}$ for 96 h at $37^{\circ}C$ in a shaker incubator. After removing the microbial biomass, a lipopeptide biosurfactant was extracted from the supernatant. Its structure was established by chemical and spectroscopy methods. The structure was confirmed by physical properties, such as Hydrophile-Lipophile Balance (HLB), surface activity and erythrocyte hemolytic capacity. The critical micelle concentration (cmc) and erythrocyte hemolytic capacity of the biosurfactant were compared to those of surfactants such as SDS, BC (benzalkonium chloride), TTAB (tetradecyltrimethylammonium bromide) and HTAB (hexadecyltrimethylammonium bromide). The maximum hemolytic effect for all surfactants mentioned was observed at concentrations above cmc. The maximum hemolytic effect of synthetic surfactants was more than that of the biosurfactant produced by B. subtilis ATCC 6633. Therefore, biosurfactant would be considered a suitable surface-active agent due to low toxicity to the membrane.

Development of Piston Friction Force Measurement System (피스톤계 마찰 측정 장치 개발)

  • Ha, Gyeong-Pyo;Kim, Jung-Su;Jo, Myeong-Rae;O, Dae-Yun
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.26 no.8
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    • pp.1608-1614
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    • 2002
  • This Paper presents a novel piston friction force measurement system that has characteristics of relieving the Pressure force acting on the upper surface of the liner; the system uses general rubber O-rings for combustion chamber sealing, and does not need special changes to the piston top land. The lower supporter of the floating liner increases stiffness in liner axial direction, and results in the increase of natural frequency. The upper supporter has multi-layer structure designed fer low axial stiffness and high radial stiffness. With the use of the present system, the effects of variation in clearance and piston ring tension were studied.

Ground Anchor Testing on Temporary Excavations (일반 가설앵커의 문제점과 개선방향)

  • 김성규;김낙경;김정렬
    • Proceedings of the Korean Geotechical Society Conference
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    • 2003.03a
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    • pp.545-552
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    • 2003
  • For temporary excavation support in a congested urban area, the strand of ground anchor should be removed to get permission of the private land to install anchors. But the strand doesn't need to be removed in the outside city area after use. So the anchor body, tension anchor, is fabricated in-situ. The unbonded length of This anchor has several strands, which wrap only one sheath. When the anchor body is carried into job-site or installed in the bore hole, the sheath is torn easily because it is a very week material. So the grout permeate into the torn sheath. Because of that, the load doesn't transfer to the bond length of ground anchors. It may indicate that load is being transferred along the unbonded length and thus within the potential slip surface assumed for overall stability of the anchored system. The load tests were performed on seven low-pressure grouted anchors installed in weathered soil to verify its problems. Four anchors(Type A) have the unbonded length, which consist of five strands and a week sheath and three anchors(Type B) have strands, which is covered by plastic sheath filled with grease, in the unbonded length. Both anchors are compared with load tests results.

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The influences of coating components and structures on ink absorbency (도공층 조성 및 구조의 잉크흡수성에 대한 영향)

  • 곽상효;김진현
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 1999.04a
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    • pp.7-16
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    • 1999
  • The aim of this research was to evaluate the influences of coating components and structures on ink absorbency. The ink absorbency was measured as porosity, K&N ink absorption, gloss and ink set-off. In order to obtain the relationship between the coating structure and the ink absorbency, the binder level was adjusted and two types of pigments were examined. One of the pigments was known to make the porous coating structure and the other one had strong ink affinity. The effects of coating components were studied by applying six different types of latex and various additives . In this research, CLC(cylindrical laboratory coater) and Prufbau printability tester were used. It was found that the decreasing latex dosage and introducing porous pigment were effective solutions to increase ink absorbency. However, the ink absorbency could not be improved by applying the fine pigment even though it had strong ink affinity. Among the characters of the latex, particle size and surface tension were found to have the strong effect on ink absorbency. The ink absorbency increased with large particle size and low surface tension latex. The additives were varied and it was found that applying to the top coating was effective.

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A Nonlinear Response Analysis of Tension Leg Platforms in Irregular Waves (불규칙파중의 인장계류식 해양구조물의 비선형 응답 해석)

  • Lee, Chang-Ho;Gu, Ja-Sam;Jo, Hyo-Je;Hong, Bong-Gi
    • Journal of Ocean Engineering and Technology
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    • v.12 no.2 s.28
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    • pp.33-42
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    • 1998
  • In the presence of incident waves with different frequencies, the second order sum and difference frequency waves due to the nonlinearity of the incident waves come into existence. Although the magnitudes of the forces produced on a Tension Leg Platform(TLP) by these nonlinear waves are small, they act on the TLP at sum and difference frequencies away from those of the incident waves. So, the second order sum and difference frequency wave loads produced close to the natural frequencies of TLPs often give greater contributions to high and low frequency resonant responses. The second order wave exciting forces and moments have been obtained by the method based on direct integration of pressure acting on the submerged surface of a TLP. The components of the second order forces which depend on first order quantities have been evaluated using the three dimensional source distribution method. The numerical results of time domain analysis for the nonlinear wave exciting forces in regular waves are compared with the numerical ones of frequency domain analysis. The results of comparison confirmed the validity of the proposed approach.

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FE Simulation of Axial Crushing Test for AZ31 Tube Considering Tension-Compression Asymmetry (압축-인장 비대칭을 고려한 AZ31 튜브의 압괴해석)

  • Yoon, Jong-Hun;Lee, Jung-Hwan
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.36 no.9
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    • pp.997-1002
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    • 2012
  • With the increasing demand for lightweight materials to reduce fuel consumption, especially in the transportation industry, magnesium alloys are being widely studied. However, there are several limitations to the large-scale application of magnesium alloys in a structure because of their low formability and strong anisotropy. In order to take into account both the strong anisotropy and tension-compression asymmetry of AZ31 sheet alloy, the Cazacu-Plunkett-Barlat yield criterion (Cazacu, 2006) was adopted in material modeling. The variation of the anisotropic coefficients that describe the yield surface evolution of AZ31 is optimized using an interpolation function based on specific calibration results. It generates continuous yield surfaces, which makes it possible to describe different hardening rates in tension and compression as well as the tension-compression asymmetry of magnesium alloys. The performance of the CPB06 yield criterion for simulating an axial crushing test was tested and compared with that of the Hill (1948) yield criterion.

Novel Bumping Process for Solder on Pad Technology

  • Choi, Kwang-Seong;Bae, Ho-Eun;Bae, Hyun-Cheol;Eom, Yong-Sung
    • ETRI Journal
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    • v.35 no.2
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    • pp.340-343
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    • 2013
  • A novel bumping process using solder bump maker is developed for the maskless low-volume solder on pad (SoP) technology of fine-pitch flip chip bonding. The process includes two main steps: one is the aggregation of powdered solder on the metal pads on a substrate via an increase in temperature, and the other is the reflow of the deposited powder to form a low-volume SoP. Since the surface tension that exists when the solder is below its melting point is the major driving force of the solder deposit, only a small quantity of powdered solder adjacent to the pads can join the aggregation process to obtain a uniform, low-volume SoP array on the substrate, regardless of the pad configurations. Through this process, an SoP array on an organic substrate with a pitch of $130{\mu}m$ is successfully formed.